Aids to Computation in Spectrophotometric Analysis of Binary Mixtures

1946 ◽  
Vol 18 (10) ◽  
pp. 603-604 ◽  
Author(s):  
Mark Fred ◽  
F.W. Porsche
1979 ◽  
Vol 62 (1) ◽  
pp. 67-70
Author(s):  
Abdel-Aziz Wahbi ◽  
Hassan Abdine ◽  
Mohamed Korany ◽  
Fawzi El-Yazbi

Abstract Different methods for analyzing binary mixtures by using 2 wavelengths are reviewed. The absorbance ratio calculated at 2 wavelengths, not including the isoabsorptive point, was a quadratic function of relative concentration. The curve-fitting process using orthogonal polynomials was applied to obtain the quadratic equation. An absorbance ratio can be used as a rapid purity index for sulfacetamide sodium in the presence of sulfanilamide. Sulfacetamide sodium has been determined in eye drop preparations.


1978 ◽  
Vol 67 (1) ◽  
pp. 140-141 ◽  
Author(s):  
A.M. Wahbi ◽  
H. Abdine ◽  
M.A. Korany ◽  
F.A. El-Yazbi

2003 ◽  
Vol 26 (1) ◽  
pp. 5-13
Author(s):  
Abd El-Maaboud Mohamed ◽  
Samiha Hussein ◽  
Hanaa Abdel-Wadood

1954 ◽  
Vol 32 (1) ◽  
pp. 610-620 ◽  
Author(s):  
D. H. Laughland ◽  
W. E. J. Phillips

A study has been made of the reaction whereby a blue adsorption complex is formed when an organic solvent solution of vitamin A is added to sodium bentonite. In addition to a physical adsorption of the vitamin on sodium bentonite a chemical alteration occurs in the vitamin A molecule which results in the formation of anhydro vitamin A. The adsorbed material may be removed from the sodium bentonite by extraction with diethyl ether but the blue color is dissipated and a secondary reaction product is formed. This latter compound exhibits the characteristics of triene conjugation and exhibits maximum absorption at about 290 mμ. Equations have been developed for the spectrophotometric analysis of the binary mixtures encountered in the reaction and satisfactory agreement has been obtained between calculated and observed values.


1954 ◽  
Vol 32 (6) ◽  
pp. 610-620 ◽  
Author(s):  
D. H. Laughland ◽  
W. E. J. Phillips

A study has been made of the reaction whereby a blue adsorption complex is formed when an organic solvent solution of vitamin A is added to sodium bentonite. In addition to a physical adsorption of the vitamin on sodium bentonite a chemical alteration occurs in the vitamin A molecule which results in the formation of anhydro vitamin A. The adsorbed material may be removed from the sodium bentonite by extraction with diethyl ether but the blue color is dissipated and a secondary reaction product is formed. This latter compound exhibits the characteristics of triene conjugation and exhibits maximum absorption at about 290 mμ. Equations have been developed for the spectrophotometric analysis of the binary mixtures encountered in the reaction and satisfactory agreement has been obtained between calculated and observed values.


1980 ◽  
Vol 77 ◽  
pp. 445-449 ◽  
Author(s):  
Zohra Ferhat-Hamida ◽  
Robert Philippe ◽  
Jean-Claude Merlin ◽  
V. Kehiaian

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