Sulfur Speciation and Stable Isotope Trends of Water-Soluble Sulfates in Mine Tailings Profiles

2005 ◽  
Vol 39 (15) ◽  
pp. 5650-5656 ◽  
Author(s):  
Bernhard Dold ◽  
Jorge E. Spangenberg
Author(s):  
Andrea Lazo ◽  
Henrik Hansen ◽  
Pamela Lazo ◽  
Claudia Gutiérrez

Mine tailings have been analyzed by a sequential extraction procedure after their pre-treatment with a leaching solution for 24 h and electrodialytic remediation during 15 days with a constant electric field of 2.7 V cm−1. Four leaching solutions were tested: H2SO4 + HNO3 (2:1 vol.) pH = 1.9; H2SO4 + HNO3 (2:1 vol) pH = 4.2; NH4Cl 0.8M, pH = 5.5 and 30% H2O2 adjusted to pH 2 with HNO3 1M + HCl 1M. After the treatment, the tailings were divided in six slices from anode to cathode. The highest removal efficiency of copper was obtained with H2SO4 + HNO3 pH = 1.9, which allows one to remove 67% of the copper in the total cell and 85% of the copper in the slice closest to anode. The same solution with pH = 4.2 allows one to remove 62% of the total copper. The analysis realized by the sequential extraction method indicates the easy removal of water-soluble and exchangeable fractions in all experiments, moreover, residual and sulfide are the less mobile fractions. The general trend was the movement of copper associated to different fractions from anode to cathode and its accumulation closest to the cathode in the case of exchangeable, Fe-Mn oxides and acid soluble fractions, possibly due to some precipitation of copper compounds associated with less acidic conditions.


2014 ◽  
Vol 379 (1-2) ◽  
pp. 93-107 ◽  
Author(s):  
Isabel Parraga-Aguado ◽  
Jose-Ignacio Querejeta ◽  
María Nazaret González-Alcaraz ◽  
Francisco J. Jiménez-Cárceles ◽  
Hector M. Conesa

1999 ◽  
Vol 77 (3) ◽  
pp. 410-425 ◽  
Author(s):  
Giuseppe Bagatto ◽  
Joseph D Shorthouse

INCO Ltd., a large mining company near Sudbury, Ont., deposits vast amounts of tailings on its property. These tailings contain elevated levels of Cu, Ni, and sulphides, and to curtail dust and acid drainage, INCO has undertaken a long-term project to cover its tailings with vegetation. Yearly amelioration of fresh tailings with limestone and fertilizer, followed by seeding with various grasses and herbs, transplanted conifers, and the later colonization of volunteer species of plants from adjoining forests, has resulted in the formation of ecosystems of varying age and complexity. To assess the long-term effectiveness of INCO's vegetation techniques, we studied floral diversity, attributes of developing soils, and the accumulation of Cu and Ni in various plant species growing on tailings at different stages of development. Habitat disturbance by tailings deposition, and its subsequent floral recolonizaton, is an example of "anthropogenic succession." Tailings that do not receive amelioration in the form of lime, fertilizer, and seeding remain free of vegetation, other than sparce clumps of the metal-tolerant grass Deschampsia caespitosa (L.) Beauv. Once amelioration begins, various species of grasses and herbs are able to subsist and within 8 years volunteer species begin to colonize. Substrate pH of dried tailings is less than 4 while the pH in upper horizons ranges from 5 to 6, increasing as the sites become more florally diverse; however, pH at lower depths remains less than 4. Substrate organic content in upper horizons at restored sites ranges from 4.5 to 5.0%. Water-soluble concentrations of Cu and Ni in upper horizons ranges from 1 to 5 µg/g dry mass, and 0.5 to 6 µg/g dry mass, respectively, and both metals decrease with increasing floral diversity. Levels of Ni increase at lower depths indicating greater substrate mobility. Levels of Cu and Ni are higher in plants from tailings than in those from control sites; however, concentrations do not decrease in plants from older and more florally diverse tailings sites. Root tissues contain significantly higher concentrations of Cu and Ni than aerial tissues. Monitoring air with moss plates indicates that dispersal of airborne metallic dust remains a problem.Key words: mine tailings, Sudbury, anthropogenic succession, copper, nickel, acid, monitoring.


2005 ◽  
Vol 348 (1-3) ◽  
pp. 231-243 ◽  
Author(s):  
Pilar Fernández ◽  
Irene Sommer ◽  
Silke Cram ◽  
Irma Rosas ◽  
Margarita Gutiérrez

Soil Research ◽  
2008 ◽  
Vol 46 (7) ◽  
pp. 493 ◽  
Author(s):  
Byong-Gu Ko ◽  
Christopher W. N. Anderson ◽  
Nanthi S. Bolan ◽  
Keun-Young Huh ◽  
Iris Vogeler

The objectives of this study were (1) to compare the bioavailability of arsenic (As) to plants in an As-spiked agricultural soil and a naturally contaminated mine tailings, (2) to compare the theoretical ability of various chemical amendments to solubilise As in naturally contaminated mine tailings, and (3) to examine the ability of Brassica juncea (Indian mustard) plants to remove the solubilised As from the soil and tailings. The growth media used for this study included mine tailings from a gold mine in Fiji contaminated with As (683 As mg/kg) due to the presence of arsenopyrite in the mined rock, and a pasture soil from New Zealand (Manawatu sandy loam) amended with lime and/or As. Brassica juncea was grown in these substrates in a glasshouse. In a separate batch experiment, we examined the theoretical ability of several chemical extractants to solubilise As from the mine tailings. Of the tested extractants, only hydrochloric acid (HCl) and a mixture containing ammonium oxalate (NH4)2C2O4, oxalic acid, and ascorbic acid were effective in extracting As from the tailings. In the plant growth experiment, solutions of these 2 chemicals were used as soil amendments at 2 different concentrations to increase As uptake by 6-week-old, actively growing B. juncea plants. Arsenic bioavailability as a function of the growth media influenced the germination rate of B. juncea, the As concentration in the plants, and the water-soluble As concentration in the media. There was approximately a 3-fold reduction in the germination of seeds, and a 64- and 380-fold increase in As concentration in plant and soil solution, respectively, in the spiked Manawatu soil compared with the naturally contaminated Fiji mine tailings. The spiking of soil with As did not mimic naturally contaminated tailings in this experiment. The total amount of As taken up by B. juncea plants increased approximately 9 fold with the addition of the amendments. However, the phytoremediation capacity of B. juncea for As extraction in Fiji mine tailings was too low for efficient remediation even in the presence of solubilising chemicals.


2012 ◽  
Vol 76 (5) ◽  
pp. 1209-1228 ◽  
Author(s):  
D. Kossoff ◽  
K. A. Hudson-Edwards ◽  
W. E. Dubbin ◽  
M. Alfredsson ◽  
T. Geraki

AbstractThe weathering and oxidation of mine tailings has the potential to contaminate water and soil with toxic elements. To understand the mechanisms, extent and products of the long-term weathering of complex Bolivian tailings from the Cerro Rico de Potosí, and their effects on As, Pb, P and Sb cycling, three-year long laboratory column experiments were carried out to model 20 years of dry- and wet-season conditions in the Pilcomayo basin. Chemical analysis of the leachate and column solids, optical mineralogy, X-ray diffraction, scanning electron microscopy, electron probe microanalysis, microscale X-ray absorption near edge structure spectroscopy, Bureau Commun de Référence sequential extraction and water-soluble chemical extractions, and speciation modelling have shown that the weathering of As-bearing pyrite and arsenopyrite, resulted in a loss of 13–29% of the original mass of As. By contrast, Pb and Sb showed much lower mass losses (0.1–1.1% and 0.6–1.9%, respectively) due to the formation of insoluble Pb- and Sb(V)-rich phases, which were stable at the low pH (~2) conditions that prevailed by the end of the experiment. The experiment also demonstrated a link between the cycling of As, Sb, and the oxidation of Fe(II)-bearing sphalerite, which acted as a nucleation point for an Fe-As-Sb-O phase. Phosphorus was relatively immobile in the tailings columns (up to 0.3% mass loss) but was more mobile in the soil-bearing columns (up to 10% mass loss), due to the formation of soluble P-bearing minerals or mobilization by organic matter. These results demonstrate the influence of mine tailings on the mobility of P from soils and on the potential contamination of ecosystems with As, and strongly suggest that these materials should be isolated from fluvial environments.


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