Kinetics of trace metal complexation: role of alkaline-earth metals

1988 ◽  
Vol 22 (12) ◽  
pp. 1469-1478 ◽  
Author(s):  
Janet G. Hering ◽  
Francois M. M. Morel
Keyword(s):  
Trace Metal ◽  
Alkaline Earth ◽  
Metal Complexation ◽  
Alkaline Earth Metals ◽  
Kinetics Of

scholarly journals The Influence of Alkali and Alkaline Earth Metals and the Role of Acid Pretreatments in Production of Sugars from Switchgrass Based on Solvent Liquefaction

2014 ◽  
Vol 28 (2) ◽  
pp. 1111-1120 ◽  
Author(s):  
Xianglan Bai ◽  
Robert C. Brown ◽  
Jie Fu ◽  
Brent H. Shanks ◽  
Matthew Kieffer
Keyword(s):  
Alkaline Earth ◽  
Alkaline Earth Metals

Kinetics of trace metal complexation: ligand-exchange reactions

1990 ◽  
Vol 24 (2) ◽  
pp. 242-252 ◽  
Author(s):  
Janet G. Hering ◽  
Francois M. M. Morel
Keyword(s):  
Trace Metal ◽  
Ligand Exchange ◽  
Metal Complexation ◽  
Exchange Reactions ◽  
Kinetics Of

Oxidation Kinetics of Cu Alloys Containing Alkaline Earth Metals at Low Temperature

2021 ◽  
Vol 21 (3) ◽  
pp. 2071-2074
Author(s):  
Seong-Ho Ha ◽  
Shah Abdul Wahid ◽  
Bong-Hwan Kim ◽  
Young-Ok Yoon ◽  
Hyun-Kyu Lim ◽  
...  
Keyword(s):  
Master Alloy ◽  
Alkaline Earth ◽  
Oxidation Behavior ◽  
Testing Temperature ◽  
Alkaline Earth Metals ◽  
Alloying Element ◽  
Oxidation Rates ◽  
Cu Alloys ◽  
Mg Addition ◽  
Kinetics Of

In this study, the oxidation behavior of Cu alloys containing two alkaline earth metals (i.e., Mg and Ca) at 500 °C was investigated. The Mg+Mg2Ca master alloy was used for the simultaneous addition of Mg and Ca into Cu. As a result of the oxidation test, all examined samples showed weight gains that followed parabolic laws. Mg addition in Cu considerably slowed down the oxidation rate, while the use of the Mg+Mg2Ca master alloy as an alloying element for Mg led to an even further reduction in the oxidation rates at the testing temperature. The phase diagrams with the oxygen partial pressure showed that the Ca and Mg-containing alloy resulted in the formation of CaO as the primary oxide and MgO as the secondary oxide. The improved oxidation resistance can be attributed to the mixed surface layer of CaO and MgO, which control the growth rate of Cu2O.

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