EPR and Spectroscopic Studies ofS-Methyl-N-salicylidenehydrazinecarbothioatophenanthrolineoxovanadium(IV) as Model Compound for Vanadium Bound to Nitrogen and Sulfur Heteroatoms

2000 ◽  
Vol 14 (1) ◽  
pp. 179-183 ◽  
Author(s):  
Jimmy S. Hwang ◽  
M. O. Hamad Al-Turabi ◽  
Laila El-Sayed ◽  
H. A. M. Al-Gwidi
2004 ◽  
Vol 77 (2) ◽  
pp. 201-213
Author(s):  
C. C. Pierre ◽  
R. N. Datta

Abstract Model compound vulcanization in combination with reversed-phase high-performance liquid chromatography and NMR spectroscopy was used to elucidate the reactions of accelerator, sulfur, zinc stearate and zinc-2-mercaptopyridine-N-oxide (ZPNO) in natural rubber vulcanization. Studies of different curing ingredient formulations in squalene have been done to determine the influence of each component during the vulcanization. It was found that 2-mercaptopyridine-N-oxide bridged adducts (R-Sx-Pyr(O)) were formed when squalene was heated in the presence of sulfur, curing ingredients and 2,2′-dithiobis(pyridine-N-oxide) (PyrO-S2-PyrO). Possible interactions of R-Sx-Pyr(O) with carbon black have been proposed.


1987 ◽  
Vol 84 ◽  
pp. 443-448 ◽  
Author(s):  
Teresa Kowalik ◽  
Brigitte Decock-Le Reverend ◽  
Claude Loucheux ◽  
Damien Ficheux ◽  
Henryk Kozlowski

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-187-C1-188 ◽  
Author(s):  
G. P. Gupta ◽  
J. A. Baines ◽  
D. M. Cooper ◽  
D. P.E. Dickson ◽  
C. E. Johnson

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