Investigation of High-Temperature Steam Hydration of Naturally Derived Calcium Oxide for Improved Carbon Dioxide Capture Capacity over Multiple Cycles

2012 ◽  
Vol 26 (6) ◽  
pp. 3903-3909 ◽  
Author(s):  
Nihar Phalak ◽  
Niranjani Deshpande ◽  
L.-S. Fan
2017 ◽  
Vol 5 (8) ◽  
pp. 1514-1514
Author(s):  
Liang Huang ◽  
Yu Zhang ◽  
Wanlin Gao ◽  
Takuya Harada ◽  
Qingqing Qin ◽  
...  

2017 ◽  
Vol 5 (8) ◽  
pp. 1328-1336 ◽  
Author(s):  
Liang Huang ◽  
Yu Zhang ◽  
Wanlin Gao ◽  
Takuya Harada ◽  
Qingqing Qin ◽  
...  

2017 ◽  
Vol 253 ◽  
pp. 114-127 ◽  
Author(s):  
L. Bernadet ◽  
J. Laurencin ◽  
G. Roux ◽  
D. Montinaro ◽  
F. Mauvy ◽  
...  

2018 ◽  
Vol 20 (41) ◽  
pp. 26570-26579 ◽  
Author(s):  
M. L. Grasso ◽  
M. V. Blanco ◽  
F. Cova ◽  
J. A. González ◽  
P. Arneodo Larochette ◽  
...  

The formation pathway of Li4SiO4 involves Li2SiO3 as an intermediate. Carbonation of Li4SiO4 under dynamical conditions retards the double shell formation, improving CO2 capture capacity.


2017 ◽  
Vol 139 (5) ◽  
Author(s):  
Leanne Reich ◽  
Luke Melmoth ◽  
Lindsey Yue ◽  
Roman Bader ◽  
Robert Gresham ◽  
...  

An engineering design for a novel 1-kW solar-driven reactor to capture carbon dioxide via the calcium oxide-based two-step carbonation–calcination cycle has been completed. The reactor consists of a downward-facing cylindrical dual cavity. The inner cavity serves as the radiation receiver, while the outer cavity is the reaction chamber that contains a packed- or fluidized-bed of reacting particles. Several aspects have been incorporated in this reactor design, including high flexibility, mechanical rigidity and simplicity, high-temperature and thermal shock resistance, accommodation of thermal expansion, low convective heat losses, uniform gas distribution inside the reaction chamber, and simple reactor assembly. The final reactor design is presented, and the reactor assembly is illustrated.


Author(s):  
Man Su Lee ◽  
D. Yogi Goswami ◽  
Nikhil Kothurkar ◽  
Elias K. Stefanakos

Anthropogenic carbon dioxide emission from its sources must be reduced to decrease the threat of global warming. Calcium oxide is considered as an effective carbon dioxide absorbent in biomass or coal gasification process as well as conventional power plants. It reacts with carbon dioxide to form calcium carbonate which can be decomposed into the original oxide and carbon dioxide at high temperature by calcination. In order to make this method practical for the carbon dioxide capture and sequestration, the performance of the calcium oxide absorbent must be maintained over a large number of carbonation/calcination cycles. For this reason, loss in the surface area of the absorbent due to pore plugging and sintering of particles in cyclic operation must be avoided. To prevent or minimize this problem, a simple and effective procedure for immobilization of calcium oxide on a fibrous alumina mat was developed in this study. The prepared samples were observed by SEM and the cyclic performance of the calcium oxide absorbent was evaluated by TGA experiments and compared to the previous studies in literature. 75% and 62% maximum carbonation conversions of the prepared absorbents with 23 wt % and 55 wt % calcium oxide content were achieved respectively and remained stable even after ten cycles whereas conversion in the literature data dropped steeply with the number of cycles.


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