A Colorful Laboratory Investigation of Hydrophobic Interactions, the Partition Coefficient, Gibbs Energy of Transfer, and the Effect of Hofmeister Salts

2012 ◽  
Vol 89 (8) ◽  
pp. 1074-1077 ◽  
Author(s):  
Daniel F. McCain ◽  
Ottie E. Allgood ◽  
Jacob T. Cox ◽  
Audrey E. Falconi ◽  
Michael J. Kim ◽  
...  
Keyword(s):  
Gibbs Energy ◽  
Partition Coefficient ◽  
Laboratory Investigation ◽  
Hydrophobic Interactions ◽  
Gibbs Energy Of Transfer ◽  
Hofmeister Salts ◽  
Energy Of Transfer

Studies on Thermodynamic Dissociation Constants of 2,2′-Bipyridine and 1,10-Phenanthroline in Acetonitrile + Water Mixtures and Gibbs Energy of Transfer of Hydrogen Ions from Water to Acetonitrile + Water Mixtures

2002 ◽  
Vol 216 (6) ◽  
Author(s):  
G. Bandyopadhyay ◽  
Sujit Chandra Lahiri
Keyword(s):  
Gibbs Energy ◽  
Comparative Study ◽  
Dissociation Constants ◽  
Hydrogen Ions ◽  
Gibbs Energy Of Transfer ◽  
Energy Of Transfer

The thermodynamic dissociation constants for isoelectric reactions of the type LHAttempts were made to understand the basicity and structuredness of acetonitrile + water mixtures from a comparative study of Δ

Preferential Solvation of Silver (I) Bromate in Methanol-Dimethylsulfoxide Mixtures

1984 ◽  
Vol 39 (6) ◽  
pp. 600-602
Author(s):  
S. Janardhanan ◽  
C. Kalidas
Keyword(s):  
Gibbs Energy ◽  
Dimethyl Sulfoxide ◽  
Transport Number ◽  
Preferential Solvation ◽  
Reference Method ◽  
Silver Ion ◽  
Transfer Energy ◽  
Gibbs Energy Of Transfer ◽  
Energy Of Transfer ◽  
Solvent Transport

The solubiltiy of silver bromate, the Gibbs transfer energy of Ag+ and BrO3- and the solvent transport number in methanol-dimethyl sulfoxide mixtures are reported. The solubility of silver bromate increases with addition of DMSO. The Gibbs energy of transfer of the silver ion (based on the ferrocene reference method) decreases, while that of the bromate ion becomes slightly negative with the addition of DMSO. The solvent transport number A passes through a maximum (⊿ = 1.0 at XDMSO = 0.65. From these results, it is concluded that the silver ion is preferentially solvated by DMSO whereas the bromate ion shows no preferential solvation.

scholarly journals Transfer of Individual Ions from H2O to D2O. Gibbs Energy of Transfer of Dimethylmaleate Ion.

1977 ◽  
Vol 31a ◽  
pp. 585-590 ◽  
Author(s):  
Antti Vesala ◽  
Juho-Pertti Jalava ◽  
Pentti Salomaa ◽  
H. Svanholt ◽  
Paul Hagenmuller ◽  
...  
Keyword(s):  
Gibbs Energy ◽  
Gibbs Energy Of Transfer ◽  
Energy Of Transfer

Studies on Thermodynamic Dissociation Constants of 2,2’-Bipyridine, or 1,10-Phenanthroline in Acetone + Water Mixtures and Gibbs Energy of Transfer of the Hydrogen Ion from Water to Acetone + Water Mixtures

2001 ◽  
Vol 215 (1) ◽  
Author(s):  
G. Bandyopadhyay ◽  
Sujit Chandra Lahiri
Keyword(s):  
Gibbs Energy ◽  
Comparative Study ◽  
Structural Properties ◽  
Dissociation Constants ◽  
Hydrogen Ion ◽  
Gibbs Energy Of Transfer ◽  
Acetone Water ◽  
Energy Of Transfer

AbstractThe thermodyamic dissociation constants for isoelectric reaction of the type LHAttempts have been made to understand the basicity and structural properties of acetone + water mixtures from a comparative study of ΔG

Dissociation Constants of p-Nitroaniline in Mixed Solvents and a Critical Assessment of the Solvent-Sorting Equilibrium Method for the Determination of the Single Ion Gibbs Energy of Transfer of H+ Ion from Aqueous to Aquo Rich Organic Solvents

2001 ◽  
Vol 215 (1) ◽  
Author(s):  
G. Bandyopadhyay ◽  
R. Mondal ◽  
Sujit Chandra Lahiri
Keyword(s):  
Gibbs Energy ◽  
Organic Solvents ◽  
Dissociation Constants ◽  
Mixed Solvents ◽  
Critical Assessment ◽  
Gibbs Energy Of Transfer ◽  
Equilibrium Method ◽  
Energy Of Transfer

AbstractThe dissociation constants of p-nitroaniline (B) (A critical assessment of the solvent-sorting equilibrium method using p-nitroaniline as indicator has been made. The method is not suitable to determine the Gibbs energy of transfer of H

The Measurement of the Gibbs Energy of Transfer Between Oil and Water Using a Nano-Carbon Paste Electrode

2013 ◽  
Vol 26 (2) ◽  
pp. 351-358 ◽  
Author(s):  
Patrick Gan ◽  
Denise Lowinsohn ◽  
John S Foord ◽  
Richard G Compton
Keyword(s):  
Gibbs Energy ◽  
Carbon Paste Electrode ◽  
Carbon Paste ◽  
Gibbs Energy Of Transfer ◽  
Nano Carbon ◽  
Energy Of Transfer ◽  
Paste Electrode
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