Synthesis of Imidazolium Room-Temperature Ionic Liquids. Exploring Green Chemistry and Click Chemistry Paradigms in Undergraduate Organic Chemistry Laboratory

2009 ◽  
Vol 86 (7) ◽  
pp. 856 ◽  
Author(s):  
Sergei V. Dzyuba ◽  
Katherine D. Kollar ◽  
Salil S. Sabnis
Keyword(s):  
Organic Chemistry ◽  
Ionic Liquids ◽  
Green Chemistry ◽  
Click Chemistry ◽  
Room Temperature ◽  
Chemistry Laboratory ◽  
Room Temperature Ionic Liquids ◽  
Organic Chemistry Laboratory

scholarly journals Synthesis Chalones and Their Isomerization into Flavanones and Azaflavanones

2019 ◽  
Vol 2 (3) ◽  
pp. 70 ◽  
Author(s):  
Djenisa H. A. Rocha ◽  
Patrícia A. A. M. Vaz ◽  
Diana C. G. A. Pinto ◽  
Artur M. S. Silva
Keyword(s):  
Organic Chemistry ◽  
Reaction Time ◽  
Green Chemistry ◽  
Microwave Irradiation ◽  
Aldol Condensation ◽  
Chemistry Laboratory ◽  
Efficient Catalyst ◽  
Theoretical Concepts ◽  
Catalyst Systems ◽  
Organic Chemistry Laboratory

Flavanones [2-aryl-2,3-dihydrochromen-4(1H)ones] and 2-aryl-2,3-dihydroquinolin-4(1H)-ones are valuable precursors in the synthesis of important pharmacological scaffolds, so efficient methodologies towards their synthesis are important in the medicinal chemistry context. Their synthesis also involves theoretical concepts such as aldol condensation, isomerization, and catalysis that make it useful in an undergraduate organic chemistry laboratory. The use of both microwave irradiation as a source of energy to promote reactions and efficient catalysts are considered within green chemistry principles, mostly because the reaction yields are improved and reaction time decreased. In this paper, the efficiency of microwave irradiation use in the synthesis of chalcone derivatives and efficient catalyst systems to promote their isomerization into flavanones and 2-aryl-2,3-dihydroquinolin-4(1H)-ones is demonstrated.

How the Principles of Green Chemistry Changed the Way Organic Chemistry Labs Are Taught at the University of Detroit Mercy

2017 ◽  
Vol 2 (2) ◽  
Author(s):  
Matthew J. Mio
Keyword(s):  
Organic Chemistry ◽  
Green Chemistry ◽  
Learning Outcomes ◽  
Chemistry Laboratory ◽  
Atom Economy ◽  
Laboratory Courses ◽  
Instructional Changes ◽  
Organic Chemistry Laboratory ◽  
The University ◽  
The Way

Abstract Many logistic and instructional changes followed the incorporation of the 12 principles of green chemistry into organic chemistry laboratory courses at the University of Detroit Mercy. Over the last decade, institutional limitations have been turned into green chemical strengths in many areas, including integration of atom economy metrics into learning outcomes, replacing overly toxic equipment and reagents, and modifying matters of reaction scale and type.

Emission based oxygen sensing approach with tris(2,2′-bipyridyl)ruthenium(II)chloride in green chemistry reagents: room temperature ionic liquids

2008 ◽  
Vol 161 (1-2) ◽  
pp. 209-216 ◽  
Author(s):  
Sevinc Z. Topal ◽  
Kadriye Ertekin ◽  
Derya Topkaya ◽  
Serap Alp ◽  
Berrin Yenigul
Keyword(s):  
Ionic Liquids ◽  
Green Chemistry ◽  
Room Temperature ◽  
Oxygen Sensing ◽  
Room Temperature Ionic Liquids
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