X-ray Absorption Study of Structural Coupling in Photomagnetic Prussian Blue Analogue Core@Shell Particles

2014 ◽  
Vol 26 (8) ◽  
pp. 2586-2594 ◽  
Author(s):  
Daniel M. Pajerowski ◽  
Bruce Ravel ◽  
Carissa H. Li ◽  
Matthieu F. Dumont ◽  
Daniel R. Talham
2013 ◽  
Vol 62 (12) ◽  
pp. 1910-1913 ◽  
Author(s):  
Eunsook Lee ◽  
D. H. Kim ◽  
Jihoon Hwang ◽  
J. -S. Kang ◽  
Nguyen Van Minh ◽  
...  

Author(s):  
Wanhong He ◽  
John M. Cain ◽  
Mark W. Meisel ◽  
Daniel R. Talham

Core–shell particles with a Prussian blue analogue RbaCob[Fe(CN)6]c·mH2O core and different shell thicknesses are studied as the cores undergo both thermal and light-induced spin transitions, revealing different mechanisms for accommodating strain.


1987 ◽  
Vol 48 (C9) ◽  
pp. C9-1049-C9-1052
Author(s):  
P. BELOUGNE ◽  
B. DEROIDE ◽  
J. M. ESTEVA ◽  
R. C. KARNATAK ◽  
J. V. ZANCHETTA

2000 ◽  
Vol 19 (1-6) ◽  
pp. 277-283 ◽  
Author(s):  
Isabella Ascone ◽  
Andrea Cognigni ◽  
Yann Le Godec ◽  
Jean Paul Itié

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3371 ◽  
Author(s):  
Svensson ◽  
Grins ◽  
Eklöf ◽  
Eriksson ◽  
Wardecki ◽  
...  

The CO2 adsorption on various Prussian blue analogue hexacyanoferrates was evaluated by thermogravimetric analysis. Compositions of prepared phases were verified by energy-dispersive X-ray spectroscopy, infra-red spectroscopy and powder X-ray diffraction. The influence of different alkali cations in the cubic Fm3m structures was investigated for nominal compositions A2/3Cu[Fe(CN)6]2/3 with A = vacant, Li, Na, K, Rb, Cs. The Rb and Cs compounds show the highest CO2 adsorption per unit cell, 3.3 molecules of CO2 at 20 C and 1 bar, while in terms of mmol/g the Na compound exhibits the highest adsorption capability, 3.8 mmol/g at 20 C and 1 bar. The fastest adsorption/desorption is exhibited by the A-cation free compound and the Li compound. The influence of the amount of Fe(CN)6 vacancies were assessed by determining the CO2 adsorption capabilities of Cu[Fe(CN)6]1/2 (Fm3m symmetry, nominally 50% vacancies), KCu[Fe(CN)6]3/4 (Fm3m symmetry, nominally 25% vacancies), and CsCu[Fe(CN)6] (I-4m2 symmetry, nominally 0% vacancies). Higher adsorption was, as expected, shown on compounds with higher vacancy concentrations.


2011 ◽  
Author(s):  
Yogesh Kumar ◽  
Abhinav Pratap Singh ◽  
P. Thakur ◽  
Ravi Kumar ◽  
Alka B. Garg ◽  
...  

2003 ◽  
Vol 372 (3-4) ◽  
pp. 320-324 ◽  
Author(s):  
Y.H Tang ◽  
X.T Zhou ◽  
Y.F Hu ◽  
C.S Lee ◽  
S.T Lee ◽  
...  

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