Mismatched Heteroepitaxy of Tetrahedral Semiconductors with Si via ZrB2Templates

2005 ◽  
Vol 17 (18) ◽  
pp. 4647-4652 ◽  
Author(s):  
Rahul Trivedi ◽  
Po−Liang Liu ◽  
Radek Roucka ◽  
John Tolle ◽  
Andrew V. G. Chizmeshya ◽  
...  
Author(s):  
Rob. W. Glaisher ◽  
A.E.C. Spargo

Images of <11> oriented crystals with diamond structure (i.e. C,Si,Ge) are dominated by white spot contrast which, depending on thickness and defocus, can correspond to either atom-pair columns or tunnel sites. Olsen and Spence have demonstrated a method for identifying the correspondence which involves the assumed structure of a stacking fault and the preservation of point-group symmetries by correctly aligned and stigmated images. For an intrinsic stacking fault, a two-fold axis lies on a row of atoms (not tunnels) and the contrast (black/white) of the atoms is that of the {111} fringe containing the two-fold axis. The breakdown of Friedel's law renders this technique unsuitable for the related, but non-centrosymmetric binary compound sphalerite materials (e.g. GaAs, InP, CdTe). Under dynamical scattering conditions, Bijvoet related reflections (e.g. (111)/(111)) rapidly acquire relative phase differences deviating markedly from thin-crystal (kinematic) values, which alter the apparent location of the symmetry elements needed to identify the defect.


1984 ◽  
Vol 121 (1) ◽  
pp. K43-K45 ◽  
Author(s):  
L. N. Blinov ◽  
L. A. Baydakov ◽  
Z. Cimpl ◽  
F. Kosek

2004 ◽  
Vol 18 (07) ◽  
pp. 975-988
Author(s):  
SHAILESH SHUKLA ◽  
DEEPAK KUMAR ◽  
NITYA NATH SHUKLA ◽  
RAJENDRA PRASAD

Although most insulators are expected to undergo insulator to metal transition on lattice compression, tetrahedral semiconductors Si, GaAs and InSb can become metallic on compression as well as by expansion. We focus on the transition by expansion which is rather peculiar; in all cases the direct gap at Γ point closes on expansion and thereafter a zero-gap state persists over a wide range of lattice constant. The solids become metallic at an expansion of 13% to 15% when an electron Fermi surface around L-point and a hole Fermi surface at Γ-point develop. We provide an understanding of this behavior in terms of arguments based on symmetry and simple tight-binding considerations. We also report results on the critical behavior of conductivity in the metal phase and the static dielectric constant in the insulating phase and find common behavior. We consider the possibility of excitonic phases and distortions which might intervene between insulating and metallic phases.


1989 ◽  
Vol 40 (14) ◽  
pp. 9644-9651 ◽  
Author(s):  
J. R. Chelikowsky ◽  
T. J. Wagener ◽  
J. H. Weaver ◽  
A. Jin

1984 ◽  
Vol 126 (1) ◽  
pp. 11-36 ◽  
Author(s):  
A. Blacha ◽  
H. Presting ◽  
M. Cardona

1984 ◽  
Vol 52 (8) ◽  
pp. 675-678 ◽  
Author(s):  
H. W. A. M. Rompa ◽  
M. F. H. Schuurmans ◽  
F. Williams

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