Cadmium Metal-Directed Three-Dimensional Coordination Polymers: In Situ Tetrazole Ligand Synthesis, Structures, and Luminescent Properties

2010 ◽  
Vol 10 (3) ◽  
pp. 1332-1340 ◽  
Author(s):  
Yongcai Qiu ◽  
Yinghua Li ◽  
Guo Peng ◽  
Jinbiao Cai ◽  
Limin Jin ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Cadmium Metal ◽  
Ligand Synthesis

Zinc and cadmium metal-directed coordination polymers: in situ flexible tetrazole ligand synthesis, structures, and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (30) ◽  
pp. 5814-5831 ◽  
Author(s):  
Ruo Ting Dong ◽  
Zhao Ying Ma ◽  
Li Xin Chen ◽  
Lan Fen Huang ◽  
Qian Hong Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Conditions ◽  
Structures And Properties ◽  
Cadmium Metal ◽  
Ligand Synthesis ◽  
Coordination Frameworks

Seven zinc and cadmium coordination frameworks were obtained through in situ tetrazole synthesis. By varying the hydrothermal conditions the unprecedented generation of tetrazole ligands were achieved.

Two Coordination Polymers Created via In Situ Ligand Synthesis Involving C−N and C−C Bond Formation

2007 ◽  
Vol 46 (21) ◽  
pp. 8717-8721 ◽  
Author(s):  
Russell K. Feller ◽  
Paul M. Forster ◽  
Fred Wudl ◽  
Anthony K. Cheetham
Keyword(s):  
Coordination Polymers ◽  
Bond Formation ◽  
Ligand Synthesis

Two copper coordination polymers with pyridine imine-based ligand: Synthesis, crystal structure and luminescent properties

2012 ◽  
Vol 162 (13-14) ◽  
pp. 1126-1132 ◽  
Author(s):  
Yan-Hua Fan ◽  
Jun-Li Wang ◽  
Yan Bai ◽  
Dong-Bin Dang ◽  
Ya-Qing Zhao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Luminescent Properties ◽  
Copper Coordination ◽  
Ligand Synthesis

Metal Ion-Driven Assembly of Two New Coordination Polymers Constructed by Asymmetric Tricarboxylate and Imidazole-Containing Ligands: Syntheses, Crystal Structures, and Luminescent Properties

2015 ◽  
Vol 68 (1) ◽  
pp. 121 ◽  
Author(s):  
Wenlong Liu ◽  
Xueying Wang ◽  
Mengqiang Wu ◽  
Bing Wang
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Dimensional Structure ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Dimethyl Benzene

Two new coordination polymers, namely, {[Cd3(bpt)2(bimb)2]·2(H2O)}n (1) and [Zn3(bpt)2(bimb)2]n (2) (bpt = biphenyl-3,4′,5-tricarboxylate, bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene), have been obtained under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterised by elemental analysis and infrared spectroscopy. Complex 1 exhibits a trinodal (4,4,4)-connected topology with Schläfli symbol of (4.62.83)4.(64.82). Complex 2 is also a three-dimensional structure and displays a (3,4,6)-connected topology with Schläfli symbol of (4.62)2.(42.66.85.102).(64.82). It is shown that the asymmetrically tricarboxylate can bear diverse structures regulated by metal ions. The photoluminescence behaviours of compounds 1 and 2 were also discussed.

Coordination Polymers with a Bulky Perylene-Based Tetracarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties

2010 ◽  
Vol 63 (3) ◽  
pp. 463 ◽  
Author(s):  
Chun-Sen Liu ◽  
Min Hu ◽  
Song-Tao Ma ◽  
Qiang Zhang ◽  
Li-Ming Zhou ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Supramolecular Interactions ◽  
Polymeric Chain ◽  
Stacking Interactions ◽  
One Dimensional ◽  
Π Stacking ◽  
Higher Dimensional ◽  
Interchain Interactions

To explore the coordination possibilities of perylene-based ligands with a larger conjugated π-system, four ZnII, MnII, and CoII coordination polymers with perylene-3,4,9,10-tetracarboxylate (ptc) and the chelating 1,10-phenanthroline (phen) ligands were synthesized and characterized: {[Zn2(ptc)(phen)2](H2O)10}∞ (1), {[Zn3(ptc)(OH)2(phen)2](H2O)3}∞ (2), {[Mn(ptc)0.5(phen)(H2O)2](H2O)1.5}∞ (3), and {[Co(ptc)0.5(phen)(H2O)2](H2O)2.5}∞ (4). Structural analysis reveals that complexes 1 and 2 both take one-dimensional polymeric chain structures with dinuclear and trinuclear units as nodes, respectively, which are further extended via the accessorial secondary interchain interactions, such as C–H···O H-bonding or aromatic π···π stacking interactions, to give rise to the relevant higher-dimensional frameworks. Compound 3 has a two-dimensional sheet structure that is further assembled to form a three-dimensional framework by interlayer π···π stacking interactions. Complex 4 is a one-dimensional ribbon-like array structure that is interlinked by the co-effects of intermolecular π···π stacking and C–H···π supramolecular interactions, resulting in a higher-dimensional framework from the different crystallographic directions. Moreover, complexes 1–4 exhibit strong solid-state luminescence emissions at room temperature, which mainly originate from intraligand π→π* transitions of ptc.

A New Route for Preparing Coordination Polymers from Hydrothermal Reactions Involving in Situ Ligand Synthesis

2004 ◽  
Vol 43 (7) ◽  
pp. 2261-2266 ◽  
Author(s):  
Xi-Xue Hu ◽  
Ji-Qing Xu ◽  
Peng Cheng ◽  
Xiao-Yan Chen ◽  
Xiao-Bing Cui ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Reactions ◽  
Ligand Synthesis

Two three-dimensional cadmium(ii) coordination polymers based on 5-amino-tetrazolate and 1,2,4,5-benzenetetracarboxylate: the pH value controlled syntheses, crystal structures and luminescent properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4633-4640 ◽  
Author(s):  
Di-Chang Zhong ◽  
Wen-Guan Lu ◽  
Ji-Hua Deng
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Ph Value ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Ph Values

Two 3D cadmium(ii) coordination polymers have been prepared by controlling the pH values of the reaction mixture.

Two coordination polymers of benzene-1,2,4,5-tetracarboxylic acid (H4BTC): in situ ligand syntheses, structures, and luminescent properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (18) ◽  
pp. 3519-3525 ◽  
Author(s):  
Di-Chang Zhong ◽  
Hua-Bin Guo ◽  
Ji-Hua Deng ◽  
Qing Chen ◽  
Xu-Zhong Luo
Keyword(s):  
Coordination Polymers ◽  
Luminescent Properties ◽  
Tetracarboxylic Acid
Sign in / Sign up

Export Citation Format

Share Document