Variation of Structures of Coordination Polymers of Ca(II), Sr(II), and Ba(II) with a Tripodal Ligand: Synthesis, Structural, and Gas Adsorption Studies

2008 ◽  
Vol 8 (5) ◽  
pp. 1554-1558 ◽  
Author(s):  
Subhadip Neogi ◽  
Jorge A. R. Navarro ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Tripodal Ligand ◽  
Adsorption Studies ◽  
Ligand Synthesis

Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

2015 ◽  
Vol 44 (40) ◽  
pp. 17494-17507 ◽  
Author(s):  
Chris S. Hawes ◽  
Nicholas F. Chilton ◽  
Boujemaa Moubaraki ◽  
Gregory P. Knowles ◽  
Alan L. Chaffee ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Material Properties ◽  
Gas Adsorption ◽  
Adsorption Studies ◽  
Ligand Structure

Studies into a series of coordination polymers from a new diamine polycarboxylate ligand reveal an interplay between flexibility and material properties.

Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (22) ◽  
pp. 4783-4795 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debraj Saha ◽  
Dilip Kumar Maity ◽  
Rajdip Dey ◽  
Debajyoti Ghoshal
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Luminescent Properties ◽  
Donor Ligand ◽  
X Ray

Infinite Copper(II) Coordination Architectures from a Resonative Aminotriazine-Derived Tripodal Ligand: Synthesis, Structures, and Magnetic Properties

2012 ◽  
Vol 51 (22) ◽  
pp. 12360-12371 ◽  
Author(s):  
Meng-Jung Tsai ◽  
Jing-Yun Wu ◽  
Ming-Hsi Chiang ◽  
Cheng-Hao Huang ◽  
Ming-Yu Kuo ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Tripodal Ligand ◽  
Ligand Synthesis

Directed adenine functionalization for creating complex architectures for material and biological applications

2017 ◽  
Vol 53 (35) ◽  
pp. 4748-4758 ◽  
Author(s):  
Balaram Mohapatra ◽  
Pratibha Pratibha ◽  
Sandeep Verma
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Bioactive Molecules ◽  
Biological Applications ◽  
Design Strategies ◽  
Feature Article ◽  
Complex Architectures ◽  
Adenine Derivatives

This feature article outlines design strategies for modified adenine derivatives to construct discrete metal complexes, ring-expanded skeletons, coordination polymers, MOFs, and capped nanoparticles, for applications in gas adsorption, as bioimaging agents and as bioactive molecules.

Two Coordination Polymers Constructed from Pentanuclear Zinc Clusters with Triazolate and Benzenecarboxylate Ligands: Selective Gas Adsorption

2018 ◽  
Vol 71 (3) ◽  
pp. 111 ◽  
Author(s):  
Wen-Wen Zhang ◽  
Yu-Ling Wang ◽  
Ying Liu ◽  
Qing-Yan Liu
Keyword(s):  
Porous Structure ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
3D Structure ◽  
Co2 Uptake ◽  
N2 Adsorption ◽  
Carboxylate Oxygen ◽  
Zinc Clusters ◽  
Solvent Molecules ◽  
3D Framework

Reactions of Zn(NO3)2·6H2O with 1,2,4-triazole (Htrz) and 1,3,5-benzenetricarboxylic acid (H3BTC) or 5-sulfoisophthalic acid (5-H3SIP) afforded two coordination polymers, {[Zn5(μ3-OH)2(trz)2(BTC)2(DMF)2]·x(solvent)}n (1) and {[Zn7(trz)8(5-SIP)2(H2O)4]·4(H2O)}n (2). Compound 1 has pentanuclear [Zn5(μ3-OH)2] clusters, which are linked by the triazolate ligands to give a 2D layer. The 2D layer is further bridged by BTC3− ligands to form a 3D framework. The 3D framework of 1 has 1D channels filled by solvent molecules. Desolvated 1 shows a moderate CO2 uptake and high CO2/CH4 and CO2/N2 adsorption selectivities due to its carboxylate oxygen decorated pore environment. Compound 2 contains a rare 3D zinc-triazolate framework constructed from a pentanuclear [Zn5(trz)8] cluster wherein the five zinc atoms are arranged linearly. The 3D zinc-triazolate substructure has 1D open channels filled by 5-SIP3− ligands, which interact with the zinc-triazolate framework through Zn–O bonds, leading to a non-porous 3D structure of 2. Introduction of BTC3− into the zinc-triazolate system gave the porous structure of 1. While a variation of BTC3−, 5-SIP3− was introduced into the zinc-triazolate system yielding a non-porous structure of 2, demonstrating that the secondary ligands play an important role in the formation of the final structures.

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