One dimensional coordination polymers of Cd(II) and Zn(II): Synthesis, structure, polar packing through strong inter-chain hydrogen bonding and gas adsorption studies

Polyhedron ◽  
2016 ◽  
Vol 106 ◽  
pp. 163-170 ◽  
Author(s):  
Rashmi A. Agarwal ◽  
Soumya Mukherjee
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
One Dimensional ◽  
Adsorption Studies

A Three-Component 1D/2D → 2D Interpenetrated Coordination Network: Structure and Gas Adsorption Studies

2014 ◽  
Vol 67 (10) ◽  
pp. 1391 ◽  
Author(s):  
Jin-Xiang Chen ◽  
Ni-Ni Ding ◽  
Ming Chen ◽  
Wen-Hua Chen ◽  
David J. Young ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
Gas Adsorption ◽  
Two Dimensional ◽  
One Dimensional ◽  
Adsorption Studies ◽  
Coordination Network

We herein report a Cd-based coordination polymer containing three integrated polymeric components: two neutral and entangled two-dimensional (6,3) nets and one zwitterionic one-dimensional polymer with corner-sharing double-stranded chains propagating along the c-direction to lock the consecutive ligand struts of the (6,3) nets. Despite a sophisticated entanglement, this coordination polymer is porous to selectively adsorb CO2.

Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

2015 ◽  
Vol 44 (40) ◽  
pp. 17494-17507 ◽  
Author(s):  
Chris S. Hawes ◽  
Nicholas F. Chilton ◽  
Boujemaa Moubaraki ◽  
Gregory P. Knowles ◽  
Alan L. Chaffee ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Material Properties ◽  
Gas Adsorption ◽  
Adsorption Studies ◽  
Ligand Structure

Studies into a series of coordination polymers from a new diamine polycarboxylate ligand reveal an interplay between flexibility and material properties.

Emissive and birefringent Hg(CN)2-based coordination polymer materials with very distorted coordination geometries

2018 ◽  
Vol 96 (2) ◽  
pp. 226-234 ◽  
Author(s):  
David Guan ◽  
John R. Thompson ◽  
Daniel B. Leznoff
Keyword(s):  
Optical Properties ◽  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Polymer Materials ◽  
Stacking Interactions ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Π Stacking ◽  
New Compounds

New compounds and coordination polymers with highly polarizable metals (M = Hg, Pb) and 2,2′;6′2′-terpyridine (terpy) and 2,6-bis(benzimidazol-2-yl)pyridine (bbp) ligands have been synthesized and characterized for their photo-physical and optical properties. Hg(L)(CN)2 (L = terpy, bbp) exhibit π-stacking interactions, which form a supramolecular alignment of the planar terpy and bbp units. Pb(terpy)X2[Hg(CN)2]0.5 (X = Cl, Br) generate one-dimensional coordination polymers through bridging Hg(CN)2 linkers and hydrogen-bonding interactions. All of the metal centres have very distorted coordination geometries. Hg(L)(CN)2 (L = terpy, bbp) and Pb(terpy)Br2[Hg(CN)2]0.5 show terpy or bbp based emission. The materials are very birefringent, with Δn ranging from 0.37(2) to 0.45(2). The magnitude of the observed birefringence depends on the orientation of the highly polarizable terpy and bbp units in relation to the viewing axis of the crystals. These materials represent rare examples of multifunctional emissive and birefringent systems.

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

On-Surface Synthesis of One-Dimensional Coordination Polymers with Tailored Magnetic Anisotropy

2021 ◽  
Author(s):  
Benjamin Mallada ◽  
Piotr Błoński ◽  
Rostislav Langer ◽  
Pavel Jelínek ◽  
Michal Otyepka ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Coordination Polymers ◽  
One Dimensional
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