Modulation of Thermal Expansion by Guests and Polymorphism in a Hydrogen Bonded Host

2015 ◽  
Vol 15 (2) ◽  
pp. 593-601 ◽  
Author(s):  
Viswanadha G. Saraswatula ◽  
Binoy K. Saha
Keyword(s):  
Thermal Expansion ◽  
Hydrogen Bonded

Thermal expansion of β-succinic acid and α-adipic acid in relation to their crystal structures

1965 ◽  
Vol 285 (1402) ◽  
pp. 370-381 ◽  
Keyword(s):  
Thermal Expansion ◽  
Succinic Acid ◽  
Crystal Structures ◽  
Adipic Acid ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Molecular Packing ◽  
X Ray ◽  
Angular Vibration ◽  
Hydrogen Bonded

The thermal expansion quadrics of β -succinic acid and α -adipic acid have been determined by X-ray Weissenberg method. In adipic acid, X-ray measurements have been made between —100 and +100°C and in succinic acid between —150 and +130°C. In these monoclinic crystals, the minimum expansion corresponds to the c axis, which coincides with the direction of the hydrogen-bonded molecular columns. In other directions along which van der Waals forces prevail, thermal expansion is greater, being maximum perpendicular to the (100) planes, the direction of the obtuse bisectrix of the molecular packing angle. The thermal expansion is quantitatively explained by assuming an increase in the angular vibration of the molecules.

Influence of Multiple Hydrogen Bonds on Thermal Expansion Within and Between Two-Dimensional Hydrogen-Bonded Sheets

2019 ◽  
Vol 19 (12) ◽  
pp. 7380-7384
Author(s):  
Xiaodan Ding ◽  
Navkiran Juneja ◽  
Adam W. Crawford ◽  
Eric W. Reinheimer ◽  
Daniel K. Unruh ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Hydrogen Bonds ◽  
Two Dimensional ◽  
Multiple Hydrogen Bonds ◽  
Hydrogen Bonded

Unusual Thermal Expansion in Hydrogen Bonded Network of an Organic Salt Induced by Large Transverse Vibration of Atoms

2021 ◽  
Vol 21 (3) ◽  
pp. 1428-1433
Author(s):  
Lalita Negi ◽  
Sunil Kumar ◽  
Bhavna Dwivedi ◽  
Dinabandhu Das
Keyword(s):  
Thermal Expansion ◽  
Transverse Vibration ◽  
Organic Salt ◽  
Hydrogen Bonded

Can the thermal expansion be controlled by varying the hydrogen bond dimensionality in polymorphs?

2015 ◽  
Vol 39 (5) ◽  
pp. 3345-3348 ◽  
Author(s):  
Viswanadha G. Saraswatula ◽  
Suman Bhattacharya ◽  
Binoy K. Saha
Keyword(s):  
Hydrogen Bond ◽  
Thermal Expansion ◽  
Higher Dimensional ◽  
Lower Dimensional ◽  
Hydrogen Bonded

A higher dimensional (1-D) hydrogen bonded form shows smaller thermal expansion than a lower dimensional (0-D) hydrogen bonded form of 2-butynoic acid.

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