Series of Cd(II) Metal–Organic Frameworks Based on a Flexible Tripodal Ligand and Polycarboxylate Acids: Syntheses, Structures, and Photoluminescent Properties

2012 ◽  
Vol 12 (5) ◽  
pp. 2435-2444 ◽  
Author(s):  
Xianjuan Wang ◽  
Yanhua Liu ◽  
Chunying Xu ◽  
Qianqian Guo ◽  
Hongwei Hou ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Tripodal Ligand ◽  
Metal Organic

Zinc(ii) and cadmium(ii) metal–organic frameworks with 4-imidazole containing tripodal ligand: sorption and anion exchange properties

2014 ◽  
Vol 43 (16) ◽  
pp. 6012 ◽  
Author(s):  
Shui-Sheng Chen ◽  
Peng Wang ◽  
Satoshi Takamizawa ◽  
Taka-aki Okamura ◽  
Min Chen ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Metal Organic Frameworks ◽  
Tripodal Ligand ◽  
Metal Organic ◽  
Exchange Properties

scholarly journals Two Lanthanide Metal–Organic Frameworks Based on Semi-Rigid T-Shaped Tricarboxylate Ligand: Syntheses, Structures, and Properties

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 868
Author(s):  
Yun-Shan Xue ◽  
Zhuo-Lin Chen ◽  
Youzhen Dong ◽  
Wei-Wei Cheng
Keyword(s):  
Near Infrared ◽  
Metal Organic Frameworks ◽  
Infrared Emission ◽  
Tripodal Ligand ◽  
Structures And Properties ◽  
3D Network ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Near Infrared Emission ◽  
Solvothermal Conditions

By using a semi-rigid tripodal ligand 5-(4-carboxybenzyloxy)isophthalic acid (H3L) and lanthanide metal ions (Nd3+, Tb3+), two novel lanthanide metal–organic frameworks, namely, {[Nd2L2(DMF)4] DMF}n (1), and {TbL(DMF)(H2O)}n (2), were synthesized under mild solvothermal conditions and structurally characterized by X-ray single crystal diffraction. Compounds 1 and 2 are isostructural, in which L3– ligands linked dinuclear lanthanide metal–carboxylate units to form non-interpenetrated 3D network with (3,6)-connected topology. Luminescent investigations reveal that compound 1 displays the near-infrared emission at room temperature, and compound 2 can be employed as selective probe for Cr2O72− anion in aqueous solution based on luminescence quenching. Moreover, compound 2 exhibits catalytic activity for cyclo-addition of CO2 and epoxides under relatively mild conditions.

Metal–organic frameworks with oxazoline-containing tripodal ligand: structure changes via reaction medium and metal-to-ligand ratio

CrystEngComm ◽  
2010 ◽  
Vol 12 (12) ◽  
pp. 4328 ◽  
Author(s):  
Yong-Qing Huang ◽  
Zhong-Liang Shen ◽  
Xia-Ying Zhou ◽  
Taka-aki Okamura ◽  
Zhi Su ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Reaction Medium ◽  
Tripodal Ligand ◽  
Ligand Ratio ◽  
Ligand Structure ◽  
Structure Changes ◽  
Metal Organic

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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