Four metal–organic frameworks based on a semirigid tripodal ligand and different secondary building units: structures and electrochemical performance

CrystEngComm ◽  
2016 ◽  
Vol 18 (36) ◽  
pp. 6841-6848 ◽  
Author(s):  
Xiao-Ming Lin ◽  
Ji-Liang Niu ◽  
Dan-Ni Chen ◽  
Yan-Na Lu ◽  
Gang Zhang ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Metal Organic Frameworks ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

ChemInform Abstract: Secondary Building Units, Nets and Bonding in the Chemistry of Metal-Organic Frameworks

ChemInform ◽  
2009 ◽  
Vol 40 (29) ◽  
Author(s):  
David J. Tranchemontagne ◽  
Jose L. Mendoza-Cortes ◽  
Michael O'Keeffe ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

Zinc(ii) and cadmium(ii) metal–organic frameworks with 4-imidazole containing tripodal ligand: sorption and anion exchange properties

2014 ◽  
Vol 43 (16) ◽  
pp. 6012 ◽  
Author(s):  
Shui-Sheng Chen ◽  
Peng Wang ◽  
Satoshi Takamizawa ◽  
Taka-aki Okamura ◽  
Min Chen ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Metal Organic Frameworks ◽  
Tripodal Ligand ◽  
Metal Organic ◽  
Exchange Properties

Intrinsic White‐Light‐Emitting Metal–Organic Frameworks with Structurally Deformable Secondary Building Units

2019 ◽  
Vol 58 (23) ◽  
pp. 7818-7822 ◽  
Author(s):  
Chengdong Peng ◽  
Xueling Song ◽  
Jinlin Yin ◽  
Guiyang Zhang ◽  
Honghan Fei
Keyword(s):  
White Light ◽  
Metal Organic Frameworks ◽  
Light Emitting ◽  
Secondary Building Units ◽  
Metal Organic

Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission

2020 ◽  
Vol 8 (4) ◽  
pp. 1374-1379 ◽  
Author(s):  
Yutong Wang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Xuelian Xin ◽  
Xiurong Zhang ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Earth Metal ◽  
White Light Emission ◽  
One Dimensional ◽  
1D Chain ◽  
Secondary Building Units ◽  
Metal Organic

An unprecedented three-dimensional (3D) (3,4,5)-czkf topological framework (UPC-38) with one-dimensional (1D) chain secondary building units exhibits strong white light emission.

Ammonia Capture within Isoreticular Metal–Organic Frameworks with Rod Secondary Building Units

2019 ◽  
Vol 1 (4) ◽  
pp. 476-480 ◽  
Author(s):  
Shinya Moribe ◽  
Zhijie Chen ◽  
Selim Alayoglu ◽  
Zoha H. Syed ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

Four novel Co(II) metal-organic frameworks based on semi-rigid ligand and their secondary building units transformation

2019 ◽  
Vol 1197 ◽  
pp. 87-95 ◽  
Author(s):  
Lili Fan ◽  
Xiaobin Liu ◽  
Liangliang Zhang ◽  
Xia Kong ◽  
Zhenyu Xiao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

scholarly journals Two-dimensional metal-organic frameworks containing linear dicarboxylates

2006 ◽  
Vol 62 (5) ◽  
pp. 808-814 ◽  
Author(s):  
Samuel M. Hawxwell ◽  
Harry Adams ◽  
Lee Brammer
Keyword(s):  
Dicarboxylic Acid ◽  
Solvothermal Synthesis ◽  
Interplanar Spacing ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Gas Molecules ◽  
Solvent Molecules

The solvothermal synthesis of four two-dimensional metal-organic frameworks containing linear dicarboxylic acids as ligands for ZnII centres is described. Zn(BDC)(DMF) [(1) where BDC = benzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide] adopts a common paddlewheel motif leading to a 44 grid network, whereas Zn3(BDC)3(EtOH)2 (2), Zn3(BDC)3(H2O)2·4DMF (3) and Zn3(BPDC)3(DMF)2·4DMF (4) each form networks with the relatively uncommon 36 topology based upon Zn3(O2CR)6 secondary building units. All contain coordinated solvent molecules, namely DMF [(1) and (4)], ethanol (2) or H2O (3). Comparison of structures (2) and (3) illustrates a clay-like flexibility in interplanar spacing which sheds light on the ability of the Zn3(BDC)3 framework to undergo desolvation and uptake of small solvent and gas molecules.

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