Effect of Lanthanide Contraction on Crystal Structures of Three-Dimensional Lanthanide Based Metal–Organic Frameworks with Thiophene-2,5-Dicarboxylate and Oxalate

2011 ◽  
Vol 11 (6) ◽  
pp. 2294-2301 ◽  
Author(s):  
Jing Xu ◽  
Jianwen Cheng ◽  
Weiping Su ◽  
Maochun Hong
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Lanthanide Contraction ◽  
Metal Organic

Structural Diversity of Four Lanthanide Metal-Organic Frameworks based on 2,6-Naphthalenedicarboxylate: Synthesis, Structures and Photoluminescent Properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ana Chatenever ◽  
Joe E Matsuoka ◽  
Stanley J Wang ◽  
Beatriz Ehlke ◽  
Pierre LeMagueres ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Structural Diversity ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Linker

We report the crystal structures of four different neutral lanthanide (Ln = La, Nd, Eu and Gd) metal-organic frameworks based on the organic linker 2,6-naphthalenedicarboxylate (NDC). The materials are three-dimensional...

Negative linear compressibility in nanoporous metal-organic frameworks rationalized by the empty channel structural mechanism

2021 ◽  
Author(s):  
Francisco Colmenero
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Structural Mechanism ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Linear Compressibility

Cobalt squarate hydroxide (Co3(C4O4)2(OH)2), zinc squarate tetrahydrate (ZnC4O4·4 H2O) and titanium oxalate trioxide dihydrate (Ti2(C2O4)O3·2 H2O) are nanoporous metal-organic frameworks possessing empty channels in their crystal structures. The crystal structures...

scholarly journals Experimental investigations on the irregular synthesis of the iron(III) terephthalate metal-organic frameworks MOF-235 and MIL-101

2021 ◽  
Author(s):  
Isabelle Simonsson ◽  
Philip Gärdhagen ◽  
Moira Andrén ◽  
Pui Lam Tam ◽  
Zareen Abbas
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Experimental Investigations ◽  
Surface Areas ◽  
Metal Organic

(Fe)-MOF-235 and (Fe)-MIL-101 are two well-studied iron(III) terephthalate metal-organic frameworks (MOFs) with dissimilar crystal structures and topologies. Previously reported syntheses of the former show greatly varying surface areas, indicating a...

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