scholarly journals Water-Stable Nanoscale Zirconium-Based Metal–Organic Frameworks for the Effective Removal of Glyphosate from Aqueous Media

ACS Omega ◽  
2018 ◽  
Vol 3 (7) ◽  
pp. 7832-7839 ◽  
Author(s):  
Asha Pankajakshan ◽  
Mekhola Sinha ◽  
Anupam Anand Ojha ◽  
Sukhendu Mandal
2016 ◽  
Vol 98 ◽  
pp. 70-74
Author(s):  
Andrius Laurikėnas ◽  
Jurgis Barkauskas ◽  
Aivaras Kareiva

In this study, lanthanide elements (Ln3+) and 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid (TFBDC) based metal-organic frameworks (MOFs) were synthesized by precipitation and diffusion-controlled precipitation methods. Powders insoluble in aqueous media and polar solvents were obtained. The microstructure and properties of Ln3+ MOFs were evaluated and discussed. X-ray diffraction (XRD) analysis, infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and fluorescence spectroscopy (FLS) were carried out to characterize Ln3+ MOF's crystallinity, the microstructure, chemical composition and optical properties.


CrystEngComm ◽  
2020 ◽  
Vol 22 (41) ◽  
pp. 6927-6934
Author(s):  
Ruihong Guo ◽  
Lingling Gao ◽  
Jinxia Liang ◽  
Zhikai Zhang ◽  
Jie Zhang ◽  
...  

Two Cd-MOFs were solvothermally synthesized by mixed-ligand strategy. 1 has the largest adsorption selectivity for CO2. Furthermore, 1 and 2 present sensitive sensing for TNP/Fe3+ in water or soil samples.


RSC Advances ◽  
2017 ◽  
Vol 7 (11) ◽  
pp. 6691-6696 ◽  
Author(s):  
P. Asha ◽  
Mekhola Sinha ◽  
Sukhendu Mandal

Water stable zirconium based MOFs are used for the efficient adsorptive removal of chemical warfare agent simulants from aqueous medium.


2017 ◽  
Vol 245 ◽  
pp. 305-313 ◽  
Author(s):  
Kowsalya Vellingiri ◽  
Danil W. Boukhvalov ◽  
Sudhir Kumar Pandey ◽  
Akash Deep ◽  
Ki-Hyun Kim

2018 ◽  
Vol 514 ◽  
pp. 234-239 ◽  
Author(s):  
Xudong Zhao ◽  
Yanan Wei ◽  
Huifang Zhao ◽  
Zhuqing Gao ◽  
Yuezhong Zhang ◽  
...  

2021 ◽  
Vol 35 (1) ◽  
pp. 119-128
Author(s):  
S. Iram ◽  
T. Khurshid ◽  
S. Latif ◽  
M. Imran ◽  
F. Kanwal ◽  
...  

Metal organic frameworks are formed by the three-dimensional linkage of metal cores and organic linkers. In this work, bismuth-based metal organic framework (Bi-MOF) has been synthesized by using 5-hydroxyisophthalic acid (H2HIA) as linker via hydrothermal method. The said MOF was structurally characterized by UV/Vis, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), 1H NMR, energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA) and X-ray diffraction technique. This MOF showed highly porous structure with surface area 1096 m2/g as determined by BET analysis. A model batch adsorption experiment was performed to evaluate the efficiency of methylene blue (MB) dye removal from aqueous media. It was found that monolayer adsorption capacity calculated from the Langmuir isotherm was 0.6240 mg/g. Bi-MOF was also screened for its antibacterial and luminescent behavior.                     KEY WORDS: Bismuth, Metal-organic Frameworks, Luminescence, Sorption   Bull. Chem. Soc. Ethiop. 2021, 35(1), 119-128. DOI: https://dx.doi.org/10.4314/bcse.v35i1.10


Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1481
Author(s):  
Yajie Chen ◽  
Xue Bai ◽  
Zhengfang Ye

Heavy metals are inorganic pollutants which pose a serious threat to human and environmental safety, and their effective removal is becoming an increasingly urgent issue. Metal–organic frameworks (MOFs) are a novel group of crystalline porous materials, which have proven to be promising adsorbents because of their extremely high surface areas, optimizable pore volumes and pore size distributions. This study is a systematic review of the recent research on the removal of several major heavy metal ions by MOFs. Based on the different structures of MOFs, varying adsorption capacity can be achieved, ranging from tens to thousands of milligrams per gram. Many MOFs have shown a high selectivity for their target metal ions. The corresponding mechanisms involved in capturing metal ions are outlined and finally, the challenges and prospects for their practical application are discussed.


2020 ◽  
Vol 41 (8) ◽  
pp. 843-850 ◽  
Author(s):  
Sungjune Kim ◽  
Jihyun Lee ◽  
Younghu Son ◽  
Minyoung Yoon

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