scholarly journals Deep Insights into Heavy Oil Upgrading Using Supercritical Water by a Comprehensive Analysis of GC, GC–MS, NMR, and SEM–EDX with the Aid of EPR as a Complementary Technical Analysis

ACS Omega ◽  
2020 ◽  
Author(s):  
Richard Djimasbe ◽  
Mikhail A. Varfolomeev ◽  
Ameen A. Al-muntaser ◽  
Chengdong Yuan ◽  
Muneer A. Suwaid ◽  
...  
2019 ◽  
Vol 152 ◽  
pp. 104569 ◽  
Author(s):  
Ramazan Oğuz Canıaz ◽  
Serhat Arca ◽  
Muzaffer Yaşar ◽  
Can Erkey

2020 ◽  
Vol 165 ◽  
pp. 104961
Author(s):  
Seungjae Sim ◽  
Won Bae Kong ◽  
Jonghyeon Kim ◽  
Jimoon Kang ◽  
Hwi-Sung Lee ◽  
...  

2017 ◽  
Vol 126 ◽  
pp. 55-64 ◽  
Author(s):  
Oxana N. Fedyaeva ◽  
Vladimir R. Antipenko ◽  
Anatoly A. Vostrikov

Author(s):  
Ashwin Raghavan ◽  
Ping He ◽  
Ahmed Ghoniem

We present the development and application of a two-phase stirred reactor model for heavy oil upgrading in the presence of supercritical water (SCW), with coupled phase-specific thermolysis reaction kinetics and multicomponent hydrocarbon water phase equilibrium. We demonstrate the inference of oil and water phase kinetics parameters for a compact lumped reaction kinetics model through the application of this model to two different sets of batch reactor experiments reported in the literature. We infer that, though SCW can suppress the formation of newer polynuclear aromatics (PNA) from distillate range species, it is broadly ineffective in deterring the combination of pre-existing PNA fragments in the oil feed. Quantification of the conversion to distillate liquids before the onset of coke formation helps arrive at a clearer conclusion on whether the use of SCW in the batch reactor leads to better product outcomes for different oil feeds and operating conditions.


2008 ◽  
Vol 51 (5) ◽  
pp. 309-314 ◽  
Author(s):  
Shinsuke Kokubo ◽  
Koji Nishida ◽  
Akinori Hayashi ◽  
Hirokazu Takahashi ◽  
Osami Yokota ◽  
...  

2011 ◽  
Vol 54 (2) ◽  
pp. 96-102
Author(s):  
Hirokazu Takahashi ◽  
Nobuyuki Hokari ◽  
Osami Yokota ◽  
Kouji Nishida ◽  
Akinori Hayashi ◽  
...  

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