scholarly journals Transport of Rhodium(III) from Chloride Media across a Polymer Inclusion Membrane Containing an Ionic Liquid Metal Ion Carrier

ACS Omega ◽  
2020 ◽  
Vol 5 (22) ◽  
pp. 12989-12995
Author(s):  
Takafumi Hanada ◽  
Mochamad Lutfi Firmansyah ◽  
Wataru Yoshida ◽  
Fukiko Kubota ◽  
Spas D. Kolev ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Metal ◽  
Metal Ion ◽  
Inclusion Membrane ◽  
Polymer Inclusion Membrane ◽  
Ion Carrier

scholarly journals Calixresorcin[4]arene-Mediated Transport of Pb(II) Ions Through Polymer Inclusion Membrane

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 285
Author(s):  
Joanna Konczyk ◽  
Wojciech Ciesielski
Keyword(s):  
Activation Energy ◽  
Transport Process ◽  
Optimal Conditions ◽  
Inclusion Membrane ◽  
Polymer Inclusion Membrane ◽  
Membrane Effect ◽  
Feed Phase ◽  
Ion Carrier ◽  
Feed Effect ◽  
Nitrate Solutions

A facilitated transport of Pb(II) through polymer inclusion membrane (PIM) containing 1,8,15,22-tetra(1-heptyl)-calixresorcin[4]arene and its tetra- and octasubstituted derivatives containing phosphoryl, thiophosphoryl or ester groups as an ion carrier was investigated. The efficiency of Pb(II) removal from aqueous nitrate solutions was considered as a function of the composition of membrane (effect of polymer, plasticizer, and carrier), feed (effect of initial metal concentration and presence of other metal ions) and stripping phases, and temperature of the process conducting. Two kinetic models were applied for the transport description. The highest Pb(II) ions removal efficiency was obtained for the membrane with tetrathiophosphorylated heptyl-calixresorcin[4]arene as an ion carrier. The activation energy value, found from Eyring plot to be equal 38.7 ± 1.3 kJ/mol, suggests that the transport process is controllable both by diffusion and chemical reaction. The competitive transport of Pb(II) over Zn(II), Cd(II), and Cr(III) ions across PIMs under the optimal conditions was also performed. It was found that the Cr(III) ions’ presence in the feed phase disturb effective re-extraction of Pb(II) ions from membrane to stripping phase. Better stability of PIM-type than SLM-type membrane was found.

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