Emerging Two-Dimensional Covalent and Coordination Polymers for Stable Lithium Metal Batteries: From Liquid to Solid

ACS Nano ◽  
2021 ◽  
Author(s):  
Jiwei Wang ◽  
Kaixi Wang ◽  
Yuxi Xu
Keyword(s):  
Coordination Polymers ◽  
Two Dimensional ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Towards Real-Time Simulation of Two-Dimensional Models for Electrodeposition/Stripping in Lithium-Metal Batteries

2021 ◽  
Vol MA2021-02 (1) ◽  
pp. 176-176
Author(s):  
Taejin Jang ◽  
Lubhani Mishra ◽  
Krishna Shah ◽  
Akshay Subramaniam ◽  
Maitri Uppaluri ◽  
...  
Keyword(s):  
Real Time ◽  
Two Dimensional ◽  
Lithium Metal ◽  
Real Time Simulation ◽  
Lithium Metal Batteries ◽  
Time Simulation ◽  
Dimensional Models

Two-dimensional materials as a stabilized interphase for the solid-state electrolyte Li10GeP2S12 in lithium metal batteries

2021 ◽  
Author(s):  
Jiachen Ma ◽  
Ruge Quhe ◽  
Zheyu Zhang ◽  
Chen Yang ◽  
Xiuying Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Two Dimensional ◽  
Lithium Metal ◽  
Solid State Electrolyte ◽  
Ion Flow ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Two Dimensional Materials ◽  
Efficient Screening

An efficient screening procedure for two-dimensional (2D) solid-electrolyte interphases (SEIs) is designed. In the concrete case, the two selected 2D SEIs (h-BN and α-BNyne) do stabilize the interface between the solid-state electrolyte Li10GeP2S12 and the lithium metal anode, blocking the electron transfer and maintaining the Li-ion flow.

Towards Real-Time Simulation of Two-Dimensional Models for Electrodeposition/Stripping in Lithium-Metal Batteries

2021 ◽  
Vol 104 (1) ◽  
pp. 131-152
Author(s):  
Taejin Jang ◽  
Lubhani Mishra ◽  
Krishna Shah ◽  
Akshay Subramaniam ◽  
Maitri Uppaluri ◽  
...  
Keyword(s):  
Real Time ◽  
Two Dimensional ◽  
Lithium Metal ◽  
Real Time Simulation ◽  
Lithium Metal Batteries ◽  
Time Simulation ◽  
Dimensional Models

Two-Dimensional Silicon/Carbon from Commercial Alloy and CO2 for Lithium Storage and Flexible Ti3C2Tx MXene-Based Lithium–Metal Batteries

ACS Nano ◽  
2020 ◽  
Vol 14 (12) ◽  
pp. 17574-17588
Author(s):  
Yongling An ◽  
Yuan Tian ◽  
Yuchan Zhang ◽  
Chuanliang Wei ◽  
Liwen Tan ◽  
...  
Keyword(s):  
Two Dimensional ◽  
Lithium Metal ◽  
Commercial Alloy ◽  
Lithium Storage ◽  
Lithium Metal Batteries ◽  
Silicon Carbon

scholarly journals Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2468
Author(s):  
Hui Zhan ◽  
Mengjun Wu ◽  
Rui Wang ◽  
Shuohao Wu ◽  
Hao Li ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Specific Capacity ◽  
Sio2 Nanoparticles ◽  
Inorganic Materials ◽  
Solid Polymer Electrolytes ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries

Composite polymer electrolytes (CPEs) incorporate the advantages of solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs), which have shown huge potential in the application of safe lithium-metal batteries (LMBs). Effectively avoiding the agglomeration of inorganic fillers in the polymer matrix during the organic–inorganic mixing process is very important for the properties of the composite electrolyte. Herein, a partial cross-linked PEO-based CPE was prepared by porous vinyl-functionalized silicon (p-V-SiO2) nanoparticles as fillers and poly (ethylene glycol diacrylate) (PEGDA) as cross-linkers. By combining the mechanical rigidity of ceramic fillers and the flexibility of PEO, the as-made electrolyte membranes had excellent mechanical properties. The big special surface area and pore volume of nanoparticles inhibited PEO recrystallization and promoted the dissolution of lithium salt. Chemical bonding improved the interfacial compatibility between organic and inorganic materials and facilitated the homogenization of lithium-ion flow. As a result, the symmetric Li|CPE|Li cells could operate stably over 450 h without a short circuit. All solid Li|LiFePO4 batteries were constructed with this composite electrolyte and showed excellent rate and cycling performances. The first discharge-specific capacity of the assembled battery was 155.1 mA h g−1, and the capacity retention was 91% after operating for 300 cycles at 0.5 C. These results demonstrated that the chemical grafting of porous inorganic materials and cross-linking polymerization can greatly improve the properties of CPEs.

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