Three-Dimensional Nanoporous Iron Nitride Film as an Efficient Electrocatalyst for Water Oxidation

ACS Catalysis ◽  
2017 ◽  
Vol 7 (3) ◽  
pp. 2052-2057 ◽  
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Fang Yu ◽  
Haiqing Zhou ◽  
Zhuan Zhu ◽  
Jingying Sun ◽  
Ran He ◽  
...  
1997 ◽  
Vol 96 (1) ◽  
pp. 34-38 ◽  
Author(s):  
Li Guibin ◽  
Li Guoqing ◽  
Lei Minkai ◽  
Liu Bangzhi

2019 ◽  
Vol 68 (11) ◽  
pp. 118101
Author(s):  
Qi-Hai Lu ◽  
Xiao-Li Tang ◽  
Yu-Zhe Song ◽  
Xian-Wei Zuo ◽  
Gen-Liang Han ◽  
...  

2000 ◽  
Vol 45 (20) ◽  
pp. 3367-3373 ◽  
Author(s):  
Takuya Goto ◽  
Ryoji Obata ◽  
Yasuhiko Ito

ISIAME 2012 ◽  
2012 ◽  
pp. 331-335
Author(s):  
Yasuhiro Yamada ◽  
Ryo Usui ◽  
Yoshio Kobayashi

2012 ◽  
Vol 219 (1-3) ◽  
pp. 13-17 ◽  
Author(s):  
Yasuhiro Yamada ◽  
Ryo Usui ◽  
Yoshio Kobayashi

1990 ◽  
Vol 2 (3) ◽  
pp. 263-268 ◽  
Author(s):  
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M. M. Amini ◽  
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O. A. Pringle ◽  
Gary J. Long ◽  
...  

Shinku ◽  
1995 ◽  
Vol 38 (3) ◽  
pp. 350-353 ◽  
Author(s):  
Yukihiro HAYASHI ◽  
Shigeyoki MORINAGA

2016 ◽  
Vol 2 (10) ◽  
pp. e1600495 ◽  
Author(s):  
Bo-Quan Li ◽  
Cheng Tang ◽  
Hao-Fan Wang ◽  
Xiao-Lin Zhu ◽  
Qiang Zhang

Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot survive. We propose a preoxidization coupled electrodeposition strategy in which Co2+ is preoxidized to Co3+ through cobalt Fenton reaction in aqueous solution, whereas the reductive nickel framework is well maintained during the sequential annealing under nonoxidative atmosphere. The in situ–generated Co3+ is inherited into oxidized perovskites deposited on 3D nickel foam, rendering the monolithic perovskite electrocatalysts with extraordinary OER performance with an ultralow overpotential of 350 mV required for 10 mA cm−2, a very small Tafel slope of 59 mV dec−1, and superb stability in 0.10 M KOH. Therefore, we inaugurate a unique strategy for in situ hybridization of oxidative active phase with reductive framework, affording superb reactivity of perovskite electrocatalyst for efficient water oxidation.


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