Highly Durable C2 Hydrocarbon Production via the Oxidative Coupling of Methane Using a BaFe0.9Zr0.1O3−δ Mixed Ionic and Electronic Conducting Membrane and La2O3 Catalyst

ACS Catalysis ◽  
2021 ◽  
pp. 3638-3661
Author(s):  
Georgios Dimitrakopoulos ◽  
Bonjae Koo ◽  
Bilge Yildiz ◽  
Ahmed F. Ghoniem
Keyword(s):  
Oxidative Coupling ◽  
Oxidative Coupling Of Methane ◽  
Hydrocarbon Production ◽  
C2 Hydrocarbon

scholarly journals Oxidative Coupling of Methane over YSZ Support Catalysts for Application in C2 Hydrocarbon Production

2015 ◽  
Vol 19 (4) ◽  
pp. 1-11 ◽  
Author(s):  
Weerinda Appamana ◽  
Kridsada Khammona ◽  
Wisitsree Wiyaratn ◽  
Suttichai Assabumrungrat
Keyword(s):  
Oxidative Coupling ◽  
Oxidative Coupling Of Methane ◽  
Hydrocarbon Production ◽  
C2 Hydrocarbon

Simulation of Oxidative Coupling of Methane in Solid Oxide Fuel Cell Type Reactor for C2 Hydrocarbon and Electricity Co-Generation

2005 ◽  
Vol 38 (10) ◽  
pp. 841-848 ◽  
Author(s):  
Worapon Kiatkittipong ◽  
Shigeo Goto ◽  
Tomohiko Tagawa ◽  
Suttichai Assabumrungrat ◽  
Piyasan Praserthdam
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Oxidative Coupling ◽  
Oxidative Coupling Of Methane ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Cell Type ◽  
Type Reactor ◽  
C2 Hydrocarbon

scholarly journals Identification of the structure of the Bi promoted Pt non-oxidative coupling of methane catalyst: a nanoscale Pt3Bi intermetallic alloy

2019 ◽  
Vol 9 (6) ◽  
pp. 1349-1356 ◽  
Author(s):  
Johnny Zhu Chen ◽  
Zhenwei Wu ◽  
Xiaoben Zhang ◽  
Slgi Choi ◽  
Yang Xiao ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Oxidative Coupling Of Methane ◽  
Intermetallic Alloy ◽  
Alloy Catalyst

Identification of a Pt3Bi nanoscale, surface intermetallic alloy catalyst for non-oxidative coupling of methane (NOCM).

Catalytic performance of Na-Mn2O3-based catalysts towards oxidative coupling of methane

2021 ◽  
Author(s):  
P. Saychu ◽  
M. Thanasiriruk ◽  
C. Khajonvittayakul ◽  
R. Viratikul ◽  
V. Tongnan ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Catalytic Performance ◽  
Oxidative Coupling Of Methane

scholarly journals Nanosheet-Like Ho2O3 and Sr-Ho2O3 Catalysts for Oxidative Coupling of Methane

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 388
Author(s):  
Yuqiao Fan ◽  
Changxi Miao ◽  
Yinghong Yue ◽  
Weiming Hua ◽  
Zi Gao
Keyword(s):  
Oxidative Coupling ◽  
Temperature Programmed Desorption ◽  
Oxidative Coupling Of Methane ◽  
Molar Ratio ◽  
Impregnation Method ◽  
Oxygen Species ◽  
N2 Adsorption ◽  
Basic Sites ◽  
Chemisorbed Oxygen ◽  
Temperature Programmed

In this work, Ho2O3 nanosheets were synthesized by a hydrothermal method. A series of Sr-modified Ho2O3 nanosheets (Sr-Ho2O3-NS) with a Sr/Ho molar ratio between 0.02 and 0.06 were prepared via an impregnation method. These catalysts were characterized by several techniques such as XRD, N2 adsorption, SEM, TEM, XPS, O2-TPD (temperature-programmed desorption), and CO2-TPD, and they were studied with respect to their performances in the oxidative coupling of methane (OCM). In contrast to Ho2O3 nanoparticles, Ho2O3 nanosheets display greater CH4 conversion and C2-C3 selectivity, which could be related to the preferentially exposed (222) facet on the surface of the latter catalyst. The incorporation of small amounts of Sr into Ho2O3 nanosheets leads to a higher ratio of (O− + O2−)/O2− as well as an enhanced amount of chemisorbed oxygen species and moderate basic sites, which in turn improves the OCM performance. The optimal catalytic behavior is achievable on the 0.04Sr-Ho2O3-NS catalyst with a Sr/Ho molar ratio of 0.04, which gives a 24.0% conversion of CH4 with 56.7% selectivity to C2-C3 at 650 °C. The C2-C3 yield is well correlated with the amount of moderate basic sites present on the catalysts.

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