Laser Synthesis of Carbonaceous TiO2 from Metal–Organic Frameworks: Optimum Support for Pd Nanoparticles for C–C Cross-Coupling Reactions

2018 ◽  
Vol 1 (9) ◽  
pp. 4852-4862 ◽  
Author(s):  
Julian A. Bobb ◽  
Amr Awad Ibrahim ◽  
M. Samy El-Shall
Keyword(s):  
Metal Organic Frameworks ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Coupling Reactions ◽  
Laser Synthesis ◽  
Cross Coupling Reactions ◽  
Metal Organic

scholarly journals Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry

Inorganics ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 27
Author(s):  
Fan Chen ◽  
Hannah F. Drake ◽  
Liang Feng ◽  
Joshua A. Powell ◽  
Kun-Yu Wang ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Structural Design ◽  
Gas Adsorption ◽  
Metal Cluster ◽  
Metal Organic Frameworks ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Metal Organic ◽  
Organometallic Transformations

Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many decades. Through the years, organometallic chemistry has been incorporated into functional MOF construction for diverse applications. Here, we will focus on how organometallic chemistry is applied in MOF design and modifications from linker-centric and metal-cluster-centric perspectives, respectively. Through structural design, MOFs can function as a tailorable platform for traditional organometallic transformations, including reaction of alkenes, cross-coupling reactions, and C–H activations. Besides, an overview will be made on other application categories of organometallic MOFs, such as gas adsorption, magnetism, quantum computing, and therapeutics.

scholarly journals Palladium-scavenging self-assembled hybrid hydrogels – reusable highly-active green catalysts for Suzuki–Miyaura cross-coupling reactions

2018 ◽  
Vol 9 (46) ◽  
pp. 8673-8681 ◽  
Author(s):  
Petr Slavík ◽  
Dustin W. Kurka ◽  
David K. Smith
Keyword(s):  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Cross Coupling Reactions ◽  
Highly Active ◽  
Hybrid Hydrogels ◽  
Self Assembled

From waste to wealth – a self-assembled hydrogel remediates palladium from solution down to sub-ppm levels, and the resulting gel, which has embedded Pd nanoparticles, acts as a green and efficient catalyst for Suzuki–Miyaura cross-coupling reactions.

Dendrimer-encapsulated Pd nanoparticles as catalysts for C–C cross-couplings in flow microreactors

2015 ◽  
Vol 13 (17) ◽  
pp. 4953-4959 ◽  
Author(s):  
Roberto Ricciardi ◽  
Jurriaan Huskens ◽  
Willem Verboom
Keyword(s):  
Continuous Flow ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Flow Microreactors

Dendrimer-encapsulated Pd nanoparticles anchored within continuous flow microreactors are efficient for C–C cross-coupling reactions. This is witnessed by the good catalytic performance for the Heck–Cassar and Suzuki–Miyaura couplings.

scholarly journals Poly(o-aminothiophenol)-stabilized Pd nanoparticles as efficient heterogenous catalysts for Suzuki cross-coupling reactions

RSC Advances ◽  
2017 ◽  
Vol 7 (74) ◽  
pp. 47104-47110 ◽  
Author(s):  
Yuan Chen ◽  
Minggui Wang ◽  
Long Zhang ◽  
Yan Liu ◽  
Jie Han
Keyword(s):  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
One Step ◽  
Excellent Catalytic Performance

Poly(o-aminothiophenol)-stabilized Pd nanoparticles have been obtained through a facile one-step route, which exhibit excellent catalytic performance in Suzuki cross-coupling reactions.

The effect of external magnetic fields on the catalytic activity of Pd nanoparticles in Suzuki cross-coupling reactions

Nanoscale ◽  
2016 ◽  
Vol 8 (15) ◽  
pp. 8355-8362 ◽  
Author(s):  
Lei Gao ◽  
Changlai Wang ◽  
Ren Li ◽  
Ran Li ◽  
Qianwang Chen
Keyword(s):  
Catalytic Activity ◽  
Magnetic Fields ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Coupling Reactions ◽  
Cross Coupling Reactions
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