Flowerlike Ti-Doped MoO3 Conductive Anode Fabricated by a Novel NiTi Dealloying Method: Greatly Enhanced Reversibility of the Conversion and Intercalation Reaction

2020 ◽  
Vol 12 (7) ◽  
pp. 8240-8248 ◽  
Author(s):  
Yu Yan ◽  
Shaobo Li ◽  
Bin Yuan ◽  
Renzong Hu ◽  
Lichun Yang ◽  
...  
Keyword(s):  
Intercalation Reaction

Soft Chemical Routes to Heterostructured High-Tc Superconducting Materials

MRS Bulletin ◽  
2000 ◽  
Vol 25 (9) ◽  
pp. 32-39 ◽  
Author(s):  
Jin-Ho Choy ◽  
Soon-Jae Kwon ◽  
Seong-Ju Hwang ◽  
Eue-Soon Jang
Keyword(s):  
Solid State ◽  
High Performance ◽  
Inorganic Compounds ◽  
Rechargeable Batteries ◽  
Host Lattice ◽  
Inorganic Materials ◽  
Solid State Reactions ◽  
Metal Chalcogenides ◽  
Structural Anisotropy ◽  
Intercalation Reaction

Recently, inorganic/inorganic and organic/inorganic heterostructured materials have attracted considerable research interest, due to their unusual physicochemical properties, which cannot be achieved by conventional solid-state reactions. In order to develop new hybrid materials, various synthetic approaches, such as vacuum deposition, Langmuir–Blodgett films, selfassembly, and intercalation techniques, have been explored. Among them, the intercalation reaction technique—that is, the reversible insertion of guest species into the two-dimensional host lattice—is expected to be one of the most effective tools for preparing new layered heterostructures because this process can provide a soft chemical way of hybridizing inorganic/inorganic, organic/inorganic, or biological/inorganic compounds. In fact, the intercalation/deintercalation process allows us to design high-performance materials in a solution at ambient temperature and pressure, just as “soft solution processing” provides a simple and economical route for advanced inorganic materials by means of an environmentally benign, lowenergy method. These unique advantages of the intercalation technique have led to its wide application to diverse fields of the solid-state sciences, namely, secondary (rechargeable) batteries, electrochromic systems, oxidation–reduction catalysts, separating agents, sorbents, and so on. Through these extensive studies, many kinds of low-dimensional compounds have been developed as host materials for the intercalation reaction, including graphite, transition-metal chalcogenides, transitionmetal oxides, aluminosilicates, metal phosphates, metal chalcogenohalides, and so on. Recently, the area of intercalation chemistry has been extended to high-Tc superconducting copper oxides, resulting in remarkable structural anisotropy.

Observation of combination displacement/intercalation reaction in aqueous zinc-ion battery

2019 ◽  
Vol 18 ◽  
pp. 10-14 ◽  
Author(s):  
Lutong Shan ◽  
Yongqiang Yang ◽  
Wanying Zhang ◽  
Huijie Chen ◽  
Guozhao Fang ◽  
...  
Keyword(s):  
Zinc Ion ◽  
Intercalation Reaction

Intercalation Reaction

2016 ◽  
Author(s):  
J. Alemán ◽  
A. V. Chadwick ◽  
J. He ◽  
M. Hess ◽  
K. Horie ◽  
...  
Keyword(s):  
Intercalation Reaction

Effect of Preparation Parameters on the Structure and Property of Montmorillonite/Alkylammonium Complexes

2010 ◽  
Vol 158 ◽  
pp. 97-105
Author(s):  
Xian Jun Lu ◽  
Jun Qiu ◽  
Yu Qin Liu ◽  
Ping Chen
Keyword(s):  
Retention Time ◽  
Layer Structure ◽  
Structure And Property ◽  
Intercalation Reaction ◽  
Maximum Value ◽  
Interlayer Structure ◽  
Adsorption Amount

A series of montmorillonite/alkylammonium complexes were prepared by the intercalation reaction between montmorillonite and Octadecyltrimethylammonium chloride (OTA). The effects of OTA dosage and intercalation duration on the structure and gelating properties of the complexes were investigated. And, the correlation between the structure of complexes and their gel viscosities were discussed. Results indicate that the OTA dosage and retention time have remarkable influence on the structure and gelating properties of montmorillonite/alkylammonium complexes, and the gelating properties also relates to the arrangement of the alkylammonium molecules in the interlayers of montmorillonite. Along with the increase of the OTA dosage under the same retentation time, both the d001 value of the montmorillonite/alkylammonium complexes and the adsorption amount of OTA increase to some extent, and the layer structure of the complex tends to show an interstratification structure. However, maximum gel viscosity of the complex was obtained at a moderate OTA dosage of 1.1~1.3CEC. Along with the increase of the retentation time, the adsorption amount of the OTA shows little variations, but the interlayer structure of the complex prepared under longer retention time tends to form a stable monolayer structure from an unstable interstratification structure under shorter retention time, and the gel viscosity of the complex increases gradually to the maximum value.

A reversible conversion and intercalation reaction material for Li ion battery cathode

2016 ◽  
Vol 180 ◽  
pp. 260-263 ◽  
Author(s):  
Yongqiang Shen ◽  
Xianyou Wang ◽  
Hai Hu ◽  
Miaoling Jiang ◽  
Shuangying Wei ◽  
...  
Keyword(s):  
Li Ion Battery ◽  
Intercalation Reaction ◽  
Li Ion
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