Comparative Analysis of Aqueous Binders for High-Energy Li-Rich NMC as a Lithium-Ion Cathode and the Impact of Adding Phosphoric Acid

2018 ◽  
Vol 10 (20) ◽  
pp. 17214-17222 ◽  
Author(s):  
Arefeh Kazzazi ◽  
Dominic Bresser ◽  
Agnese Birrozzi ◽  
Jan von Zamory ◽  
Maral Hekmatfar ◽  
...  
Keyword(s):  
Comparative Analysis ◽  
Phosphoric Acid ◽  
Lithium Ion ◽  
High Energy ◽  
The Impact

scholarly journals Performance Analysis of Indentation Punch on High Energy Lithium Pouch Cells and Simulated Model Improvement

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1971
Author(s):  
Lihua Ye ◽  
Muhammad Muzamal Ashfaq ◽  
Aiping Shi ◽  
Syyed Adnan Raheel Shah ◽  
Yefan Shi
Keyword(s):  
Short Circuit ◽  
Lithium Ion ◽  
Mechanical Deformation ◽  
High Energy ◽  
State Of Charge ◽  
Punch Test ◽  
Short Course ◽  
Model Cell ◽  
The Impact

In this research, the aim relates to the material characterization of high-energy lithium-ion pouch cells. The development of appropriate model cell behavior is intended to simulate two scenarios: the first is mechanical deformation during a crash and the second is an internal short circuit in lithium-ion cells during the actual effect scenarios. The punch test has been used as a benchmark to analyze the effects of different state of charge conditions on high-energy lithium-ion battery cells. This article explores the impact of three separate factors on the outcomes of mechanical punch indentation experiments. The first parameter analyzed was the degree of prediction brought about by experiments on high-energy cells with two different states of charge (greater and lesser), with four different sizes of indentation punch, from the cell’s reaction during the indentation effects on electrolyte. Second, the results of the loading position, middle versus side, are measured at quasi-static speeds. The third parameter was the effect on an electrolyte with a different state of charge. The repeatability of the experiments on punch loading was the last test function analyzed. The test results of a greater than 10% state of charge and less than 10% state of charge were compared to further refine and validate this modeling method. The different loading scenarios analyzed in this study also showed great predictability in the load-displacement reaction and the onset short circuit. A theoretical model of the cell was modified for use in comprehensive mechanical deformation. The overall conclusion found that the loading initiating the cell’s electrical short circuit is not instantaneously instigated and it is subsequently used to process the development of a precise and practical computational model that will reduce the chances of the internal short course during the crash.

scholarly journals Energy Evaluation of a PV-Based Test Facility for Assessing Future Self-Sufficient Buildings

Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 329
Author(s):  
Angela Amato ◽  
Matteo Bilardo ◽  
Enrico Fabrizio ◽  
Valentina Serra ◽  
Filippo Spertino
Keyword(s):  
Real Life ◽  
Lithium Ion ◽  
Energy Performance ◽  
High Energy ◽  
Test Facility ◽  
Local Energy ◽  
Community Concept ◽  
Energy Sharing ◽  
The Impact ◽  
Photovoltaic Generators

In recent years, investigations on advanced technological solutions aiming to achieve high-energy performance in buildings have been carried out by research centers and universities, in accordance with the reduction in buildings’ energy consumption required by European Union. However, even if the research and design of new technological solutions makes it possible to achieve the regulatory objectives, a building’s performance during operation deviates from simulations. To deepen this topic, interesting studies have focused on testing these solutions on full-scale facilities used for real-life activities. In this context, a test facility will be built in the university campus of Politecnico di Torino (Italy). The facility has been designed to be an all-electric nearly Zero Energy Building (nZEB), where heating and cooling demand will be fulfilled by an air-source heat pump and photovoltaic generators will meet the energy demand. In this paper, the facility energy performance is evaluated through a dynamic simulation model. To improve energy self-sufficiency, the integration of lithium-ion batteries in a HVAC system is investigated and their storage size is optimized. Moreover, the facility has been divided into three units equipped with independent electric systems with the aim of estimating the benefits of local energy sharing. The simulation results clarify that the facility meets the expected energy performance, and that it is consistent with a typical European nZEB. The results also demonstrate that the local use of photovoltaic energy can be enhanced thanks to batteries and local energy sharing, achieving a greater independence from the external electrical grid. Furthermore, the analysis of the impact of the local energy sharing makes the case study of particular interest, as it represents a simplified approach to the energy community concept. Thus, the results clarify the academic potential for this facility, in terms of both research and didactic purposes.

scholarly journals Cation-disordered rocksalt transition metal oxides and oxyfluorides for high energy lithium-ion cathodes

2020 ◽  
Vol 13 (2) ◽  
pp. 345-373 ◽  
Author(s):  
R. J. Clément ◽  
Z. Lun ◽  
G. Ceder
Keyword(s):  
Energy Density ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Short Range ◽  
Short Range Order ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Detailed Understanding ◽  
The Impact

Cation-disordered rocksalt oxides and oxyfluorides are promising high energy density lithium-ion cathodes, yet require a detailed understanding of the impact of disorder and short-range order on the structural and electrochemical properties.

scholarly journals Effect of Size and Shape on Electrochemical Performance of Nano-Silicon-Based Lithium Battery

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 307
Author(s):  
Caroline Keller ◽  
Antoine Desrues ◽  
Saravanan Karuppiah ◽  
Eléa Martin ◽  
John Alper ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Coulombic Efficiency ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Specific Area ◽  
High Energy ◽  
Transport Pathways ◽  
Size And Shape ◽  
Nano Silicon ◽  
The Impact

Silicon is a promising material for high-energy anode materials for the next generation of lithium-ion batteries. The gain in specific capacity depends highly on the quality of the Si dispersion and on the size and shape of the nano-silicon. The aim of this study is to investigate the impact of the size/shape of Si on the electrochemical performance of conventional Li-ion batteries. The scalable synthesis processes of both nanoparticles and nanowires in the 10–100 nm size range are discussed. In cycling lithium batteries, the initial specific capacity is significantly higher for nanoparticles than for nanowires. We demonstrate a linear correlation of the first Coulombic efficiency with the specific area of the Si materials. In long-term cycling tests, the electrochemical performance of the nanoparticles fades faster due to an increased internal resistance, whereas the smallest nanowires show an impressive cycling stability. Finally, the reversibility of the electrochemical processes is found to be highly dependent on the size/shape of the Si particles and its impact on lithiation depth, formation of crystalline Li15Si4 in cycling, and Li transport pathways.

scholarly journals A Review of Pulsed Current Technique for Lithium-ion Batteries

Energies ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2458 ◽  
Author(s):  
Xinrong Huang ◽  
Yuanyuan Li ◽  
Anirudh Budnar Acharya ◽  
Xin Sui ◽  
Jinhao Meng ◽  
...  
Keyword(s):  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Impact Factors ◽  
Future Research ◽  
Pulsed Current ◽  
Li Ion Batteries ◽  
Li Ion ◽  
Discharging Capacity ◽  
The Impact

Lithium-ion (Li-ion) batteries have been competitive in Electric Vehicles (EVs) due to their high energy density and long lifetime. However, there are still issues, which have to be solved, related to the fast-charging capability of EVs. The pulsed current charging technique is expected to improve the lifetime, charging speed, charging/discharging capacity, and the temperature rising of Li-ion batteries. However, the impact of the pulsed current parameters (i.e., frequency, duty cycle, and magnitude) on characteristics of Li-ion batteries has not been fully understood yet. This paper summarizes the existing pulsed current modes, which are positive Pulsed Current Mode (PPC) and its five extended modes, and Negative Pulsed Current (NPC) mode and its three extended modes. An overview of the impact of pulsed current techniques on the performance of Li-ion batteries is presented. Then the main impact factors of the PPC strategy and the NPC strategy are analyzed and discussed. The weight of these impact factors on lifetime, charging speed, charging/discharging capacity, and the temperature rising of batteries is presented, which provides guidance to design advanced charging/discharging strategies as well as to determine future research gaps.

Corruption as “one‑stop‑shop”: theory and empirical analysis

2018 ◽  
pp. 32-51
Author(s):  
R. Yu. Kochnev ◽  
L. I. Polishchuk ◽  
A. Yu. Rubin
Keyword(s):  
Comparative Analysis ◽  
Business Environment ◽  
Enterprise Performance ◽  
Double Jeopardy ◽  
One Stop ◽  
The Commons ◽  
Public Production ◽  
Performance Project ◽  
The Impact ◽  
Sector Theory

We present the comparative analysis of the impact of centralized and decentralized corruption for private sector. Theory and empirical evidence point out to a “double jeopardy” of decentralized corruption which increases the burden of corruption upon private firms and weakens the incentives of bureaucracy to provide public production inputs, such as infrastructure. These outcomes are produced by simultaneous free-riding and the tragedy of the commons effects. The empirical part of the paper utilizes data of the Business Environment and Enterprise Performance project.

Assessment of small businesses activities in Ukraine

2019 ◽  
pp. 40-47
Author(s):  
Igor Ponomarenko ◽  
Kateryna Volovnenko
Keyword(s):  
Comparative Analysis ◽  
Statistical Analysis ◽  
Small Business ◽  
Small Businesses ◽  
Government Agencies ◽  
Small Enterprises ◽  
The Subject ◽  
Business Entities ◽  
The Impact ◽  
Micro Enterprises

The subject of the research is a set of approaches to the statistical analysis ofthe activities of small business entities in Ukraine, including micro-enterprises. The purpose of writing this article is to study of the features of functioningof small business entities in Ukraine. Methodology. The research methodology isto use a system-structural and comparative analysis (to study the change in thenumber of small enterprises by major components); monographic (when studyingmethods of statistical analysis of small businesses); economic analysis (when assessing the impact of small business entities on socio-economic phenomena andprocesses in Ukraine). The scientific novelty consists to determine the features ofthe functioning of small businesses in Ukraine in modern conditions. The influenceof the activities of the main socio-economic and political indicators on the activities of small enterprises in recent periods of time has been identified. It has beenestablished that there is flexibility in the development of strategies by small businesses in conditions of significant competition, which makes it possible to quicklyrespond to changing situations in specific markets. Conclusions. The use of acomprehensive statistical analysis of small businesses functioning in Ukraine willallow government agencies to develop a set of measures to optimize the activitiesof these enterprises, which ultimately will positively affect the strengthening oftheir competitiveness and will contribute to the growth of the national economicsystem.

Unemployment as an indicator of economic security in the employment sector: A regional dimension

2020 ◽  
Vol 16 (4) ◽  
pp. 715-729
Author(s):  
T.N. Savina
Keyword(s):  
Comparative Analysis ◽  
Age Groups ◽  
National Development ◽  
Federal District ◽  
Economic Security ◽  
Employment Policy ◽  
Multivariate Statistical ◽  
Band Theory ◽  
The Republic ◽  
The Impact

Subject. To achieve a high level of economic security is a key priority of national development. Employment reveals one of the most important aspects of social development of the individual that is associated with his or her needs satisfaction in the sphere of employment and is boon to economic security. Objectives. The purpose of the study is to show the impact of unemployment on economic security in employment. Methods. I apply such scientific methods as dialectical, historical and logical unity, structural and functional analysis, traditional techniques of economic analysis and synthesis. The methods of multivariate statistical and comparative analysis serve as a methodological basis of the study. To determine the indicator of unemployment, I use the band theory. Results. I underpin the growing role of employment in ensuring economic security. The paper presents a comprehensive assessment of the unemployment status and a comparative analysis of the indicator in the Republic of Mordovia, the Volga Federal District, and the Russian Federation as a whole. I identify trends in the average duration of unemployment, show the distribution of unemployed by level of education and age groups. Conclusions. The average annual unemployment rate in the Republic of Mordovia is lower than in Russia and the Volga Federal District. The findings may be useful for public authorities to substantiate their employment policy at both macro- and meso-levels, for designing programs and strategies for socio-economic development of regions and the social security doctrine, as well as in practical activities of employment services.

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