Utilizing van der Waals Slippery Interfaces to Enhance the Electrochemical Stability of Silicon Film Anodes in Lithium-Ion Batteries

2018 ◽  
Vol 10 (16) ◽  
pp. 13442-13451 ◽  
Author(s):  
Swastik Basu ◽  
Shravan Suresh ◽  
Kamalika Ghatak ◽  
Stephen F. Bartolucci ◽  
Tushar Gupta ◽  
...  
Ionics ◽  
2014 ◽  
Vol 21 (2) ◽  
pp. 579-585 ◽  
Author(s):  
Jianping Wang ◽  
Chongyun Wang ◽  
Yuanmin Zhu ◽  
Ningning Wu ◽  
Wenhuai Tian

2010 ◽  
Vol 56 (1) ◽  
pp. 372-375 ◽  
Author(s):  
Zhongsheng Wen ◽  
Meikang Cheng ◽  
Juncai Sun ◽  
Liang Wang

2019 ◽  
Vol 9 (13) ◽  
pp. 2677 ◽  
Author(s):  
Yong Liu ◽  
Haichao Wang ◽  
Keke Yang ◽  
Yingnan Yang ◽  
Junqing Ma ◽  
...  

A binder plays an important role in lithium-ion batteries (LIBs), especially for the electrode materials which have large volume expansion during charge and discharge. In this work, we designed a cross-linked polymeric binder with an esterification reaction of Sodium Carboxymethyl Cellulose (CMC) and Fumaric Acid (FA), and successfully used it in an Sb2O3 anode for LIBs. Compared with conventional binder polyvinylidene fluoride (PVDF) and CMC, the new cross-linked binder improves the electrochemical stability of the Sb2O3 anode. Specifically, with CMC-FA binder, the battery could deliver ~611.4 mAh g−1 after 200 cycles under the current density of 0.2 A g−1, while with PVDF or CMC binder, the battery degraded to 265.1 and 322.3 mAh g−1, respectively. The improved cycling performance is mainly due to that the cross-linked CMC-FA network could not only efficiently improve the contact between Sb2O3 and conductive agent, but can also buffer the large volume charge of the electrode during repeated charge/discharge cycles.


Nanoscale ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 5812-5816 ◽  
Author(s):  
Jinyun Liu ◽  
Xirong Lin ◽  
Tianli Han ◽  
Qianqian Lu ◽  
Jiawei Long ◽  
...  

Metallic germanium (Ge) as the anode can deliver a high specific capacity and high rate capability in lithium ion batteries.


2017 ◽  
Vol 19 (41) ◽  
pp. 28139-28152 ◽  
Author(s):  
S. Papović ◽  
N. Cvjetićanin ◽  
Slobodan Gadžurić ◽  
M. Bešter-Rogač ◽  
M. Vraneš

The effect of C(2) methylation of imidazolium ionic liquids on electrochemical stability in electrolytes with GBL on TiO2 anatase electrodes.


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