Crucial Role of the Electron Transport Layer and UV Light on the Open-Circuit Voltage Loss in Inverted Organic Solar Cells

2017 ◽  
Vol 9 (39) ◽  
pp. 34131-34138 ◽  
Author(s):  
Aurélien Tournebize ◽  
Giorgio Mattana ◽  
Thérèse Gorisse ◽  
Antoine Bousquet ◽  
Guillaume Wantz ◽  
...  
Solar RRL ◽  
2020 ◽  
Vol 4 (12) ◽  
pp. 2000551
Author(s):  
Muhammad Ishaq ◽  
Shuo Chen ◽  
Umar Farooq ◽  
Muhammad Azam ◽  
Hui Deng ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Chandra Bhal Singh ◽  
Vandana Singh ◽  
S. Bhattacharya ◽  
P. Balaji Bhargav ◽  
Nafis Ahmed

Hybrid solar cells are based on the concept of using both organic and inorganic materials for fabrication of devices. Hybrid solar cells, based on a heterojunction between inorganic electron acceptor layer and organic donor layer, has been fabricated. Effect of electron transport layer on open circuit voltage (Voc) of hybrid solar cells was investigated. Hybrid solar cells were fabricated using amorphous silicon as main absorbing layer and as electron acceptor layer while using copper phthalocyanine (CuPc) as the donor materials. Al doped ZnO layer was used as buffer layer between ITO and a-Si:H to prevent ITO from reacting with silane gas during plasma enhanced chemical deposition (PECVD) process. ZnO:Al thin film also acts as electron transport layer. The open circuit voltage of hybrid solar cells studied with varying the thickness of ZnO:Al layer. Voc was increased from 0.30 volt to 0.52 volt with increasing the thickness of ZnO:Al layer from 15 nm to 45 nm. The poor interface between inorganic (a-Si:H) and organic layers may be a possible reason for low fill factor and low photocurrent in hybrid solar cells.


2021 ◽  
Author(s):  
Ying Hu ◽  
Jiaping Wang ◽  
Peng Zhao ◽  
Zhenhua Lin ◽  
Siyu Zhang ◽  
...  

Abstract Due to excellent thermal stability and optoelectronic properties, all-inorganic perovskite is one of the promising candidates to solve the thermal decomposition problem of conventional organic-inorganic hybrid perovskite solar cells (PSCs), but the larger voltage loss (V loss) cannot be ignored, especially CsPbIBr2, which limits the improvement of efficiency. To reduce the V loss, one promising solution is the modification of the energy level alignment between perovskite layer and adjacent charge transport layer (CTL), which can facilitate charge extraction and reduce carrier recombination rate at perovskite/CTL interface. Therefore, the key issues of minimum V loss and high efficiency of CsPbIBr2-based PSCs were studied in terms of the perovskite layer thickness, the effects of band offset of CTL/perovskite layer, the doping concentration of the CTL, and the electrode work function in this study based on device simulations. The open-circuit voltage (V oc) is increased from 1.37 V to 1.52 V by replacing SnO2 with ZnO as electron transport layer (ETL) due to more matching conduction band with CsPbIBr2 layer.


2015 ◽  
Vol 3 (7) ◽  
pp. 3719-3725 ◽  
Author(s):  
Hong Li Gao ◽  
Xing Wang Zhang ◽  
Jun Hua Meng ◽  
Zhi Gang Yin ◽  
Liu Qi Zhang ◽  
...  

We present a novel and efficient route to improve the open-circuit voltage and efficiency of polymer solar cells by modifying ZnO electron transport layer with H-plasma treatment.


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