Effects of Applied Interfacial Pressure on Li-Metal Cycling Performance and Morphology in 4 M LiFSI in DME

2021 ◽  
Author(s):  
Katharine L. Harrison ◽  
Subrahmanyam Goriparti ◽  
Laura C. Merrill ◽  
Daniel Martin Long ◽  
Benjamin Warren ◽  
...  
Keyword(s):  
Cycling Performance ◽  
Metal Cycling ◽  
Interfacial Pressure

Improved Li-Metal Cycling Performance in High Concentrated Electrolytes for Li-O2 Batteries

2018 ◽  
Vol 5 (19) ◽  
pp. 2758-2766 ◽  
Author(s):  
K. Pranay Reddy ◽  
Philipp Fischer ◽  
Mario Marinaro ◽  
Margret Wohlfahrt-Mehrens
Keyword(s):  
Cycling Performance ◽  
Metal Cycling ◽  
Concentrated Electrolytes

scholarly journals Cover Feature: Improved Li-Metal Cycling Performance in High Concentrated Electrolytes for Li-O2 Batteries (ChemElectroChem 19/2018)

2018 ◽  
Vol 5 (19) ◽  
pp. 2696-2696
Author(s):  
K. Pranay Reddy ◽  
Philipp Fischer ◽  
Mario Marinaro ◽  
Margret Wohlfahrt-Mehrens
Keyword(s):  
Cycling Performance ◽  
Metal Cycling ◽  
Concentrated Electrolytes

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Potassium Pre-Inserted K1.04Mn8O16 Cathode Materials for Aqueous Li-Ion and Na-Ion Hybrid Capacitors

2019 ◽  
Author(s):  
Yamin Zhang ◽  
Lina Chen ◽  
Chongyang Hao ◽  
Xiaowen Zheng ◽  
Yixuan Guo ◽  
...  
Keyword(s):  
Cycling Performance ◽  
High Energy ◽  
High Energy Density ◽  
Potassium Ions ◽  
Tunnel Structure ◽  
Hybrid Supercapacitor ◽  
Hybrid Supercapacitors ◽  
Li Ion ◽  
Power Densities ◽  
Hybrid Capacitors

For the applications of aqueous Li-ion hybrid capacitors and Na-ion hybrid capacitors, potassium ions are pre-inserted into MnO<sub>2</sub> tunnel structure, the as-prepared K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16</sub> materials consist of <a>nanoparticles</a> and nanorods were prepared by facile high-temperature solid-state reaction. <a></a>The as-prepared materials were well studied andthey show outstanding electrochemical behavior. We assembled hybrid supercapacitors with commercial activated carbon (YEC-8A) as anode and K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16 </sub>as cathode. It has high energy densities and power densities. Li-ion capacitors reach a high energy density of 127.61 Wh kg<sup>-1 </sup>at the power density of 99.86 W kg<sup>-1</sup> and Na-ion capacitor obtains 170.96 Wh kg<sup>-1 </sup>at 133.79 W kg<sup>-1</sup>. In addition, the <a>hybrid supercapacitor</a>s demonstrate excellent cycling performance which maintain 97 % capacitance retention for Li-ion capacitor and 85 % for Na-ion capacitor after 10,000 cycles.

Highly thermally conductive graphene-based electrodes for supercapacitors with excellent heat dissipation ability

2017 ◽  
Vol 1 (10) ◽  
pp. 2145-2154 ◽  
Author(s):  
Bo Zhao ◽  
Xian-Zhu Fu ◽  
Rong Sun ◽  
Ching-Ping Wong
Keyword(s):  
Heat Dissipation ◽  
Cycling Performance ◽  
Thermally Conductive ◽  
Rate Capacity ◽  
Electrodes For Supercapacitors

The highly thermally conductive graphene-based electrodes for supercapacitors exhibit great heat dissipation ability as well as excellent cycling performance and rate capacity.

Enabling highly reversible sodium metal cycling across a wide temperature range with dual-salt electrolytes

2021 ◽  
Author(s):  
Akila C. Thenuwara ◽  
Pralav P. Shetty ◽  
Neha Kondekar ◽  
Chuanlong Wang ◽  
Weiyang Li ◽  
...  
Keyword(s):  
Wide Temperature Range ◽  
High Energy ◽  
Liquid Electrolyte ◽  
Metal Cycling ◽  
Temperature Range ◽  
Sodium Metal ◽  
Wide Range

A new dual-salt liquid electrolyte is developed that enables the reversible operation of high-energy sodium-metal-based batteries over a wide range of temperatures down to −50 °C.

Improved Cycling Performance of P2-Na0.67Ni0.33Mn0.67O2 Based on Sn Substitution Combined with Polypyrrole Coating

2021 ◽  
Vol 13 (3) ◽  
pp. 3793-3804
Author(s):  
Siqi Yuan ◽  
Jizhen Qi ◽  
Meidan Jiang ◽  
Guijia Cui ◽  
Xiao-Zhen Liao ◽  
...  
Keyword(s):  
Cycling Performance ◽  
Sn Substitution
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