Enabling highly reversible sodium metal cycling across a wide temperature range with dual-salt electrolytes

Author(s):  
Akila C. Thenuwara ◽  
Pralav P. Shetty ◽  
Neha Kondekar ◽  
Chuanlong Wang ◽  
Weiyang Li ◽  
...  

A new dual-salt liquid electrolyte is developed that enables the reversible operation of high-energy sodium-metal-based batteries over a wide range of temperatures down to −50 °C.

1974 ◽  
Vol 52 (10) ◽  
pp. 894-902 ◽  
Author(s):  
Hans W. Behrisch

Liver of the hibernating (H) Arctic ground squirrel (Citellus undulatus) contains a single species of pyruvate kinase (PyK) that is distinct from the single isoenzyme of pyK observed in the non-hibernating (NH) ground squirrel, which has been previously described (Behrisch &Johnson (1974) Can. J. Biochem. 52, 547–559). The H-PyK has a pI value of 5.7 and a molecular weight of 241 000 – 243 000. Affinity of the H-PyK for the substrates phosphoenolpyruvate (PEP) and ADP is not affected by changing temperature. It is argued that this stability of the apparent Km's for substrate over a wide temperature range permits the hibernator to take advantage of the Q10 effect in maintaining a low rate of the PyK reaction. Similarly, affinity of H-PyK for the allosteric activator fructose-1,6-phosphate (FDP) and the inhibitor ATP is also conspicuously independent of temperature, suggesting a fine stoichiometry in the relative concentrations of the regulatory ligands in control of H-PyK over a wide temperature range. Further, affinity of H-PyK for the inhibitor ATP is about three- to fourfold lower than that of the NH-PyK, a condition that would favor the maintenance of a high energy charge in the hibernating liver cell. ATP apparently inhibits PyK by causing a dissociation of the enzyme molecule into two "halves" of about 110 000 molecular weight each. This dissociation is offset and reversed by FDP. Removal of the ATP by dialysis does not of itself result in a reassociation of the PyK "halves"; FDP and/or the substrates are required for the two subunits of PyK to reassociate. As the apparent Ki of H-PyK for ATP is higher than that of NH-PyK, substantially higher concentrations of ATP are required to effect the dissociation of H-PyK. Similarly, elevated concentrations of FDP are required to offset the ATP-caused dissociation of the H-PyK.Hibernating Arctic ground squirrels that are preparing to emerge finally from the hibernating state already possess substantial activities of the NH-PyK isoenzyme. This suggests that the animal "anticipates" its transition from one metabolic state from another. On the basis of these data a formal mechanism is proposed for the regulation of liver PyK in the Arctic ground squirrel in both the non-hibernating and hibernating states.


Author(s):  
Takashi Inoue ◽  
Toshiyuki Meshii

The fracture toughness KJc of the material in the ductile to brittle transition temperature (DBTT) range exhibits both test specimen thickness (TST) dependence and temperature dependence. Attention has been paid to the master curve (MC) method, which provides an engineering approach to address these two issues. Although MC is intended to be applied to arbitrary ferritic material whose yield stress is within the range of 275 to 825 MPa, the KJc value must be obtained to determine the material dependent reference temperature T0. The applicable range of MC method is restricted to T0 ± 50 °C. Previous studies indicate that additional pre-tests to obtain T0 are necessary; thus, there might be some unwritten requirement to the test temperature for the KJc temperature dependence prediction in MC method to work effectively. If testing must be conducted for the material of interest at some restricted temperature, a more flexible KJc temperature dependence prediction can possibly be obtained for a wide temperature range in the DBTT range, if the simplified and direct scaling (SDS) method, which predicts fracture “load” from yield stress temperature dependence proposed previously is applied. In this study, the SDS method was applied to two different steels: Cr-Mo steel JIS SCM440 and 0.55% carbon steel JIS S55C. Both tensile and fracture toughness tests were performed over a wide range of temperatures, specifically, −166 to 100 °C for SCM440 and −166 to 20 °C for S55C. The SDS method (i.e., fracture load is proportional to 1/(yield stress)) was initially validated for the specimens in the DBTT range. Finally, a simplified method was proposed and initially validated to predict the KJc temperature dependence, by applying the SDS using the EPRI plastic J functional form.


Nano Energy ◽  
2019 ◽  
Vol 62 ◽  
pp. 725-733 ◽  
Author(s):  
Qiaolan Fan ◽  
Chunrui Ma ◽  
Yi Li ◽  
Zhongshuai Liang ◽  
Sheng Cheng ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 10115-10123 ◽  
Author(s):  
José L. Rivera ◽  
Luis Molina-Rodríguez ◽  
Mariana Ramos-Estrada ◽  
Pedro Navarro-Santos ◽  
Enrique Lima

Picture of the ionic liquid [bmim][triflate] at the vapor/vacuum interface. The liquid density and surface tension show linear behavior in a wide temperature range. The outer interfacial space shows a zero-surface tension zone.


Circuit World ◽  
2015 ◽  
Vol 41 (3) ◽  
pp. 116-120 ◽  
Author(s):  
Paweł Winiarski ◽  
Adam Kłossowicz ◽  
Jacek Wróblewski ◽  
Andrzej Dziedzic ◽  
Wojciech Stęplewski

Purpose – The purpose of this paper is to characterize electrical properties of nickel-phosphorus (Ni-P) thin-film resistors made on FR-4 laminate in a wide range of temperature (from −180 to 20°C). Design/methodology/approach – The study was performed using resistors made of Ni-P foil with two different thicknesses (0.1 or 0.05 μm) and sheet resistances (100 or 250 Ω/sq), respectively. The resistance rectangular resistors had length and width from the range between 0.59 and 5.91 mm. The resistance versus temperature characteristics and their distribution as well as resistors ' durability to low-temperature thermal shocks were investigated. Findings – The results showed almost linear temperature dependence of resistance with a negative temperature coefficient of resistance of about −95 ppm/°C for 250 Ω/sq layer and −55 ppm/°C for 100 Ω/sq layer. A very small dimensional effect was observed for sheet resistance as well as for R(T) characteristic. Thin-film resistors are also characterized by very high durability to low-temperature thermal shocks. Originality/value – The results presented in this paper can be very useful for low-temperature applications of thin-film resistors made on printed circuit boards. They suggest possibility of wide applications of these components in a wide temperature range.


2015 ◽  
Vol 233-234 ◽  
pp. 8-11 ◽  
Author(s):  
Ivan Popov ◽  
P. Prudnikov

In the past few years, systems with slow dynamics have attracted considerable interest. Coarsening effects are exhibited in a wide range of systems. Non-equilibrium critical behavior of 2D XY-model demonstrates slow dynamics in a wide temperature range. The coarsening in pure and diluted 2D XY-model are investigated for various defects concentration. The period of logarithmic grows of cluster size was found.


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