High-Temperature-Aging Induced Sequential Recovery of Shape Memory Nitrile Butadiene Rubber Composites

2021 ◽  
Vol 13 (8) ◽  
pp. 10376-10387
Author(s):  
Jihua Zhang ◽  
Xiaoyan Liu ◽  
Weitao Zao ◽  
Huadong Feng ◽  
Yange Hou ◽  
...  
2020 ◽  
Vol 137 (30) ◽  
pp. 48911
Author(s):  
Shi‐Kai Hu ◽  
Tao Shou ◽  
Si Chen ◽  
Xiu‐Ying Zhao ◽  
Yong‐Lai Lu ◽  
...  

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 482-490
Author(s):  
Meng Song ◽  
Xiulin Yue ◽  
Xiujuan Wang ◽  
Mengjie Huang ◽  
Mingxing Ma ◽  
...  

AbstractBy introducing hindered amine GW-622 or GW-944 into nitrile-butadiene rubber/phenolic resin (NBR/PR, abbreviated as NBPR) matrix, we have prepared different hindered amine/NBR/PR ternary hybrid damping materials with high-temperature damping performance, respectively. Fourier transform infrared (FTIR) spectroscopy, scanning electron microscope (SEM), differential scanning calorimetry (DSC), and dynamic thermomechanical analysis (DMA) were used to research the microstructure, compatibility, and damping properties of the hindered amine/NBPR composites. FTIR results indicate that hydrogen bonds are formed between the hindered amine and the NBPR matrix. Both DSC and SEM results show that hindered amine has partial compatibility with the NBPR matrix. DMA results show that two loss peaks appear in the hindered amine/NBPR composite. Thereby, the composites show better damping performance at a higher temperature, and the temperature domain of high-temperature damping becomes wider with the increase in the addition of hindered amine. This study provides a theoretical support for the preparation of high-temperature damping materials.


2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Young Il Moon ◽  
Jae Kap Jung ◽  
Ki Soo Chung

The dielectric permittivity of synthetic rubber polymers, nitrile butadiene rubber (NBR) and ethylene propylene diene monomer (EPDM), with both frequency and temperature variations, was thoroughly investigated by dielectric relaxation spectroscopy (DRS). The spectrum versus frequency of DRS was analyzed with the semiempirical Havriliak–Negami formula and conductivity contribution by employing the newly developed “dispersion analyzer” analysis program. The main dielectric relaxations called the α- and β-processes, associated with the cooperative motion of chains in polymers, were discovered in the low-temperature region. In the high-temperature region, we found Maxwell–Wagner–Sillars (MWS) relaxation associated with polymer interfacing and normal-mode (α’) relaxation responsible for end-to-end dipole vector motion. The activation energies of schematic molecular chains responsible for the relaxation processes were obtained with the information about its motional mode. The glass transition temperature and dipole moment for the side group were also determined and compared with those from previous studies. In the EPDM specimen, the peaks of α- and β-relaxation merged at high temperature and were separated with decreasing temperature. The first observations of both merging and splitting were consistent with the results on the temperature dependency of the relaxation strength. Both contour mapping and three-dimensional plots for the two rubbers provide visual information for the distribution and mapping of relaxation.


2019 ◽  
Vol 150 ◽  
pp. 166-173
Author(s):  
Sergey Yu. Kondrat'ev ◽  
Grigoriy P. Anastasiadi ◽  
Alina V. Ptashnik ◽  
Sergey N. Petrov

2014 ◽  
Vol 601 ◽  
pp. 57-62 ◽  
Author(s):  
Sumei Zhao ◽  
Yu Zhao ◽  
Binglin Zou ◽  
Xizhi Fan ◽  
Jiaying Xu ◽  
...  

2019 ◽  
Vol 68 (9) ◽  
pp. 1618-1625
Author(s):  
Jihua Zhang ◽  
Hao Wang ◽  
Weitao Zao ◽  
Huadong Feng ◽  
Yunfeng Zhao

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