Role of Regeneration of Nanoclusters in Dictating the Power Conversion Efficiency of Metal-Nanocluster-Sensitized Solar Cells

2020 ◽  
Vol 12 (14) ◽  
pp. 16566-16575 ◽  
Author(s):  
Muhammad A. Abbas ◽  
Rizwan Khan ◽  
Seog Joon Yoon ◽  
Jin Ho Bang
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Metal Nanocluster ◽  
Sensitized Solar Cells

Spontaneous Enhancement of Power Conversion Efficiency in SnO2-Based Dye-Sensitized Solar Cells

2021 ◽  
Vol 11 (3) ◽  
pp. 674-678
Author(s):  
Shibing Zou ◽  
Lingting Song ◽  
Junhong Duan ◽  
Le Huang ◽  
Weiqing Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Donor-π-acceptor, triazine-linked porphyrin dyads as sensitizers for dye-sensitized solar cells

2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Carboxylic Acid ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Orbital Energy ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.

Push–pull type alkoxy-wrapped N-annulated perylenes for dye-sensitized solar cells

RSC Advances ◽  
2016 ◽  
Vol 6 (84) ◽  
pp. 81184-81190 ◽  
Author(s):  
Qingbiao Qi ◽  
Jing Zhang ◽  
Soumyajit Das ◽  
Wangdong Zeng ◽  
Jie Luo ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Three push–pull type, alkoxy-wrapped N-annulated perylene based sensitizers were synthesized and power conversion efficiency up to 8.38% was achieved.

scholarly journals The role of connectivity in significant bandgap narrowing for fused-pyrene based non-fullerene acceptors toward high-efficiency organic solar cells

2020 ◽  
Vol 8 (12) ◽  
pp. 5995-6003 ◽  
Author(s):  
Shungang Liu ◽  
Wenyan Su ◽  
Xianshao Zou ◽  
Xiaoyan Du ◽  
Jiamin Cao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Organic Solar Cells ◽  
High Efficiency ◽  
Power Conversion ◽  
Structural Isomer ◽  
Bandgap Narrowing ◽  
Higher Power

Isomers of non-fullerene acceptors with pyrene as cores but fused at different positions were studied. FPIC6 possessed ∼119 nm of red-shift absorption and much higher power conversion efficiency of 11.55% as compared to its structural isomer FPIC5.

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