A Metal-Free N-Annulated Thienocyclopentaperylene Dye: Power Conversion Efficiency of 12 % for Dye-Sensitized Solar Cells

2015 ◽  
Vol 127 (20) ◽  
pp. 6092-6096 ◽  
Author(s):  
Zhaoyang Yao ◽  
Min Zhang ◽  
Renzhi Li ◽  
Lin Yang ◽  
Yongna Qiao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Metal Free ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Metal-free branched alkyl tetrathienoacene (TTAR)-based sensitizers for high-performance dye-sensitized solar cells

2017 ◽  
Vol 5 (24) ◽  
pp. 12310-12321 ◽  
Author(s):  
Yamuna Ezhumalai ◽  
Byunghong Lee ◽  
Miao-Syuan Fan ◽  
Boris Harutyunyan ◽  
Kumaresan Prabakaran ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Performance ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Metal Free ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Organic Sensitizers

New branched alkyl tetrathienothiophene (TTAR)-based organic sensitizers with power conversion efficiency up to 11%.

Highly Efficient SnO2/MgO Composite Film-Based Dye-Sensitized Solar Cells Sensitized with N719 and D358 Dyes

2014 ◽  
Vol 13 (04) ◽  
pp. 1440006 ◽  
Author(s):  
E. N. Jayaweera ◽  
C. S. K. Ranasinghe ◽  
G. R. A. Kumara ◽  
R. M. G. Rajapakse
Keyword(s):  
Solar Cells ◽  
Composite Film ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Superior Performance ◽  
Metal Free ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

SnO 2/ MgO composite film-based dye-sensitized solar cells (DSCs), sensitized with both N719 dye and metal-free D358 dye, employing [Formula: see text] redox couple-based liquid electrolyte, show superior performance to those sensitized with only D358 dye, and N719 dye. A significant improvement in the power conversion efficiency was attained by co-sensitizing the N719-based DSCs with metal-free D358 dye when compared to those obtained for DSCs with individual dyes. As confirmed by UV-visible absorption spectra, N719 dye adsorption is more prominent than that of D358 dye when sensitizing the SnO 2/ MgO composite film with the two dyes, D358 and N719. However, N719 and D358 dyes, when used alone, are prone to form aggregates on the SnO 2/ MgO composite film, when N719 dye is used together with D358, the latter effectively suppresses the aggregation of N719 dye on the SnO 2/ MgO composite film, thereby enhancing the power conversion efficiency of the DSCs. Hence, the corresponding power conversion efficiency of the SnO 2/ MgO composite film-based DSCs can be significantly improved by sensitizing with both N719 and D358 dyes. The reported power conversion efficiencies for the SnO 2/ MgO composite film-based DSCs, sensitized with, (a) D358 dye, (b) N719 dye, and (c) both N719 dye and D358 dye, are 6.37%, 7.43% and 8.60% respectively, under AM 1.5 illumination.

Spontaneous Enhancement of Power Conversion Efficiency in SnO2-Based Dye-Sensitized Solar Cells

2021 ◽  
Vol 11 (3) ◽  
pp. 674-678
Author(s):  
Shibing Zou ◽  
Lingting Song ◽  
Junhong Duan ◽  
Le Huang ◽  
Weiqing Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Donor-π-acceptor, triazine-linked porphyrin dyads as sensitizers for dye-sensitized solar cells

2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Carboxylic Acid ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Orbital Energy ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.

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