Improving the Structure Stability of LiNi0.8Co0.15Al0.05O2 by Double Modification of Tantalum Surface Coating and Doping

2021 ◽  
Author(s):  
Xiaoyun Zhang ◽  
Panpan Zhang ◽  
Tianyi Zeng ◽  
Zhenlu Yu ◽  
Xingyu Qu ◽  
...  
Keyword(s):  
Surface Coating ◽  
Structure Stability ◽  
Double Modification

Development and Psychometric Evaluation of a Revised Sense of Coherence Scale

2018 ◽  
Vol 34 (3) ◽  
pp. 206-215 ◽  
Author(s):  
Rahel Bachem ◽  
Andreas Maercker
Keyword(s):  
Posttraumatic Growth ◽  
Factor Structure ◽  
Sense Of Coherence ◽  
Psychological Health ◽  
Psychometric Evaluation ◽  
Health Indicators ◽  
Structure Stability ◽  
Confirmatory Factor Analyses ◽  
Reliability Factor ◽  
Two Samples

Abstract. The present study introduces a revised Sense of Coherence (SOC) scale, a new conceptualization and operationalization of the resilience indicator SOC. It outlines the scale development and aims for testing its reliability, factor structure, and validity. Literature on Antonovsky’s SOC (SOC-A) was critically reviewed to identify needs for improving the scale. The scale was investigated in two samples. Sample 1 consisted of 334 bereaved participants, Sample 2 of 157 healthy controls. The revised SOC Scale, SOC-A, and theoretically relevant questionnaires were applied. Explorative and confirmatory factor analyses established a three-factor structure in both samples. The revised SOC Scale showed significant but discriminative associations with related constructs, including self-efficacy, posttraumatic growth, and neuroticism. The revised measure was significantly associated with psychological health indicators, including persistent grief, depression, and anxiety, but not to the extent as the previous SOC-A. Stability over time was sufficient. The study provides psychometric support for the revised SOC conceptualization and scale. It has several advantages over the previous SOC-A scale (unique variance, distinct factor structure, stability). The scale could be used for clinical and health psychological testing or research into the growing field of studies on resilience over the life span.

Antithrombin III Binding to Surface Immobilized Heparin and Its Relation to F Xa Inhibition

1987 ◽  
Vol 58 (04) ◽  
pp. 1064-1067 ◽  
Author(s):  
K Kodama ◽  
B Pasche ◽  
P Olsson ◽  
J Swedenborg ◽  
L Adolfsson ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ionic Strength ◽  
Surface Coating ◽  
Antithrombin Iii ◽  
Lower Class ◽  
Biologically Active ◽  
High Affinity ◽  
Heparin Coating ◽  
Continuous Surface ◽  
Approximate Molecular Weight

SummaryThe mode of F Xa inhibition was investigated on a thromboresistant surface with end-point attached partially depoly-merized heparin of an approximate molecular weight of 8000. Affinity chromatography revealed that one fourth of the heparin used in surface coating had high affinity for antithrombin III (AT). The heparin surface adsorbed AT from both human plasma and solutions of purified AT. By increasing the ionic strength in the AT solution the existence of high and low affinity sites could be shown. The uptake of AT was measured and the density of available high and low affinity sites was found to be in the range of 5 HTid 11 pic.omoles/cmf, respectively Thus the estimated density of biologically active high and low ailmity heparm respectively would be 40 and 90 ng/cm2 The heparin coating did not take up or exert F Xa inhibition by itself. With AT adsorbed on both high and low affinity heparin the surface had the capacity to inhibit several consecutive aliquots of F Xa exposed to the surface. When mainly high affinity sites were saturated with AT the inhibition capacity was considerably lower. Tt was demonstrated that the density of AT on both high and low affinity heparin determines the F Xa inhibition capacity whereas the amount of AT on high affinity sites limits the rate of the reaction. This implies that during the inhibition of F Xa there is a continuous surface-diffusion of AT from sites of a lower class to the high affinity sites where the F Xa/AT complex is formed and leaves the surface. The ability of the immobilized heparin to catalyze inhibition of F Xa is likely to be an important component for the thromboresistant properties of a heparin coating with non-compromized AT binding sequences.

Effects of Surface Coating on the Critical Heat Flux for Pool Boiling from a Downward Facing Surface

2004 ◽  
Vol 11 (2) ◽  
pp. 133-150 ◽  
Author(s):  
M. B. Dizon ◽  
J. Yang ◽  
F. B. Cheung ◽  
J. L. Rempe ◽  
K. Y. Suh ◽  
...  
Keyword(s):  
Heat Flux ◽  
Critical Heat Flux ◽  
Surface Coating ◽  
Pool Boiling

Cyclic fatigue comparison among endodontic instruments with similar cross section and different surface coating

2019 ◽  
Vol 68 (2) ◽  
Author(s):  
Eugenio Pedullà ◽  
Gianluca Plotino ◽  
Mauro Scibilia ◽  
Nicola M. Grande ◽  
Daniele De Santis ◽  
...  
Keyword(s):  
Cross Section ◽  
Surface Coating ◽  
Cyclic Fatigue

Structure, Stability and Water Adsorption on Ultra-Thin TiO2 Supported on TiN

2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  
Keyword(s):  
Density Functional ◽  
Water Adsorption ◽  
Chemical Potential ◽  
Energy Gap ◽  
Molecular Water ◽  
Structure Stability ◽  
Ambient Conditions ◽  
Rutile Structure ◽  
The Stability ◽  
The One

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>

PRINTING. The ageing resistance of offset and electrophotographic prints

2012 ◽  
Vol 27 (4) ◽  
pp. 739-749
Author(s):  
Silva Grilj ◽  
Tadeja Muck ◽  
Diana Gregor-Svetec
Keyword(s):  
Relative Humidity ◽  
Surface Coating ◽  
Accelerated Ageing ◽  
Colour Stability ◽  
Light Fastness ◽  
Moist Heat ◽  
Printing Technique ◽  
Lower Light ◽  
Recycled Fibres ◽  
2D And 3D

Abstract The moist heat (80°C and 65% relative humidity) and light (xenon arc lamp) treatments of accelerated ageing were applied to investigate the colour stability of offset and electrophotographic prints on papers made of virgin and I 00% recycled fibres. The prints were evaluated using spectrophotometric measurements and additional colour differences calculations. In addition to the colour differences, the 2D and 3D colour gamuts are presented. The results reveal the different colour stability of prints. The effect depends on the type of accelerated ageing, printing technique, composition of ink and paper characteristics. Moist heat ageing has less influence on colour stability than light ageing. The electrophotographic prints show better ageing resistance than offset prints. The intluence of ink on print light fastness is considerable. Azo pigments in magenta and yellow have lower light fastness than phthalocyanine pigments in cyan or carbon black. The surface coating has an intluence on light fastness of prints. Meanwhile, prints on recycled papers show similar colour stability compared to prints on papers made of virgin fibres

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