Performance Improvement of Hole-Transport Material-Free Mesoporous Perovskite Solar Cells with Carbon Electrodes Using a Solid–Gas Reaction

Author(s):  
Byol Kim ◽  
Kwon-Il Ryu ◽  
Song-Guk Ko ◽  
Kyong-Su Sonu ◽  
Jin-Hyok Ri ◽  
...  
2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Jie Xu ◽  
Jian Cui ◽  
Shaomin Yang ◽  
Yu Han ◽  
Xi Guo ◽  
...  

AbstractThe application of ionic liquids in perovskite has attracted wide-spread attention for its astounding performance improvement of perovskite solar cells (PSCs). However, the detailed mechanisms behind the improvement remain mysterious. Herein, a series of imidazolium-based ionic liquids (IILs) with different cations and anions is systematically investigated to elucidate the passivation mechanism of IILs on inorganic perovskites. It is found that IILs display the following advantages: (1) They form ionic bonds with Cs+ and Pb2+ cations on the surface and at the grain boundaries of perovskite films, which could effectively heal/reduce the Cs+/I− vacancies and Pb-related defects; (2) They serve as a bridge between the perovskite and the hole-transport-layer for effective charge extraction and transfer; and (3) They increase the hydrophobicity of the perovskite surface to further improve the stability of the CsPbI2Br PSCs. The combination of the above effects results in suppressed non-radiative recombination loss in CsPbI2Br PSCs and an impressive power conversion efficiency of 17.02%. Additionally, the CsPbI2Br PSCs with IILs surface modification exhibited improved ambient and light illumination stability. Our results provide guidance for an in-depth understanding of the passivation mechanism of IILs in inorganic perovskites."Image missing"


2018 ◽  
Vol 10 (41) ◽  
pp. 35404-35410 ◽  
Author(s):  
Randi Azmi ◽  
Un-Hak Lee ◽  
Febrian Tri Adhi Wibowo ◽  
Seung Hun Eom ◽  
Sung Cheol Yoon ◽  
...  

2020 ◽  
Vol 32 (10) ◽  
pp. 105205
Author(s):  
Haixia Xie ◽  
Xingtian Yin ◽  
Yuxiao Guo ◽  
Dan Liu ◽  
Tong Liang ◽  
...  

Solar Energy ◽  
2018 ◽  
Vol 174 ◽  
pp. 897-900 ◽  
Author(s):  
Guan-Syun Chen ◽  
Yi-Ching Chen ◽  
Ching-Ting Lee ◽  
Hsin-Ying Lee

Nanoscale ◽  
2018 ◽  
Vol 10 (23) ◽  
pp. 11043-11051 ◽  
Author(s):  
Guanchen Liu ◽  
Xiaoyin Xie ◽  
Zhihai Liu ◽  
Guanjian Cheng ◽  
Eun-Cheol Lee

We introduced alcohol based vapor annealing of the hole transport layer for fabricating high-performance inverted perovskite solar cells.


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