Alcohol based vapor annealing of a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) layer for performance improvement of inverted perovskite solar cells

Nanoscale ◽  
2018 ◽  
Vol 10 (23) ◽  
pp. 11043-11051 ◽  
Author(s):  
Guanchen Liu ◽  
Xiaoyin Xie ◽  
Zhihai Liu ◽  
Guanjian Cheng ◽  
Eun-Cheol Lee

We introduced alcohol based vapor annealing of the hole transport layer for fabricating high-performance inverted perovskite solar cells.

2018 ◽  
Vol 246 ◽  
pp. 195-203 ◽  
Author(s):  
Dian Wang ◽  
Naveen Kumar Elumalai ◽  
Md Arafat Mahmud ◽  
Haimang Yi ◽  
Mushfika Baishakhi Upama ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1281
Author(s):  
Jae Woong Jung ◽  
Seung Hwan Son ◽  
Jun Choi

We herein address the optoelectronic properties of polyaniline composite films with graphene oxide and reduced graphene oxide as a hole transport layer in inverted perovskite solar cells. The composite films exhibited enhanced electrical conductivity and suitable energy level matching with CH3NH3PbI3 for efficient hole extraction/transport than the pristine polyaniline film, which thus can deliver improved photovoltaic properties of device. The composite film-based devices exhibited maximum efficiency of 16.61%, which is enhanced by 21.6% from the device with the pristine polyaniline hole transport layer (efficiency = 13.66%). The reduced graphene oxide-based composite film also achieved improved long-term operative stability as compared to the pristine polyaniline-based device, demonstrating a great potential of reduced graphene oxide/polyaniline composite hole transport layer for high performance perovskite solar cells.


2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Jie Xu ◽  
Jian Cui ◽  
Shaomin Yang ◽  
Yu Han ◽  
Xi Guo ◽  
...  

AbstractThe application of ionic liquids in perovskite has attracted wide-spread attention for its astounding performance improvement of perovskite solar cells (PSCs). However, the detailed mechanisms behind the improvement remain mysterious. Herein, a series of imidazolium-based ionic liquids (IILs) with different cations and anions is systematically investigated to elucidate the passivation mechanism of IILs on inorganic perovskites. It is found that IILs display the following advantages: (1) They form ionic bonds with Cs+ and Pb2+ cations on the surface and at the grain boundaries of perovskite films, which could effectively heal/reduce the Cs+/I− vacancies and Pb-related defects; (2) They serve as a bridge between the perovskite and the hole-transport-layer for effective charge extraction and transfer; and (3) They increase the hydrophobicity of the perovskite surface to further improve the stability of the CsPbI2Br PSCs. The combination of the above effects results in suppressed non-radiative recombination loss in CsPbI2Br PSCs and an impressive power conversion efficiency of 17.02%. Additionally, the CsPbI2Br PSCs with IILs surface modification exhibited improved ambient and light illumination stability. Our results provide guidance for an in-depth understanding of the passivation mechanism of IILs in inorganic perovskites."Image missing"


2018 ◽  
Vol 29 (47) ◽  
pp. 1806740 ◽  
Author(s):  
Hytham Elbohy ◽  
Behzad Bahrami ◽  
Sally Mabrouk ◽  
Khan Mamun Reza ◽  
Ashim Gurung ◽  
...  

2021 ◽  
Author(s):  
Hamed Moeini Alishah ◽  
Fatma Pinar Gokdemir Choi ◽  
Serap Gunes

Abstract Inverted-type perovskite solar cells have drawn remarkable attention due to solution-processable, straightforward configuration, low-cost processing, and manufacturing at very high throughput, even on top of flexible materials. The hole transport material (HTM) plays a vital role to achieve high performance in inverted type of perovskite solar cells. Herein, we report on the effect of different commercial PEDOT: PSS such as PH 1000, PH 500, P VP AI, and P T2, on the performance of CH3NH3PbI3 based planar perovskite solar cells.


2018 ◽  
Vol 6 (26) ◽  
pp. 6975-6981 ◽  
Author(s):  
Chongyang Xu ◽  
Zhihai Liu ◽  
Eun-Cheol Lee

A poly(bis(4-phenyl)(2,4,6-trimethylphenyl)amine) hole transfer layer was used to enhance the performance and lifetime of metal oxide-free inverted perovskite solar cells.


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