A General Catalyst for Site-Selective C(sp3)–H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp3)–H Bonds

2016 ◽  
Vol 18 (12) ◽  
pp. 3014-3017 ◽  
Author(s):  
Ryan J. Scamp ◽  
James G. Jirak ◽  
Nicholas S. Dolan ◽  
Ilia A. Guzei ◽  
Jennifer M. Schomaker
Keyword(s):  
Site Selective ◽  
Tertiary Alkyl

ChemInform Abstract: A General Catalyst for Site-Selective C(sp3)-H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp3)-H Bonds.

ChemInform ◽  
2016 ◽  
Vol 47 (44) ◽  
Author(s):  
Ryan J. Scamp ◽  
James G. Jirak ◽  
Nicholas S. Dolan ◽  
Ilia A. Guzei ◽  
Jennifer M. Schomaker
Keyword(s):  
Site Selective ◽  
Tertiary Alkyl

scholarly journals Synthesis of tertiary alkyl fluorides and chlorides by site-selective nucleophilic ring-opening reaction of α-aryl azetidinium salts

RSC Advances ◽  
2021 ◽  
Vol 11 (62) ◽  
pp. 39607-39618
Author(s):  
Eiji Tayama ◽  
Kohei Kawai
Keyword(s):  
Ring Opening ◽  
Alkyl Halides ◽  
Ring Opening Reaction ◽  
Site Selective ◽  
Alkyl Fluorides ◽  
Nucleophilic Ring Opening ◽  
Tertiary Alkyl

Site-selective nucleophilic ring-opening of 2 with Bu4NX proceeded at a much-substituted 2-position preferentially and produced tertiary alkyl halides 3.

Site-Selective Tertiary Alkyl-Fluorine Bond Formation from α-Bromoamides Using a Copper/CsF Catalyst System

2016 ◽  
Vol 128 (34) ◽  
pp. 10162-10166 ◽  
Author(s):  
Takashi Nishikata ◽  
Syo Ishida ◽  
Ryo Fujimoto
Keyword(s):  
Bond Formation ◽  
Catalyst System ◽  
Site Selective ◽  
Tertiary Alkyl

Chemical and Electrochemical Heteroepitaxial Growth of Chalcogenide Semiconductors from Solutions

1996 ◽  
Vol 451 ◽  
Author(s):  
D. Lincot ◽  
M. J. Furlong ◽  
M. Froment ◽  
R. Cortes ◽  
M. C. Bernard
Keyword(s):  
Heteroepitaxial Growth ◽  
X Ray Diffraction ◽  
Basic Principles ◽  
Lattice Match ◽  
X Ray ◽  
Chalcogenide Semiconductors ◽  
Influence Of Temperature On ◽  
Deposition Processes ◽  
A Site ◽  
Site Selective

ABSTRACTChalcogenide semiconductors have been deposited epitaxially from aqueous solutions either chemically or electrochemically at growth rates of up to 0.7 μmhr−1. After recalling the basic principles of these deposition processes, results are presented concerning chemically deposited CdS on InP, GaP and CuInSe2 substrates, electrodeposited CdTe on InP, and CdSAnP heterostructures. Characterisation of these structures by RHEED, TEM, HRTEM, and glazing angle X ray diffraction allows to analyse the effects of substrate orientation, polarity, lattice match plus the influence of temperature on epitaxial growth. These results are discussed in terms of self organisation and a site selective growth mechanisms due to the free enegy of formation of each compound.

para-Selective Cyanation of Arenes by H-Bonded Template

2019 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Trisha Bhattacharya ◽  
Arun Maji ◽  
Argha Saha ◽  
Ramasamy Jayarajan ◽  
...  
Keyword(s):  
Selective Functionalization ◽  
Directing Group ◽  
Product Utility ◽  
Site Selective

The significance of site selective functionalization stands upon the superior selectivity, easy synthesis and diverse product utility. In this work we demonstrate the <i>para</i>-selective introduction of versatile nitrile moiety, enabled by detachable and reusable H-bonded auxiliary. The methodology holds its efficiency irrespective of substrate electronic bias. The conspicuous shift in the step energetics was probed by both experimental and computational mechanistic tools heralds the inception of <i>para</i>-deuteration. The synthetic impact of the methodology was highlighted with reusability of directing group and post synthetic modifications

para-Selective Cyanation of Arenes by H-Bonded Template

2019 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Trisha Bhattacharya ◽  
Arun Maji ◽  
Argha Saha ◽  
Ramasamy Jayarajan ◽  
...  
Keyword(s):  
Selective Functionalization ◽  
Directing Group ◽  
Product Utility ◽  
Site Selective

The significance of site selective functionalization stands upon the superior selectivity, easy synthesis and diverse product utility. In this work we demonstrate the <i>para</i>-selective introduction of versatile nitrile moiety, enabled by detachable and reusable H-bonded auxiliary. The methodology holds its efficiency irrespective of substrate electronic bias. The conspicuous shift in the step energetics was probed by both experimental and computational mechanistic tools heralds the inception of <i>para</i>-deuteration. The synthetic impact of the methodology was highlighted with reusability of directing group and post synthetic modifications

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