An Iterative Phosphate Tether Mediated Approach for the Synthesis of Complex Polyol Subunits

2021 ◽  
Author(s):  
Salim Javed ◽  
Arghya Ganguly ◽  
Gihan C. Dissanayake ◽  
Paul R. Hanson
Keyword(s):  
Phosphate Tether

scholarly journals Phosphate tether-mediated ring-closing metathesis for the generation of medium to large, P-stereogenic bicyclo[n.3.1]phosphates

Tetrahedron ◽  
2015 ◽  
Vol 71 (35) ◽  
pp. 5734-5740 ◽  
Author(s):  
Soma Maitra ◽  
Jana L. Markley ◽  
Rambabu Chegondi ◽  
Paul R. Hanson
Keyword(s):  
Ring Closing Metathesis ◽  
Phosphate Tether

scholarly journals A Multifaceted Phosphate Tether:  Application to the C1−C14 Subunit of Dolabelides A−D

2008 ◽  
Vol 10 (1) ◽  
pp. 109-112 ◽  
Author(s):  
Joshua D. Waetzig ◽  
Paul R. Hanson
Keyword(s):  
Phosphate Tether

ChemInform Abstract: Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, P-Stereogenic Bicyclo[n.3.1]phosphates.

ChemInform ◽  
2015 ◽  
Vol 46 (48) ◽  
pp. no-no
Author(s):  
Soma Maitra ◽  
Jana L. Markley ◽  
Rambabu Chegondi ◽  
Paul R. Hanson
Keyword(s):  
Ring Closing Metathesis ◽  
Phosphate Tether

scholarly journals Phosphate-Tether-Mediated Ring-Closing Metathesis for the Preparation of Complex 1,3-anti-Diol-Containing Subunits

2013 ◽  
Vol 19 (25) ◽  
pp. 8088-8093 ◽  
Author(s):  
Rambabu Chegondi ◽  
Soma Maitra ◽  
Jana L. Markley ◽  
Paul R. Hanson
Keyword(s):  
Ring Closing Metathesis ◽  
Phosphate Tether

scholarly journals A Multifaceted Phosphate Tether:  Application to the C15−C30 Subunit of Dolabelides A−D

2008 ◽  
Vol 10 (7) ◽  
pp. 1421-1424 ◽  
Author(s):  
Alan Whitehead ◽  
Joshua D. Waetzig ◽  
Christopher D. Thomas ◽  
Paul R. Hanson
Keyword(s):  
Phosphate Tether

scholarly journals A modular phosphate tether-mediated divergent strategy to complex polyols

2014 ◽  
Vol 10 ◽  
pp. 2332-2337 ◽  
Author(s):  
Paul R Hanson ◽  
Susanthi Jayasinghe ◽  
Soma Maitra ◽  
Cornelius N Ndi ◽  
Rambabu Chegondi
Keyword(s):  
Reduction Process ◽  
Phosphoryl Chloride ◽  
One Pot ◽  
Simple Order ◽  
Coupling Strategy ◽  
Phosphate Tether

An efficient and divergent synthesis of polyol subunits utilizing a phosphate tether-mediated, one-pot, sequential RCM/CM/reduction process is reported. A modular, 3-component coupling strategy has been developed, in which, simple “order of addition” of a pair of olefinic-alcohol components to a pseudo-C 2-symmetric phosphoryl chloride, coupled with the RCM/CM/reduction protocol, yields five polyol fragments. Each of the product polyols bears a central 1,3-anti-diol subunit with differential olefinic geometries at the periphery.

scholarly journals Phosphate Tether-Mediated Approach to the Formal Total Synthesis of (−)-Salicylihalamides A and B

2011 ◽  
Vol 76 (10) ◽  
pp. 3909-3916 ◽  
Author(s):  
Rambabu Chegondi ◽  
Mary M. L. Tan ◽  
Paul R. Hanson
Keyword(s):  
Total Synthesis ◽  
Phosphate Tether

scholarly journals A Phosphate Tether-Mediated, One-Pot, Sequential Ring-Closing Metathesis/Cross-Metathesis/Chemoselective Hydrogenation Protocol

2012 ◽  
Vol 14 (10) ◽  
pp. 2634-2637 ◽  
Author(s):  
Phanindra K. M. Venukadasula ◽  
Rambabu Chegondi ◽  
Gregory M. Suryn ◽  
Paul R. Hanson
Keyword(s):  
Ring Closing Metathesis ◽  
One Pot ◽  
Cross Metathesis ◽  
Chemoselective Hydrogenation ◽  
Phosphate Tether
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