Hierarchical Scattering Function for Silica-Filled Rubbers under Deformation: Effect of the Initial Cluster Distribution

2019 ◽  
Vol 52 (24) ◽  
pp. 9735-9745 ◽  
Author(s):  
Mariapaola Staropoli ◽  
Dominik Gerstner ◽  
Michael Sztucki ◽  
Guido Vehres ◽  
Benoit Duez ◽  
...  
Keyword(s):  
Scattering Function ◽  
Deformation Effect ◽  
Cluster Distribution ◽  
Initial Cluster ◽  
Filled Rubbers

The semiclassical limit of the intermediate scattering function

1996 ◽  
Vol 89 (4) ◽  
pp. 1203-1207
Author(s):  
S. BONELLA ◽  
G. CICCOTTI ◽  
D.F. COKER
Keyword(s):  
Semiclassical Limit ◽  
Scattering Function ◽  
Intermediate Scattering Function

Novel Coupling Agents for Silica-filled Rubbers with Superior Processing Safety and Improved Hysteresis of the Vulcanizates

2010 ◽  
Vol 38 (1) ◽  
pp. 80-98 ◽  
Author(s):  
M. Gerster ◽  
C. Fagouri ◽  
E. Peregi
Keyword(s):  
Mixing Time ◽  
Cost Savings ◽  
Coupling Agents ◽  
Tire Industry ◽  
Selective Functionalization ◽  
Current State ◽  
Rubber Compounds ◽  
Volatile Organic ◽  
Filled Rubbers ◽  
Ethanol Removal

Abstract One challenge facing green tire technology is to achieve good silica hydrophobation/dispersion within the polymer matrix without a detrimental increase in the rubber compound’s viscosity during compounding. This phenomenon is well known to be induced by premature and unwanted coupling and/or crosslinking of the traditional coupling agents. The current state-of-the-art polysulfides silanes, bis(3-triethoxysilylpropyl)tetrasulfide and to a lesser extent bis(3-triethoxysilylpropyl)disulfide (“Product Application—VP Si 75/VP X 75-S in the Rubber Industry,” Degussa Hüls Report No. PA 723.1E), need to be carefully incorporated with careful temperature control during the rubber compounding to prevent this “scorchy” behavior. This paper will present novel monofunctional silanes which are suited for preparing highly silica-loaded rubber compounds of superior processability, while applying fewer mixing passes, thereby reducing mixing times which can lead to improved productivity and cost savings. Additionally, these safer coupling agents can be processed at higher temperatures which can, again, lead to reduced mixing time and better ethanol removal thereby improving the tire’s physical properties and reducing the volatile organic compounds generated during the tire’s use. The rubber compounds produced using these monofunctional silanes are characterized by lower Mooney viscosity and improved processability. Advantageously, within these novel chemical classes of coupling agents, selective functionalization of the silanes allows production of tailor-made coupling agents which can respond to the specific requirements of the tire industry (Vilgis, T. A. and Heinrich, G., “Die Physic des Autoreifens,” Physikalische Blätter, Vol. 57, 2001, pp. 1–7).

Research of nonlinear network connection based on scattering function

2010 ◽  
Vol 24 (2) ◽  
pp. 119-124 ◽  
Author(s):  
Chao Zhang ◽  
Fushun Nian ◽  
Shengli Liang ◽  
Zhiying Cao
Keyword(s):  
Scattering Function ◽  
Nonlinear Network ◽  
Network Connection

scholarly journals Experimental Results on Scattering by Irregular and Meteoritic Dust Particles Related to Photopolarimetry of Zodiacal Light and Comets

1985 ◽  
Vol 85 ◽  
pp. 223-226
Author(s):  
K. Weiss-Wrana ◽  
R.H. Giese ◽  
R.H. Zerull
Keyword(s):  
Light Scattering ◽  
Size Range ◽  
Experimental Results ◽  
Dust Particles ◽  
Dust Grains ◽  
Scattering Function ◽  
Negative Polarization ◽  
Zodiacal Light ◽  
Cometary Dust ◽  
Characteristic Features

AbstractThe investigations of light scattering by larger meteoritic and terrestrial single grains (size range 20 μm to 120 μm ) demonstrate that the scattering properties of irregularly shaped dark opaque particles with very rough surfaces resemble the characteristic features of the empirical scattering function as derived from measurements of the zodiacal light. Purely transparent or translucent irregularly shaped particles show a quite different scattering behaviour. Furthermore irregular and multicomponent fluffy particles in the size range of a few microns were modelled by microwave analog measurements in order to explain positive and negative polarization of the light scattered by cometary dust grains.

scholarly journals Laboratory Measurements of Light Scattering by Dust Particles

1996 ◽  
Vol 150 ◽  
pp. 409-413
Author(s):  
Patrick P. Combet ◽  
Philippe L. Lamy
Keyword(s):  
Light Scattering ◽  
Laser Beam ◽  
Mie Theory ◽  
Spherical Particles ◽  
Dust Particles ◽  
Laboratory Measurements ◽  
Scattering Function ◽  
Hene Laser ◽  
Set Up ◽  
Good Agreement

AbstractWe have set up an experimental device to optically study the scattering properties of dust particles. Measurements over the 8 — 174° interval of scattering angles are performed on a continuously flowing dust loaded jet illuminated by a polarized red HeNe laser beam. The scattering is averaged over the population of the dust particles in the jet, which can be determined independently, and give the “volume scattering function” for the two directions of polarization directly. While results for spherical particles are in good agreement with Mie theory, those for arbitrary particles show conspicuous deviations.

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