Interfacial Dynamics Governs the Mechanical Properties of Glassy Polymer Thin Films

2019 ◽  
Vol 52 (17) ◽  
pp. 6547-6554 ◽  
Author(s):  
Wenjie Xia ◽  
Tian Lan
2010 ◽  
Vol 43 (2) ◽  
pp. 214-217 ◽  
Author(s):  
Izaro López García ◽  
Joseph L Keddie ◽  
Michele Sferrazza

2011 ◽  
Vol 44 (22) ◽  
pp. 9040-9045 ◽  
Author(s):  
Jessica M. Torres ◽  
Chengqing Wang ◽  
E. Bryan Coughlin ◽  
John P. Bishop ◽  
Richard A. Register ◽  
...  

2009 ◽  
Vol 55 (5(1)) ◽  
pp. 1780-1784
Author(s):  
Sang-Jin Cho ◽  
In-Seob Bae ◽  
Jin-Hyo Boo ◽  
Sungwoo Lee ◽  
Donggeun Jung

2013 ◽  
Vol 748 ◽  
pp. 165-169 ◽  
Author(s):  
M. Rahmah Siti ◽  
Anika Zafiah M. Rus ◽  
S. Nurulsaidatulsyida ◽  
D.A. Talib ◽  
T.M.Y.S. Tuan Ya

This study reports on the effect of UV-light on the mechanical properties of bio polymer thin films (BPF) doped with 10 % Titanium Dioxide (TiO2). Bio monomer was mixed with 4, 4-methylenebis (phenylisocyanate) (MDI) to produce neat BPF and TiO2 was added to form BPF doped with 10 % TiO2. The film samples were irradiated in UV Accelerated Weatherometer at 50 °C with different exposure time. Universal Testing Machine was used to measure the tensile strength and the fracture surfaces of the tensile specimens were observed by Scanning Electron Microscopy (SEM). The maximum tensile strength of UV irradiated neat BPF is lower than BPF doped with 10 % TiO2 of 3.5 MPa and 4.2 MPa respectively. Stress of neat BPF was decreased from 3.7 MPa to 3.2 MPa after 144 hours of UV exposure at 50 °C while BPF doped with 10 % TiO2 decrease from 4.7 to 3.6 MPa. The Modulus Young of neat BPF is lower than BPF doped with 10 % TiO2 which are 0.32 GPa and 0.33 GPa respectively. The cumulative strain percentage irradiated neat BPF is lower than BPF doped with 10 % TiO2 with 98.7 % and 113.7 % respectively. Unexposed UV light of neat BPF and BPF doped with 10 % TiO2 were observed by SEM shows smooth fracture and brittle fracture respectively. Neat BPF and BPF doped with 10 % TiO2 exposed to UV light show higher ductility property as compared to unexposed BPF. The higher the exposure time of BPF to UV light, revealed systematic increment of tensile strength due to increased crosslink between isocyanate and hydroxyl group.


2005 ◽  
Vol 122 (14) ◽  
pp. 144712 ◽  
Author(s):  
Kenji Yoshimoto ◽  
Tushar S. Jain ◽  
Paul F. Nealey ◽  
Juan J. de Pablo

2018 ◽  
Vol 21 (8) ◽  
pp. 817-824 ◽  
Author(s):  
Jinho Hyon ◽  
Olawale Lawal ◽  
Omri Fried ◽  
Ramathasan Thevamaran ◽  
Sadegh Yazdi ◽  
...  

2016 ◽  
Vol 2016 (0) ◽  
pp. 353
Author(s):  
Katsumi FUKUDA ◽  
Mitsuo KOBAYASHI ◽  
Kenji SUZUKI ◽  
Jun ONOE ◽  
Masato NAKAYA ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 935
Author(s):  
Youngmin Lee ◽  
Alfred Mongare ◽  
Aaron Plant ◽  
Donghyeon Ryu

Mechano-optoelectronic (MO) behavior indicates changes in optoelectronic properties in response to the applied mechanical deformation. The MO behavior can be employed to monitor the mechanical deformation of a targeted system by tracing its optoelectronic properties. Poly(3-hexylthiophene) and phenyl-C61-butyric acid methyl ester (P3HT/PCBM) blend thin films exhibited changes in direct current under tensile strain. Although optoelectronic properties and photovoltaic performance of P3HT/PCBM blends have been studied extensively and intensively, research required for MO properties has a fundamental difference from previous research mostly for solar cells. In research for MO systems, a greater extent of changes in optoelectronic properties under mechanical deformation is favorable. Herein, previous research for optoelectronic properties and mechanical properties of conjugated polymers will be reviewed from a perspective on MO properties. The microstructure of a conjugated polymer thin film plays a pivotal role in its optoelectronic properties and mechanical properties. Key parameters involved in the microstructure of conjugated polymer thin films will be addressed. A scalable process is required to broaden applications of MO systems. Potential challenges in the fabrication of MO conjugated polymer thin films will be discussed. Finally, this review is envisioned to provide insight into the design and manufacturing of MO conjugated polymer thin films.


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