Effect of Concentration on the Dissolution of One-Dimensional Polymer Crystals: A TEM and NMR Study

2018 ◽  
Vol 52 (1) ◽  
pp. 208-216 ◽  
Author(s):  
Gerald Guerin ◽  
Gregory Molev ◽  
Dmitry Pichugin ◽  
Paul A. Rupar ◽  
Fei Qi ◽  
...  
1986 ◽  
Vol 18-19 ◽  
pp. 878-882 ◽  
Author(s):  
Y ONODA ◽  
Y FUJIKI ◽  
S YOSHIKADO ◽  
T OHACHI ◽  
I TANIGUCHI

2017 ◽  
Vol 828 ◽  
pp. 012015
Author(s):  
R. Uesugi ◽  
M. Akaki ◽  
M. Hagiwara ◽  
H. Kuwahara ◽  
T. Goto
Keyword(s):  

2013 ◽  
Vol 63 (3) ◽  
pp. 739-742
Author(s):  
Yukiichi Ideta ◽  
Yu Kawasaki ◽  
Yutaka Kishimoto ◽  
Takashi Ohno ◽  
Yoshitaka Michihiro ◽  
...  
Keyword(s):  
51V Nmr ◽  

2016 ◽  
Vol 72 (9) ◽  
pp. 685-691
Author(s):  
Nutalapati Venkatramaiah ◽  
Ricardo F. Mendes ◽  
Artur M. S. Silva ◽  
João P. C. Tomé ◽  
Filipe A. Almeida Paz

The preparation of coordination polymers (CPs) based on either transition metal centres or rare-earth cations has grown considerably in recent decades. The different coordination chemistry of these metals allied to the use of a large variety of organic linkers has led to an amazing structural diversity. Most of these compounds are based on carboxylic acids or nitrogen-containing ligands. More recently, a wide range of molecules containing phosphonic acid groups have been reported. For the particular case of Ca2+-based CPs, some interesting functional materials have been reported. A novel one-dimensional Ca2+-based coordination polymer with a new organic linker, namely poly[[diaqua[μ4-(4,5-dicyano-1,2-phenylene)bis(phosphonato)][μ3-(4,5-dicyano-1,2-phenylene)bis(phosphonato)]dicalcium(II)] tetrahydrate], {[Ca2(C8H4N2O6P2)2(H2O)2]·4H2O}n, has been prepared at ambient temperature. The crystal structure features one-dimensional ladder-like∞1[Ca2(H2cpp)2(H2O)2] polymers [H2cpp is (4,5-dicyano-1,2-phenylene)bis(phosphonate)], which are created by two distinct coordination modes of the anionic H2cpp2−cyanophosphonate organic linkers: while one molecule is only bound to Ca2+cationsviathe phosphonate groups, the other establishes an extra single connectionviaa cyano group. Ladders close pack with water molecules through an extensive network of strong and highly directional O—H...O and O—H...N hydrogen bonds; the observed donor–acceptor distances range from 2.499 (5) to 3.004 (6) Å and the interaction angles were found in the range 135–178°. One water molecule was found to be disordered over three distinct crystallographic positions. A detailed solution-state NMR study of the organic linker is also provided.


2007 ◽  
Vol 310 (2) ◽  
pp. 1122-1124 ◽  
Author(s):  
Masayuki Itoh ◽  
Ichihiro Yamauchi ◽  
Tomokazu Kozuka ◽  
Tomoyuki Suzuki ◽  
Touru Yamauchi ◽  
...  

2012 ◽  
Vol 344 ◽  
pp. 012026
Author(s):  
K Nishiyama ◽  
T Mito ◽  
Y Kujirai ◽  
T Koyama ◽  
K Ueda ◽  
...  

1988 ◽  
Vol 28-30 ◽  
pp. 179-184 ◽  
Author(s):  
Y. Onoda ◽  
M. Watanabe ◽  
Y. Fujiki ◽  
Y. Kudo ◽  
T. Erata ◽  
...  

1975 ◽  
Vol 16 (5) ◽  
pp. 655-657 ◽  
Author(s):  
W.H.-G. Müller ◽  
H. Niedoba ◽  
D. Jérome
Keyword(s):  

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