Relating Chemical Structure to Toughness via Morphology Control in Fully Sustainable Sebacic Acid Cured Epoxidized Soybean Oil Toughened Polylactide Blends

2018 ◽  
Vol 51 (5) ◽  
pp. 2027-2037 ◽  
Author(s):  
Tong-Hui Zhao ◽  
Wen-Qiang Yuan ◽  
Yi-Dong Li ◽  
Yun-Xuan Weng ◽  
Jian-Bing Zeng
Keyword(s):  
Soybean Oil ◽  
Chemical Structure ◽  
Sebacic Acid ◽  
Morphology Control ◽  
Epoxidized Soybean Oil

scholarly journals Bio-Based Coating Materials Derived from Acetoacetylated Soybean Oil and Aromatic Dicarboxaldehydes

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1809 ◽  
Author(s):  
Zhiyuan Cao ◽  
Fei Gao ◽  
Jinze Zhao ◽  
Xiao Wei ◽  
Qian Cheng ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Chemical Structure ◽  
Knoevenagel Condensation ◽  
Condensation Reaction ◽  
Gel Permeation Chromatography ◽  
Epoxidized Soybean Oil ◽  
Raw Material ◽  
Coating Materials ◽  
Elongation At Break ◽  
Knoevenagel Condensation Reaction

Bio-based coating materials were prepared from epoxidized soybean oil as a renewable source. Acetoacetylated soybean oil was synthesized by the ring-opened and transesterification reaction of epoxidized soybean oil, and its chemical structure was characterized by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), and rheometric viscosity analyses. On the basis of acetoacetylated soybean oil, several bio-based coating materials were prepared using different aromatic dicarboxaldehydes (1,2-benzenedialdehyde, 1,3-benzenedialdehyde, 1,4-phthalaldehyde, 4,4′-biphenyldicarboxaldehyde) and characterized. The resulting films possess good performance, including the highest glass transition temperature of 54 °C, a Young’s modulus of 24.91 MPa, tensile strength of 5.65 MPa, and an elongation at break of 286%. Thus, this work demonstrates the Knoevenagel condensation reaction, which is based on soybean oil as a potential newer eco-friendly raw material.

Preparation and Characterization of Soybean Oil-based Flame Retardant Rigid Polyurethane Foams Containing Phosphaphenanthrene Groups

2020 ◽  
Vol 17 (10) ◽  
pp. 760-771
Author(s):  
Qirui Gong ◽  
Niangui Wang ◽  
Kaibo Zhang ◽  
Shizhao Huang ◽  
Yuhan Wang
Keyword(s):  
Soybean Oil ◽  
Flame Retardant ◽  
Chemical Structure ◽  
Cell Structure ◽  
Polyurethane Foams ◽  
Limiting Oxygen Index ◽  
Rigid Polyurethane Foams ◽  
Degradation Activation Energy ◽  
Ft Ir

A phosphaphenanthrene groups containing soybean oil based polyol (DSBP) was synthesized by epoxidized soybean oil (ESO) and 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide (DOPO). Soybean oil based polyol (HSBP) was synthesized by ESO and H2O. The chemical structure of DSBP and HSBP were characterized with FT-IR and 1H NMR. The corresponding rigid polyurethane foams (RPUFs) were prepared by mixing DSBP with HSBP. The results revealed apparent density and compression strength of RPUFs decreased with increasing the DSBP content. The cell structure of RPUFs was examined by scanning electron microscope (SEM) which displayed the cells as spherical or polyhedral. The thermal degradation and flame retardancy of RPUFs were investigated by thermogravimetric analysis, limiting oxygen index (LOI), and UL 94 vertical burning test. The degradation activation energy (Ea) of first degradation stage reduced from 80.05 kJ/mol to 37.84 kJ/mol with 80 wt% DSBP. The RUPF with 80 wt% DSBP achieved UL94 V-0 rating and LOI 28.3. The results showed that the flame retardant effect was mainly in both gas phase and condensed phase.

Properties of Biobased Epoxy Resins from Epoxidized Soybean Oil (ESBO) Cured with Maleic Anhydride (MA)

2012 ◽  
Vol 89 (11) ◽  
pp. 2067-2075 ◽  
Author(s):  
J. M. España ◽  
L. Sánchez-Nacher ◽  
T. Boronat ◽  
V. Fombuena ◽  
R. Balart
Keyword(s):  
Maleic Anhydride ◽  
Soybean Oil ◽  
Epoxy Resins ◽  
Epoxidized Soybean Oil

Highly epoxidized soybean oil in replacement of mineral oil for high performance on silica-filled tread rubber compounds

2021 ◽  
pp. 009524432110290
Author(s):  
Leandro Hernán Esposito ◽  
Angel José Marzocca
Keyword(s):  
Soybean Oil ◽  
High Performance ◽  
Rolling Resistance ◽  
Wear Test ◽  
Mineral Oil ◽  
Epoxidized Soybean Oil ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Compound ◽  
The Impact

The potential replacement of a treated residual aromatic extract mineral oil (TRAE) by a highly epoxidized soybean oil (ESO) into a silica-filled styrene-butadiene rubber compound was investigated. In order to determine if ESO compounds performance are suitable for tread tire applications, processing properties cure and characteristics were evaluated. The impact of ESO amount on the silica dispersion was confirmed by Payne Effect. The presence of chemical or physical interactions between ESO and silica improves the filler dispersion, enabling the compound processability and affecting the cure kinetic rate. An adjusted rubber compound with 2 phr of ESO and 2 phr of sulfur presented the higher stiffness and strength values with lower weight loss from a wear test compared with TRAE compound at an equal amount of oil and curing package. Furthermore, wet grip and rolling resistance predictors of both compounds gave comparable results, maintaining a better performance and reducing the dependence of mineral oil for tire tread compounds.

Biobased, Biodegradable, Self-Healing Boronic Ester Vitrimers from Epoxidized Soybean Oil Acrylate

2020 ◽  
Author(s):  
Arkadiusz Zych ◽  
Jonathan Tellers ◽  
Laura Bertolacci ◽  
Luca Ceseracciu ◽  
Lara Marini ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Epoxidized Soybean Oil ◽  
Self Healing ◽  
Boronic Ester
Sign in / Sign up

Export Citation Format

Share Document