Viscoelastic Behavior of Unentangled POSS–Styrene Nanocomposites and the Modification of Macromolecular Dynamics

2017 ◽  
Vol 50 (18) ◽  
pp. 7177-7189 ◽  
Author(s):  
Angel Romo-Uribe
Keyword(s):  
Viscoelastic Behavior ◽  
Macromolecular Dynamics

Nonlinear Viscoelastic Finite Element Analysis of Adhesive Joints

1988 ◽  
Vol 16 (3) ◽  
pp. 146-170 ◽  
Author(s):  
S. Roy ◽  
J. N. Reddy
Keyword(s):  
Finite Element Analysis ◽  
Finite Element ◽  
Viscoelastic Behavior ◽  
Bonded Joints ◽  
Adhesively Bonded ◽  
Element Analysis ◽  
Adhesively Bonded Joints ◽  
Nonlinear Viscoelastic ◽  
Structural Failures ◽  
Updated Lagrangian

Abstract A good understanding of the process of adhesion from the mechanics viewpoint and the predictive capability for structural failures associated with adhesively bonded joints require a realistic modeling (both constitutive and kinematic) of the constituent materials. The present investigation deals with the development of an Updated Lagrangian formulation and the associated finite element analysis of adhesively bonded joints. The formulation accounts for the geometric nonlinearity of the adherends and the nonlinear viscoelastic behavior of the adhesive. Sample numerical problems are presented to show the stress and strain distributions in bonded joints.

Influence of κ-Carrageenan, Modified Starch and Inulin Addition on Rheological and Sensory Properties of Non-fat and Non-added Sugar Dairy Dessert

2020 ◽  
Vol 16 (4) ◽  
pp. 462-469
Author(s):  
Zhaleh Sheidaei ◽  
Bahareh Sarmadi ◽  
Seyede M. Hosseini ◽  
Fardin Javanmardi ◽  
Kianoush Khosravi-Darani ◽  
...  
Keyword(s):  
Storage Modulus ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Textural Properties ◽  
Complex Viscosity ◽  
Sensory Properties ◽  
Modified Starch ◽  
Consumer Health ◽  
Added Sugar ◽  
Textural Parameters

<P>Background: The high amounts of fat, sugar and calorie existing in dairy desserts can lead to increase the risk of health problems. Therefore, the development of functional and dietary forms of these products can help the consumer health. </P><P> Objective: This study aims to investigate the effects of &#954;-carrageenan, modified starch and inulin addition on rheological and sensory properties of non-fat and non-added sugar dairy dessert. </P><P> Methods: In order to determine the viscoelastic behavior of samples, oscillatory test was carried out and the values of storage modulus (G′), loss modulus (G″), loss angle tangent (tan &#948;) and complex viscosity (&#951;*) were measured. TPA test was used for analysis of the desserts’ texture and textural parameters of samples containing different concentrations of carrageenan, starch and inulin were calculated. </P><P> Results: All treatments showed a viscoelastic gel structure with the storage modulus higher than the loss modulus values. Increasing amounts of &#954;-carrageenan and modified starch caused an increase in G′ and G″ as well as &#951;* and a decrease in tan &#948;. Also, firmness and cohesiveness were enhanced. The trained panelists gave the highest score to the treatment with 0.1% &#954;-carrageenan, 2.5% starch and 5.5% inulin (sucralose as constant = 0.25%) and this sample was the best treatment with desirable attributes for the production of non-fat and non-added sugar dairy dessert. </P><P> Conclusion: It can be concluded that the concentration of &#954;-carrageenan and starch strongly influenced the rheological and textural properties of dairy desserts, whereas the inulin content had little effect on these attributes.</P>

scholarly journals Thermo-Viscoelastic Response of 3D Braided Composites Based on a Novel FsMsFE Method

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 271
Author(s):  
Jun-Jun Zhai ◽  
Xiang-Xia Kong ◽  
Lu-Chen Wang
Keyword(s):  
Finite Element ◽  
Cell Model ◽  
Structural Parameters ◽  
Thermal Relaxation ◽  
Viscoelastic Behavior ◽  
Unit Cell ◽  
Time Dependent ◽  
3D Braided Composites ◽  
Equivalent Time ◽  
Representative Unit Cell

A homogenization-based five-step multi-scale finite element (FsMsFE) simulation framework is developed to describe the time-temperature-dependent viscoelastic behavior of 3D braided four-directional composites. The current analysis was performed via three-scale finite element models, the fiber/matrix (microscopic) representative unit cell (RUC) model, the yarn/matrix (mesoscopic) representative unit cell model, and the macroscopic solid model with homogeneous property. Coupling the time-temperature equivalence principle, multi-phase finite element approach, Laplace transformation and Prony series fitting technology, the character of the stress relaxation behaviors at three scales subject to variation in temperature is investigated, and the equivalent time-dependent thermal expansion coefficients (TTEC), the equivalent time-dependent thermal relaxation modulus (TTRM) under micro-scale and meso-scale were predicted. Furthermore, the impacts of temperature, structural parameters and relaxation time on the time-dependent thermo-viscoelastic properties of 3D braided four-directional composites were studied.

scholarly journals A Highly Versatile Polymer Network Based on Liquid Crystalline Dendrimers

2021 ◽  
Vol 22 (11) ◽  
pp. 5740
Author(s):  
Ramón Cervera-Procas ◽  
José-Luis Serrano ◽  
Ana Omenat
Keyword(s):  
Smart Materials ◽  
Liquid Crystalline ◽  
Organic Dyes ◽  
Polymer Network ◽  
Viscoelastic Behavior ◽  
Diverse Range ◽  
Polymeric Systems ◽  
System A ◽  
Porous Microstructure ◽  
Solvent Molecules

Highly functional macromolecules with a well-defined architecture are the key to designing efficient and smart materials, and these polymeric systems can be tailored for specific applications in a diverse range of fields. Herein, the formation of a new liquid crystalline polymeric network based on the crosslinking of dendrimeric entities by the CuI-catalyzed variant of the Huisgen 1,3-dipolar cycloaddition of azides and alkynes to afford 1,2,3-triazoles is reported. The polymeric material obtained in this way is easy to process and exhibits a variety of properties, which include mesomorphism, viscoelastic behavior, and thermal contraction. The porous microstructure of the polymer network determines its capability to absorb solvent molecules and to encapsulate small molecules, like organic dyes, which can be released easily afterwards. Moreover, all these properties may be easily tuned by modifying the chemical structure of the constituent dendrimers, which makes this system a very interesting one for a number of applications.

Mesomechanical prediction of viscoelastic behavior of asphalt concrete considering effect of aggregate shape

2021 ◽  
Vol 274 ◽  
pp. 122096
Author(s):  
Yiren Sun ◽  
Zhuang Zhang ◽  
Xin Wei ◽  
Cong Du ◽  
Mingyang Gong ◽  
...  
Keyword(s):  
Asphalt Concrete ◽  
Viscoelastic Behavior ◽  
Aggregate Shape

Viscoelastic behavior of suspensions of reduced graphene oxide nanoparticles in epoxy

2021 ◽  
Vol 119 (4) ◽  
pp. 041901
Author(s):  
M. Majidian ◽  
A. Magrez ◽  
L. Forró ◽  
Y. Leterrier
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Viscoelastic Behavior ◽  
Oxide Nanoparticles ◽  
Reduced Graphene

scholarly journals 3D Plotting of Silica/Collagen Xerogel Granules in an Alginate Matrix for Tissue-Engineered Bone Implants

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 830
Author(s):  
Sina Rößler ◽  
Andreas Brückner ◽  
Iris Kruppke ◽  
Hans-Peter Wiesmann ◽  
Thomas Hanke ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Bone Regeneration ◽  
Material Properties ◽  
Viscoelastic Properties ◽  
Viscoelastic Behavior ◽  
Matrix Phase ◽  
Patient Specific ◽  
Active Player ◽  
Alginate Concentration ◽  
Alginate Matrix

Today, materials designed for bone regeneration are requested to be degradable and resorbable, bioactive, porous, and osteoconductive, as well as to be an active player in the bone-remodeling process. Multiphasic silica/collagen Xerogels were shown, earlier, to meet these requirements. The aim of the present study was to use these excellent material properties of silica/collagen Xerogels and to process them by additive manufacturing, in this case 3D plotting, to generate implants matching patient specific shapes of fractures or lesions. The concept is to have Xerogel granules as active major components embedded, to a large proportion, in a matrix that binds the granules in the scaffold. By using viscoelastic alginate as matrix, pastes of Xerogel granules were processed via 3D plotting. Moreover, alginate concentration was shown to be the key to a high content of irregularly shaped Xerogel granules embedded in a minimum of matrix phase. Both the alginate matrix and Xerogel granules were also shown to influence viscoelastic behavior of the paste, as well as the dimensionally stability of the scaffolds. In conclusion, 3D plotting of Xerogel granules was successfully established by using viscoelastic properties of alginate as matrix phase.

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