Precise Synthesis of New Exactly Defined Graft Copolymers Made up of Poly(alkyl methacrylate)s by Iterative Methodology Using Living Anionic Polymerization

2015 ◽  
Vol 48 (22) ◽  
pp. 8307-8314 ◽  
Author(s):  
Shotaro Ito ◽  
Takashi Ishizone ◽  
Akira Hirao
Keyword(s):  
Anionic Polymerization ◽  
Graft Copolymers ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate

scholarly journals A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16049-16056 ◽  
Author(s):  
Zheng Li ◽  
Jianding Chen ◽  
Guijin Zou ◽  
Tongyuan Zhang ◽  
Dafu Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Synthesis Method ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate ◽  
High Yields

A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .

International Rubber Science Hall of Fame Inductee

2008 ◽  
Vol 81 (2) ◽  
pp. 1-6
Author(s):  
Geoff Holden
Keyword(s):  
Anionic Polymerization ◽  
Graft Copolymers ◽  
Polymeric Materials ◽  
Thermoplastic Elastomer ◽  
Polymer Science ◽  
Living Anionic Polymerization ◽  
New Class ◽  
Vulcanized Rubber ◽  
Hall Of Fame ◽  
American Scientist

Abstract Citation* - American scientist, chemist. Dr. Ralph Milkovich was a pioneer in anionic polymerization and heterophase polymer science. He demonstrated the concept of living anionic polymerization. He prepared the first poly(styrene-block-isoprene-block-styrene) thermoplastic elastomer, exhibiting the properties of a vulcanized rubber but processible as a thermoplastic. He also prepared a new class of polymeric materials, macromonomers, useful for the syntheses of well-defined, comb-type graft copolymers.

Synthesis of well-defined graft copolymers via coupled living anionic polymerization and living ROMP

Polymer ◽  
1998 ◽  
Vol 39 (25) ◽  
pp. 6605-6610 ◽  
Author(s):  
A.C.M Rizmi ◽  
E Khosravi ◽  
W.J Feast ◽  
M.A Mohsin ◽  
A.F Johnson
Keyword(s):  
Anionic Polymerization ◽  
Graft Copolymers ◽  
Living Anionic Polymerization

Living Anionic Polymerization of 4-Halostyrenes

2021 ◽  
Vol 54 (3) ◽  
pp. 1489-1498
Author(s):  
Raita Goseki ◽  
Taro Koizumi ◽  
Reina Kurakake ◽  
Satoshi Uchida ◽  
Takashi Ishizone
Keyword(s):  
Anionic Polymerization ◽  
Living Anionic Polymerization
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