scholarly journals Tuning the Gelation of Thermoresponsive Gels Based on Triblock Terpolymers

2021 ◽  
Vol 54 (4) ◽  
pp. 1943-1960
Author(s):  
Anna P. Constantinou ◽  
Beini Zhan ◽  
Theoni K. Georgiou
Keyword(s):  
Triblock Terpolymers

Microphase separation and crystallization behaviors of bi-phased triblock terpolymers with a competitively dissolved middle block

Polymer ◽  
2017 ◽  
Vol 117 ◽  
pp. 140-149 ◽  
Author(s):  
Rui-Yang Wang ◽  
Xiang-Yue Wang ◽  
Bin Fan ◽  
Jun-Ting Xu ◽  
Zhi-Qiang Fan
Keyword(s):  
Microphase Separation ◽  
Crystallization Behaviors ◽  
Triblock Terpolymers

Multiarm star triblock terpolymers via sequential double click reactions

2010 ◽  
Vol 48 (7) ◽  
pp. 1557-1564 ◽  
Author(s):  
Hakan Durmaz ◽  
Aydan Dag ◽  
Duygu Gursoy ◽  
A. Levent Demirel ◽  
Gurkan Hizal ◽  
...  
Keyword(s):  
Click Reactions ◽  
Triblock Terpolymers

scholarly journals Hierarchical Self-Assembly of Supramolecular Double-Comb Triblock Terpolymers

2018 ◽  
Vol 7 (10) ◽  
pp. 1168-1173 ◽  
Author(s):  
Anton H. Hofman ◽  
Ivan Terzic ◽  
Marc C. A. Stuart ◽  
Gerrit ten Brinke ◽  
Katja Loos
Keyword(s):  
Self Assembly ◽  
Triblock Terpolymers

scholarly journals Morphology and Degradation of Multicompartment Microparticles Based on Semi-Crystalline Polystyrene-block-Polybutadiene-block-Poly(L-lactide) Triblock Terpolymers

Polymers ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 4358
Author(s):  
Nicole Janoszka ◽  
Suna Azhdari ◽  
Christian Hils ◽  
Deniz Coban ◽  
Holger Schmalz ◽  
...  
Keyword(s):  
Cross Sections ◽  
Ring Opening ◽  
Particle Diameter ◽  
Average Particle ◽  
Average Particle Diameter ◽  
Selective Degradation ◽  
The Core ◽  
Transmission Electron ◽  
And Control ◽  
Triblock Terpolymers

The confinement assembly of block copolymers shows great potential regarding the formation of functional microparticles with compartmentalized structure. Although a large variety of block chemistries have already been used, less is known about microdomain degradation, which could lead to mesoporous microparticles with particularly complex morphologies for ABC triblock terpolymers. Here, we report on the formation of triblock terpolymer-based, multicompartment microparticles (MMs) and the selective degradation of domains into mesoporous microparticles. A series of polystyrene-block-polybutadiene-block-poly(L-lactide) (PS-b-PB-b-PLLA, SBL) triblock terpolymers was synthesized by a combination of anionic vinyl and ring-opening polymerization, which were transformed into microparticles through evaporation-induced confinement assembly. Despite different block compositions and the presence of a crystallizable PLLA block, we mainly identified hexagonally packed cylinders with a PLLA core and PB shell embedded in a PS matrix. Emulsions were prepared with Shirasu Porous Glass (SPG) membranes leading to a narrow size distribution of the microparticles and control of the average particle diameter, d ≈ 0.4 µm–1.8 µm. The core–shell cylinders lie parallel to the surface for particle diameters d < 0.5 µm and progressively more perpendicular for larger particles d > 0.8 µm as verified with scanning and transmission electron microscopy and particle cross-sections. Finally, the selective degradation of the PLLA cylinders under basic conditions resulted in mesoporous microparticles with a pronounced surface roughness.

scholarly journals Confinement Assembly of ABC Triblock Terpolymers for the High-Yield Synthesis of Janus Nanorings

ACS Nano ◽  
2019 ◽  
Vol 13 (6) ◽  
pp. 6269-6278 ◽  
Author(s):  
Andrea Steinhaus ◽  
Ramzi Chakroun ◽  
Markus Müllner ◽  
Tai-Lam Nghiem ◽  
Marcus Hildebrandt ◽  
...  
Keyword(s):  
High Yield ◽  
Triblock Terpolymers

Triblock Terpolymers Bearing a Redox-Cleavable Junction and a Photo-Cross-Linkable Block

2014 ◽  
Vol 47 (15) ◽  
pp. 5115-5123 ◽  
Author(s):  
Muhammad Rabnawaz ◽  
Guojun Liu
Keyword(s):  
Triblock Terpolymers

Functionalized PEG-b-PAGE-b-PLGA triblock terpolymers as materials for nanoparticle preparation

2015 ◽  
Vol 53 (18) ◽  
pp. 2163-2174 ◽  
Author(s):  
Justyna A. Czaplewska ◽  
Tobias C. Majdanski ◽  
Markus J. Barthel ◽  
Michael Gottschaldt ◽  
Ulrich S. Schubert
Keyword(s):  
Nanoparticle Preparation ◽  
Triblock Terpolymers
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