Spectroscopic Line Shapes of Vibrational Quanta in the Presence of Molecular Resonances

2016 ◽  
Vol 7 (13) ◽  
pp. 2388-2393 ◽  
Author(s):  
Stefan Meierott ◽  
Nicolas Néel ◽  
Jörg Kröger
Keyword(s):  
Line Shapes ◽  
Molecular Resonances

scholarly journals Molecular Resonances Observed in the Predissociation of Cs2

1995 ◽  
Vol 16 (1) ◽  
pp. 19-29 ◽  
Author(s):  
Bongsoo Kim ◽  
Keitaro Yoshihara
Keyword(s):  
Molecular Beam ◽  
Shape Parameter ◽  
Supersonic Jet ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Line Shapes ◽  
Sign Change ◽  
Source State ◽  
Molecular Resonances ◽  
Line Shape Parameter

Very cold molecular beam of Cs2 is generated by a high temperature supersonic jet source. State-specific photofragment yield spectrum is obtained in the orange band of Cs2. Asymmetric line shapes are observed. The Fano line shape parameter, q, shows a gradual sign change, which is called “q-reversal”. A very broad absorption band which has about 50 cm-1 width is observed and explained to occur through the perturbation by the D1∑u+ state. The complex resonance line shapes are attributed to the interfering resonances.

H NMR Evidence for a Change in The Local Hydrogen Environment of Sites Associated with the Staebler-Wronski Effect in a-Si:H

2002 ◽  
Vol 715 ◽  
Author(s):  
T. Su ◽  
Robin Plachy ◽  
P. C. Taylor ◽  
S. Stone ◽  
G. Ganguly ◽  
...  
Keyword(s):  
Line Shape ◽  
Defect Density ◽  
Hydrogen Atoms ◽  
Hydrogen Environment ◽  
H Nmr ◽  
Line Shapes ◽  
Different Temperatures ◽  
Staebler Wronski Effect

AbstractWe study the H NMR line shapes of a sample of a-Si:H under several conditions: 1) as grown, 2) light-soaked for 600 hours, and 3) light-soaked followed by annealing at different temperatures. At T = 7 K, the NMR line shape of the sample after light soaking exhibits an additional doublet compared to that of the sample as-grown. This doublet is an indication of a closely separated hydrogen pair. The distance between the two hydrogen atoms is estimated to be about (2.3 ± 0.2) Å. The concentration of these hydrogen sites is estimated to be between 1017 and 1018 cm-3 consistent with ESR measurements of the defect density after light soaking. This doublet disappears after the sample is annealed at 200°C for 4 hours.

Testing the Planet Hypothesis: A Search for Variability in the Spectral‐Line Shapes of 51 Pegasi

1997 ◽  
Vol 478 (1) ◽  
pp. 374-380 ◽  
Author(s):  
Artie P. Hatzes ◽  
William D. Cochran ◽  
Christopher M. Johns‐Krull
Keyword(s):  
Spectral Line ◽  
Line Shapes

scholarly journals High-Resolution Photoabsorption Spectrum of Cs+ (5p61So + 5p5ns, nd) Between 504A and 600A using a Laser Ionized Cs Vapor Column

1984 ◽  
Vol 86 ◽  
pp. 124-124
Author(s):  
T.J. McIlrath ◽  
V. Kaufman ◽  
J. Sugar ◽  
W.T. Hill ◽  
D. Cooper
Keyword(s):  
High Resolution ◽  
Laser Pulse ◽  
High Voltage ◽  
Power Output ◽  
Random Phase ◽  
Grazing Incidence ◽  
Fano Resonances ◽  
Line Shapes ◽  
Phase Calculation ◽  
Photoabsorption Spectrum

Rapid ionization of Cs vapor in a heat pipe at 0.05 torr was achieved by pumping the 6s 2S½ – 7p 2P½ transition (f=0.007)1 with a flash-pumped dye laser at 4593.2A and I MW power output. Photoabsorptian initiated at the end of the laser pulse(≃ 0.5/s) showed the 5p5ns and nd series below and above the 5p52P3/2 threshold at 535.4A. Broad Beutler - Fano resonances appeared in the d series above threshold. The spectrum was recorded photographically on a 10.7m grazing incidence spectrograph using a continuum background generated by a BRV high-voltage spark source with a uranium anode. We will compare the line-shapes and the quantum defect (Lu-Fano2) plot with the predictions of a relativistic random phase calculation.

Critical Raman line shape behavior of fluid nitrogen

2004 ◽  
Vol 76 (1) ◽  
pp. 147-155 ◽  
Author(s):  
M. Musso ◽  
F. Matthai ◽  
D. Keutel ◽  
K.-L. Oehme
Keyword(s):  
Raman Line ◽  
Line Shape ◽  
Line Broadening ◽  
Vibrational Resonance ◽  
Critical Isochore ◽  
Molecular Fluids ◽  
Detection Techniques ◽  
Gas Phases ◽  
Line Shapes ◽  
Band Position

Isotropic Raman line shapes of simple molecular fluids exhibit critical line broadening near their respective liquid-gas critical points. In order to observe this phenomenon, it is essential that the band position of a given vibrational mode is density-dependent, and that vibrational depopulation processes negligibly contribute to line broadening. Special attention was given to the fact that the isotropic (i.e., nonrotationally broadened) line shape of liquid N2 is affected by resonant intermolecular vibrational interactions between identical oscillators. By means of the well-chosen isotopic mixture (14N2).975 - (14N15N).025, the temperature and density dependences of shift, width, and asymmetry of the resonantly coupled 14N2 and, depending on the S/N ratio available, of the resonantly uncoupled 14N15N were determined, with up to milli-Kelvin resolution, in the coexisting liquid and gas phases and along the critical isochore, using a highest-resolution double monochromator and modern charge-coupled device detection techniques. Clear evidence was found that vibrational resonance couplings are present in all dense phases studied.

scholarly journals From the Vector to Scalar Perturbations Addition in the Stark Broadening Theory of Spectral Lines

Universe ◽  
2021 ◽  
Vol 7 (6) ◽  
pp. 176
Author(s):  
Valery Astapenko ◽  
Andrei Letunov ◽  
Valery Lisitsa
Keyword(s):  
Spectral Line ◽  
Stark Effect ◽  
Coulomb Field ◽  
Spectral Lines ◽  
Alternative Methods ◽  
Scalar Perturbation ◽  
Numerical Comparison ◽  
Line Shapes ◽  
Stark Effects ◽  
The Impact

The effect of plasma Coulomb microfied dynamics on spectral line shapes is under consideration. The analytical solution of the problem is unachievable with famous Chandrasekhar–Von-Neumann results up to the present time. The alternative methods are connected with modeling of a real ion Coulomb field dynamics by approximate models. One of the most accurate theories of ions dynamics effect on line shapes in plasmas is the Frequency Fluctuation Model (FFM) tested by the comparison with plasma microfield numerical simulations. The goal of the present paper is to make a detailed comparison of the FFM results with analytical ones for the linear and quadratic Stark effects in different limiting cases. The main problem is connected with perturbation additions laws known to be vector for small particle velocities (static line shapes) and scalar for large velocities (the impact limit). The general solutions for line shapes known in the frame of scalar perturbation additions are used to test the FFM procedure. The difference between “scalar” and “vector” models is demonstrated both for linear and quadratic Stark effects. It is shown that correct transition from static to impact limits for linear Stark-effect needs in account of the dependence of electric field jumping frequency in FFM on the field strengths. However, the constant jumping frequency is quite satisfactory for description of the quadratic Stark-effect. The detailed numerical comparison for spectral line shapes in the frame of both scalar and vector perturbation additions with and without jumping frequency field dependence for the linear and quadratic Stark effects is presented.

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