scholarly journals Low-Cost Synthesis of Silicon Quantum Dots with Near-Unity Internal Quantum Efficiency

Author(s):  
Jingjian Zhou ◽  
Jing Huang ◽  
Huai Chen ◽  
Archana Samanta ◽  
Jan Linnros ◽  
...  
2016 ◽  
Vol 8 (1) ◽  
pp. 86-89 ◽  
Author(s):  
Young-In Lee ◽  
Bum-Sung Kim ◽  
Soyeong Joo ◽  
Woo-Byoung Kim

Crystals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1097
Author(s):  
Julien Brault ◽  
Mohamed Al Khalfioui ◽  
Samuel Matta ◽  
Thi Huong Ngo ◽  
Sébastien Chenot ◽  
...  

AlGaN based light emitting diodes (LEDs) will play a key role for the development of applications in the ultra-violet (UV). In the UVB region (280–320 nm), phototherapy and plant lighting are among the targeted uses. However, UVB LED performances still need to be improved to reach commercial markets. In particular, the design and the fabrication process of the active region are central elements that affect the LED internal quantum efficiency (IQE). We propose the use of nanometer-sized epitaxial islands (i.e., so called quantum dots (QDs)) to enhance the carrier localization and improve the IQE of molecular beam epitaxy (MBE) grown UVB LEDs using sapphire substrates with thin sub-µm AlN templates. Taking advantage of the epitaxial stress, AlGaN QDs with nanometer-sized (≤10 nm) lateral and vertical dimensions have been grown by MBE. The IQE of the QDs has been deduced from temperature dependent and time resolved photoluminescence measurements. Room temperature IQE values around 5 to 10% have been found in the 290–320 nm range. QD-based UVB LEDs were then fabricated and characterized by electrical and electroluminescence measurements. On-wafer measurements showed optical powers up to 0.25 mW with external quantum efficiency (EQE) values around 0.1% in the 305–320 nm range.


2018 ◽  
Vol 113 ◽  
pp. 497-501 ◽  
Author(s):  
Jianjie Liu ◽  
Zhigang Jia ◽  
Shufang Ma ◽  
Hailiang Dong ◽  
Guangmei Zhai ◽  
...  

2014 ◽  
Vol 14 (8) ◽  
pp. 5868-5872 ◽  
Author(s):  
Bomin Cho ◽  
Sangsoo Baek ◽  
Hee-Gweon Woo ◽  
Honglae Sohn

Author(s):  
Guitao Du ◽  
Guoqian Li ◽  
Shibo Qiu ◽  
Linghong Liu ◽  
Yuewei Zheng ◽  
...  

2011 ◽  
Vol 383-390 ◽  
pp. 6270-6276 ◽  
Author(s):  
Li Hao Han ◽  
Jing Wang ◽  
Ren Rong Liang

Quantum dots applied in solar cells will be of great importance to enhance the quantum tunneling efficiency and improve the photogenerated current transport. In this study, a new easy-to-operate technology was developed to fabricate germanium-silicon quantum dots in a SiOx matrix. The quantum dots were formed by first deposited germanium-rich SiO on quartz substrate using pulsed laser deposition technique and then annealed under a comparatively high temperature. We have demonstrated a stable and low-cost fabrication process which is much cheaper than the epitaxy method to provide for the fabrication of high density germanium-silicon quantum dots. Quantum dots with diameters of 3~4 nm embedded in the amorphous SiOx layer were clearly observed. The morphological features of the thin film were characterized. The optical properties were performed by Raman spectroscopy, photoluminescence spectrum and XRD test respectively to verify the crystallization of quantum dots in the SiOx matrix. Reflectance spectrum displayed a high light absorption rate in a spectra region from 300 nm to 1200 nm, evidencing that germanium-silicon quantum dots have promising features to be used as absorber for photovoltaic application.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2299
Author(s):  
Jun Deng ◽  
Zhibiao Hao ◽  
Lai Wang ◽  
Jiadong Yu ◽  
Jian Wang ◽  
...  

GaN quantum dots embedded in nanowires have attracted much attention due to their superior optical properties. However, due to the large surface-to-volume ratio of the nanowire, the impacts of surface states are the primary issue responsible for the degradation of internal quantum efficiency (IQE) in heterostructured dot-in-nanowires. In this paper, we investigate the carrier recombination mechanism of GaN/AlN dot-in-nanowires with an in situ grown AlN shell structure. Ultraviolet photoelectron spectroscopy (UPS) measurements were performed to describe the band bending effect on samples with different shell thicknesses. Temperature-dependent photoluminescence (TDPL) data support that increasing the AlN shell thickness is an efficient way to improve internal quantum efficiency. Detailed carrier dynamics was analyzed and combined with time-resolved photoluminescence (TRPL). The experimental data are consistent with our physical model that the AlN shell can effectively flatten the band bending near the surface and isolate the surface non-radiative recombination center. Our systematic research on GaN/AlN quantum dots in nanowires with a core–shell structure may significantly advance the development of a broad range of nanowire-based optoelectronic devices.


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