scholarly journals Out-of-Equilibrium Polymorph Selection in Nanoparticle Freezing

2020 ◽  
Vol 11 (19) ◽  
pp. 8060-8066
Author(s):  
Jonathan Amodeo ◽  
Fabio Pietrucci ◽  
Julien Lam
Keyword(s):  
2007 ◽  
Vol 7 (9) ◽  
pp. 1635-1642 ◽  
Author(s):  
Manish M. Parmar ◽  
Omar Khan ◽  
Linda Seton ◽  
James L. Ford

Small ◽  
2017 ◽  
Vol 13 (21) ◽  
pp. 1603100 ◽  
Author(s):  
Zhaoyong Zou ◽  
Luca Bertinetti ◽  
Yael Politi ◽  
Peter Fratzl ◽  
Wouter J. E. M. Habraken

2016 ◽  
Vol 34 (8) ◽  
pp. 1014-1020 ◽  
Author(s):  
Yao-tao Wang ◽  
Pei-ru Liu ◽  
Ying Lu ◽  
Yong-feng Men

Crystals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 351 ◽  
Author(s):  
Ziemecka ◽  
Gokalp ◽  
Stroobants ◽  
Brau ◽  
Maes ◽  
...  

The selection of polymorphs of the organic compound 5-methyl-2-[(2-nitrophenyl)amino]-3-thiophenecarbonitrile, ROY, is studied experimentally in the confined space between two horizontal glass plates when an acetone solution of ROY of variable concentration is injected at a variable flow rate into water. Depending on the local concentration within the radial flow, a polymorph selection is observed such that red prisms are favored close to the injection center while yellow needles are the preferred polymorph close to the edge of the injected ROY domain. At larger flow rates, a buoyancy-driven instability induces stripes at the outer edge of the displacement pattern, in which specific polymorphs are seen to crystallize. Our results evidence the possibility of a selection of ROY polymorph structures in out-of-equilibrium flow conditions.


2019 ◽  
Vol 19 (12) ◽  
pp. 6925-6934 ◽  
Author(s):  
Chengxiang Liu ◽  
Fengjuan Cao ◽  
Samir A. Kulkarni ◽  
Geoffrey P. F. Wood ◽  
Erik E. Santiso

CrystEngComm ◽  
2015 ◽  
Vol 17 (36) ◽  
pp. 6863-6867 ◽  
Author(s):  
Jens Kahlen ◽  
Christine Peter ◽  
Davide Donadio

Advanced simulation methods show how glutamate oligomers prestructure Ca ions and induce structural motifs in correspondence with calciumoxalate pseudopolymorphs.


CrystEngComm ◽  
2016 ◽  
Vol 18 (12) ◽  
pp. 2125-2134 ◽  
Author(s):  
Jingtan Su ◽  
Fangjie Zhu ◽  
Guiyou Zhang ◽  
Hongzhong Wang ◽  
Liping Xie ◽  
...  

Polymorph switching of calcium carbonate controlled by amorphous calcium carbonate-binding protein, an extrapallial fluid (EPF) protein from the pearl oyster, is investigated. The polymorph selection in nacre or pearl growth may be controlled not only by the nucleating template on the matrix but also by the physicochemical effects of EPF proteins.


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