scholarly journals From Collisions to Bundles: An Adaptive Coarse-Grained Model for the Aggregation of High-Aspect-Ratio Carbon Nanotubes

2020 ◽  
Vol 124 (15) ◽  
pp. 8359-8370 ◽  
Author(s):  
Nikolaos Kateris ◽  
Philipp Kloza ◽  
Rulan Qiao ◽  
James A. Elliott ◽  
Adam M. Boies
2018 ◽  
Author(s):  
Gen Hayase

By exploiting the dispersibility and rigidity of boehmite nanofibers (BNFs) with a high aspect ratio of 4 nm in diameter and several micrometers in length, multiwall-carbon nanotubes (MWCNTs) were successfully dispersed in aqueous solutions. In these sols, the MWCNTs were dispersed at a ratio of about 5–8% relative to BNFs. Self-standing BNF–nanotube films were also obtained by filtering these dispersions and showing their functionality. These films can be expected to be applied to sensing materials.


2021 ◽  
Author(s):  
Yaxiong Zhang ◽  
Erqing Xie

Carbon nanotubes (CNTs) have been widely studied as supercapacitor electrodes because of their excellent conductivity, high aspect ratio, excellent mechanical properties, chemical stability, and large specific surface area. However, the...


2010 ◽  
Vol 19 (1) ◽  
pp. 67-72 ◽  
Author(s):  
Enkeleda Dervishi ◽  
Zhongrui Li ◽  
Fumiya Watanabe ◽  
Viney Saini ◽  
Alexandru R. Biris ◽  
...  

2020 ◽  
Vol 10 (4) ◽  
pp. 1315 ◽  
Author(s):  
Artyom Plyushch ◽  
Dmitry Lyakhov ◽  
Mantas Šimėnas ◽  
Dzmitry Bychanok ◽  
Jan Macutkevič ◽  
...  

The conductivity and percolation concentration of the composite material filled with randomly distributed carbon nanotubes were simulated as a function of the mechanical deformation. Nanotubes were modelled as the hard-core ellipsoids of revolution with high aspect ratio. The evident anisotropy was observed in the percolation threshold and conductivity. The minimal mean values of the percolation of 4.6 vol. % and maximal conductivity of 0.74 S/m were found for the isotropic composite. Being slightly aligned, the composite demonstrates lower percolation concentration and conductivity along the orientation of the nanotubes compared to the perpendicular arrangement.


2016 ◽  
Vol 3 (3) ◽  
pp. 483-493 ◽  
Author(s):  
Sudjit Luanpitpong ◽  
Liying Wang ◽  
Donna C. Davidson ◽  
Heimo Riedel ◽  
Yon Rojanasakul

Review of recent advances in nanomaterial genotoxicity and carcinogenicity with a focus on lung carcinogenicity of high aspect ratio carbon nanotubes.


Nanoscale ◽  
2015 ◽  
Vol 7 (15) ◽  
pp. 6745-6753 ◽  
Author(s):  
Taeheon Lee ◽  
Byunghee Kim ◽  
Sumin Kim ◽  
Jong Hun Han ◽  
Heung Bae Jeon ◽  
...  

We synthesized p(FMA-co-DMAEMA) for the dispersion of SWCNTs while maintaining their high aspect ratios.


2018 ◽  
Vol 115 (36) ◽  
pp. 8883-8888 ◽  
Author(s):  
Chao Sun ◽  
Meng Shen ◽  
Anton D. Chavez ◽  
Austin M. Evans ◽  
Xiaolong Liu ◽  
...  

One-dimensional nanostructures such as carbon nanotubes and actin filaments rely on strong and directional interactions to stabilize their high aspect ratio shapes. This requirement has precluded making isolated, long, thin organic nanotubes by stacking molecular macrocycles, as their noncovalent stacking interactions are generally too weak. Here we report high aspect ratio (>103), lyotropic nanotubes of stacked, macrocyclic, iminium salts, which are formed by protonation of the corresponding imine-linked macrocycles. Iminium ion formation establishes cohesive interactions that, in organic solvent (tetrahydrofuran), are two orders of magnitude stronger than the neutral macrocycles, as explained by physical arguments and demonstrated by molecular dynamics simulations. Nanotube formation stabilizes the iminium ions, which otherwise rapidly hydrolyze, and is reversed and restored upon addition of bases and acids. Acids generated by irradiating a photoacid generator or sonicating chlorinated solvents also induced nanotube assembly, allowing these nanostructures to be coupled to diverse stimuli, and, once assembled, they can be fixed permanently by cross-linking their pendant alkenes. As large macrocyclic chromonic liquid crystals, these iminium salts are easily accessible through a modular design and provide a means to rationally synthesize structures that mimic the morphology and rheology of carbon nanotubes and biological tubules.


Sign in / Sign up

Export Citation Format

Share Document