Aurivillius Halide Perovskite: A New Family of Two-Dimensional Materials for Optoelectronic Applications

2019 ◽  
Vol 124 (3) ◽  
pp. 1788-1793
Author(s):  
Shuai Zhao ◽  
Chunfeng Lan ◽  
Huanhuan Li ◽  
Chu Zhang ◽  
Tingli Ma
2021 ◽  
pp. 2112277
Author(s):  
Rajesh Kumar Ulaganathan ◽  
Raghavan Chinnambedu Murugesan ◽  
Chang‐Yu Lin ◽  
Ambika Subramanian ◽  
Wei‐Liang Chen ◽  
...  

2020 ◽  
Vol 7 (8) ◽  
pp. 200456 ◽  
Author(s):  
Pritom J. Bora ◽  
T. R. Suresh Kumar ◽  
Daniel Q. Tan

MXene, the new family of two-dimensional materials having numerous nanoscale layers, is being considered as a novel microwave absorption material. However, MXene/functionalized MXene-loaded polymer nanocomposites exhibit narrow reflection loss (RL) bandwidth (RL less than or equal to −10 dB). In order to enhance the microwave absorption bandwidth of MXene hybrid-matrix materials, for the first time, macroscopic design approach is carried out for TiO 2 -Ti 3 C 2 T x MXene and Fe 3 O 4 @TiO 2 -Ti 3 C 2 T x MXene hybrids through simulation. The simulated results indicate that use of pyramidal meta structure of MXene can significantly tune the RL bandwidth. For optimized MXene hybrid-matrix materials pyramid pattern, the bandwidth enhances to 3–18 GHz. Experimental RL value well matched with the simulated RL. On the other hand, the optimized Fe 3 O 4 @TiO 2 -Ti 3 C 2 T x hybrid exhibits two specific absorption bandwidths (minimum RL value - −47 dB). Compared with other two-dimensional nanocomposites such as graphene or Fe 3 O 4 -graphene, MXene hybrid-matrix materials show better microwave absorption bandwidth in macroscopic pattern.


2013 ◽  
Vol 26 (7) ◽  
pp. 992-1005 ◽  
Author(s):  
Michael Naguib ◽  
Vadym N. Mochalin ◽  
Michel W. Barsoum ◽  
Yury Gogotsi

Electronics ◽  
2016 ◽  
Vol 5 (4) ◽  
pp. 13 ◽  
Author(s):  
Andreas Bablich ◽  
Satender Kataria ◽  
Max Lemme

ChemInform ◽  
2014 ◽  
Vol 45 (17) ◽  
pp. no-no ◽  
Author(s):  
Michael Naguib ◽  
Vadym N. Mochalin ◽  
Michel W. Barsoum ◽  
Yury Gogotsi

2019 ◽  
Author(s):  
Shuai Zhao ◽  
Chunfeng Lan ◽  
Huanhuan Li ◽  
Chu Zhang ◽  
Tingli Ma

Layered perovskites have attracted considerable attention in optoelectronic applications due to their excellent electronic properties and stability. In this work, the quasi-2D aurivillius halide perovskites are investigated using density functional theory. The single-layer aurivillius perovskite Ba2PbI6 is predicted to have a direct bandgap of 1.89 eV, which is close to that of the Ruddlesden–Popper perovskite Cs2PbI4. The electronic structures near the Fermi level are mainly governed by the [PbX6] octahedra, which leads to similar electronic properties to that of Cs2PbI4. Decomposition energies reveal that these aurivillius perovskites exhibit thermal instability. Increasing the number of [PbX6] octahedra layer can enhance the stability and reduce the bandgap. Bi- and In-based aurivillius perovskites are also calculated to evaluate the Pb-free alternatives. These calculations can serve as a theoretical support in exploring novel layered perovskites.<br>


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