Hydrogen-Insertion-Induced Itinerant Ferromagnetism in Zr2CoH4.8 with Co Chains

2019 ◽  
Vol 123 (24) ◽  
pp. 14964-14968
Author(s):  
Hiroshi Mizoguchi ◽  
Satoru Matsuishi ◽  
Sang-Won Park ◽  
Hideo Hosono
Keyword(s):  
Itinerant Ferromagnetism ◽  
Hydrogen Insertion

STUDY OF ITINERANT FERROMAGNETISM IN Zr1-xTixZn2 AND Zr1-yHfyZn2 BY MAGNETIC RESONANCE

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-632-C1-633 ◽  
Author(s):  
D. SHALTIEL ◽  
D. DAVIDOV ◽  
G. DUBLON ◽  
A. GABAI ◽  
A. GRILL ◽  
...  
Keyword(s):  
Magnetic Resonance ◽  
Itinerant Ferromagnetism

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

scholarly journals Flat-band-induced itinerant ferromagnetism in RbCo2Se2

2021 ◽  
Vol 103 (16) ◽  
Author(s):  
Jianwei Huang ◽  
Zhicai Wang ◽  
Hongsheng Pang ◽  
Han Wu ◽  
Huibo Cao ◽  
...  
Keyword(s):  
Flat Band ◽  
Itinerant Ferromagnetism

Hydrogen insertion, ESR and Mössbauer studies of Cu0.5TaFeP3O12

2005 ◽  
Vol 135 (11-12) ◽  
pp. 692-697 ◽  
Author(s):  
K. Koteswara Rao ◽  
N. Anantharamulu ◽  
A.K. Mishra ◽  
C. Bansal ◽  
M. Vithal
Keyword(s):  
Mössbauer Studies ◽  
Hydrogen Insertion

scholarly journals Investigation of weak itinerant ferromagnetism and critical behavior of Y2Ni7

2011 ◽  
Vol 84 (18) ◽  
Author(s):  
A. Bhattacharyya ◽  
Deepti Jain ◽  
V. Ganesan ◽  
S. Giri ◽  
S. Majumdar
Keyword(s):  
Critical Behavior ◽  
Itinerant Ferromagnetism

ChemInform Abstract: Electronic and Steric Control in Carbon-Hydrogen Insertion Reactions of Diazoacetoacetates Catalyzed by Dirhodium(II) Carboxylates and Carboxamides.

ChemInform ◽  
2010 ◽  
Vol 24 (24) ◽  
pp. no-no
Author(s):  
M. P. DOYLE ◽  
L. J. WESTRUM ◽  
W. N. E. WOLTHUIS ◽  
M. M. SEE ◽  
W. P. BOONE ◽  
...  
Keyword(s):  
Insertion Reactions ◽  
Hydrogen Insertion ◽  
Steric Control
Sign in / Sign up

Export Citation Format

Share Document